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Antibacterial drugs as inhibitors for the corrosion of stainless steel type 304 in HCl solution

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Abstract

The effect of three antibacterial drugs (3-thiazinonyl-bicyclo [4.2.0] octene-carboxylate derivatives) on the corrosion behavior of stainless steel type 304 in 1.0 M HCl solution has been investigated using weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) techniques. The inhibition efficiency increased with increase in inhibitor concentration but decreased with increase in temperature. The thermodynamic functions of corrosion and adsorption processes were evaluated. The potentiodynamic polarization measurements indicated that the inhibitors are of mixed type. The adsorption of these inhibitors was found to obey Langmuir’s adsorption isotherm. Synergism between iodide ion and inhibitors was proposed. The inhibitive action was satisfactory explained by using both thermodynamic and kinetic models. The results obtained from the three different techniques were in good agreement.

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References

  1. Szypowski AJ (2002) Br Corros J 37:141

    Article  CAS  Google Scholar 

  2. Quraishi MA, Ansari FA, Jamal D (2003) Mater Chem Phys 77:687

    Article  CAS  Google Scholar 

  3. Elachouri M, Hajji MS, Kertit S, Essassi EM, Salem M, Coudert R (1995) Corros Sci 37:381

    Article  CAS  Google Scholar 

  4. Merari B, Elattar H, Traisnel M, Bentiss F, Larenee M (1998) Corros Sci 40:391

    Article  Google Scholar 

  5. Bentiss F, Traisnel M, Lagrenee M (2000) Corros Sci 42:127

    Article  CAS  Google Scholar 

  6. Elkadi L, Mernari B, Traisnel M, Bentiss F, Lagrenee M (2000) Corros Sci 42:703

    Article  CAS  Google Scholar 

  7. Walker R (1975) Corros Sci 31:97

    CAS  Google Scholar 

  8. Bentiss F, Lagrenee M, Traisnel M, Lornez JC (1999) Corros Sci 41:789

    Article  CAS  Google Scholar 

  9. Eddy NO (2008) PhD Thesis University of Calabar, Nigeria

  10. Abdallah M (2004) Corros Sci 46(1):1981

    Article  CAS  Google Scholar 

  11. Odoemelam SA, Ogoko EC, Ita BI, Eddy NO (2009) Port Electrochim Acta 27(1):57

    Article  CAS  Google Scholar 

  12. Von Fraunhofer JA, Stidham SH (1991) J Biochem Eng 13(5):424

    Google Scholar 

  13. Solmaz R, Kardas G, Yazici B, Erbil M (2005) Prot Met 41(6):581

    Article  CAS  Google Scholar 

  14. Abdallah M (2002) Corros Sci 44:717

    Article  CAS  Google Scholar 

  15. El-Naggar MM (2007) Corros Sci 49(5):2236

    Google Scholar 

  16. Arslan T, Kandemirli F, Ebenso EE, Love I, Alemu H (2009) Corros Sci 51:35

    Article  CAS  Google Scholar 

  17. Ashassi-Sorkhabi H, Shabani B, Aligholipour B, Seifzadeh D (2006) Appl Surf Sci 252:4039

    Article  CAS  Google Scholar 

  18. Ehteshamzada M, Shahrabi T, Hosseini MG (2006) Appl Surf Sci 252:2949

    Article  CAS  Google Scholar 

  19. Dadgarnezhad A, Sheikhshoaie I, Baghaei F (2004) Asian J Chem 16:1109

    CAS  Google Scholar 

  20. Shokry H, Yuasa M, Sekine I, Issa RM, El-Baradie HY, Gomma GK (1998) Corros Sci 40:2173

    Article  CAS  Google Scholar 

  21. El-Kanouni A, Kertti S, Srhiri A, Bachir K (1996) Bull Electrochem 12:517

    CAS  Google Scholar 

  22. Talati JD, Modi RM (1986) Trans SEAST 11: 259

  23. Szklarska-Smiaiowska Z (1991) Electrochemical and optical techniques for the study of metallic corrosion. Kluwer Academic, The Netherlands, p 545

    Google Scholar 

  24. Langmuir I (1947) J Amer Chem Soc 39:1848

    Article  Google Scholar 

  25. Khamis E (1990) Corrosion 46:476

    CAS  Google Scholar 

  26. El-Awady YA, Ahmed AI (1985) J Ind Chem 24A:601

    CAS  Google Scholar 

  27. Putilova IK, Balezin S, Barannik V (1960) Metallic corrosion inhibitors. Pergamon, Oxford, p 30

    Google Scholar 

  28. Zhao TP, Mu GN (1999) Corros Sci 41:1937

    Article  CAS  Google Scholar 

  29. Fouda AS, Mostafa HA, El-Taib F, El-Ewady GY (2005) Corros Sci 47:1988

    Article  CAS  Google Scholar 

  30. Fouda AS, Al-Sawary AA, Ahmed FSh, El-Abbasy HM (2009) Corros Sci 51:485

    Article  CAS  Google Scholar 

  31. Ammar IA, Darwish S (1967) Corros Sci 7:679

    Google Scholar 

  32. Fisher H (1960) Ann Univ Ferrera Sez 3(Suppl 3):1

    Google Scholar 

  33. Umoren SA, Ogbobe O, Ebenso EE (2006) Trans SAEST 41:74

  34. Umoren SA, Ebenso EE (2007) Mater Chem Phys 106:387

    Article  CAS  Google Scholar 

  35. Oguzie EE, Ebenso EE (2006) Pigment Resin Technol 35:30

    Article  CAS  Google Scholar 

  36. Gomma GK (1998) Mater Chem Phys 55:241

    Article  CAS  Google Scholar 

  37. Aramaki K, Hackerman N (1969) J Electrochem Soc 116:568

    Article  CAS  Google Scholar 

  38. El-Gaber AS, Fouda AS, El-Desoky AM (2008) Sci Technol Mater 20(3):71

    Google Scholar 

  39. Li X, Deng S, Fu H, Mu G (2008) Corros Sci 50:2635

    Article  CAS  Google Scholar 

  40. Sekine I, Sabongi M, Hagiuda H, Oshibe T, Yuasa M, Imahc T, Shibata Y, Wake T (1992) J Electrochem Soc 139:3167

    Article  CAS  Google Scholar 

  41. Larabi L, Benali O, Mekelleche SM, Harek Y (2006) J Appl Surf Sci 253:1371

    Article  CAS  Google Scholar 

  42. Lagrenee M, Mernari B, Bouanis B, Traisnel M, Bentiss F (2002) Corros Sci 44:573

    Article  CAS  Google Scholar 

  43. Khamis E, Bellucci F, Latahision RM, El-Ashry ESh (1991) Corrosion 47(9):667

    Google Scholar 

  44. Wanklyn JN (1981) Corros Sci 21:211

    Article  CAS  Google Scholar 

  45. Tullmin MAA, Robinson FPA (1988) Corrosion 44:664

    CAS  Google Scholar 

  46. Ciesak WR, Duquette DJ (1985) J Electrochem Soc 132:533

    Article  Google Scholar 

  47. Galvole JR, Lumsden JB, Stechle RW (1978) J Electrochem Soc 125:1204

    Article  Google Scholar 

  48. Sugimoto K, Sawada Y (1976) Corrosion 32:347

    CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, El-Mansoura University, El-Mansoura, 35516, Egypt

    A. S. Fouda, H. A. Mostafa & H. M. El-Abbasy

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  1. A. S. Fouda
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  2. H. A. Mostafa
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  3. H. M. El-Abbasy
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Correspondence to A. S. Fouda.

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Fouda, A.S., Mostafa, H.A. & El-Abbasy, H.M. Antibacterial drugs as inhibitors for the corrosion of stainless steel type 304 in HCl solution. J Appl Electrochem 40, 163–173 (2010). https://doi.org/10.1007/s10800-009-9992-1

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  • DOI: https://doi.org/10.1007/s10800-009-9992-1

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