Skip to main content
Log in

Physicochemical properties and molecular structures of Korean waxy rice starches

  • Research Article
  • Published:
Food Science and Biotechnology Aims and scope Submit manuscript

Abstract

The physicochemical properties and molecular structures of waxy rice starches isolated from the newly inbred Korean varieties, Nunbora, Baegseolchal, Baegokchal, and Boseokchal were investigated. Nunbora had the highest ash and crude protein contents and the lowest damaged starch content and solubility at 80°C. The amylopectin contents of all samples were in the range of 98.35–98.84%. All the four waxy rice starches showed A-type crystallinity by x-ray diffraction pattern. Baegseolchal had the lowest pasting temperature (71.9°C), but the highest peak (320.1 RVU) and trough (210.5 RVU) viscosities. Nunbora had the highest pasting temperature, breakdown and setback viscosities. Beagseolchal had the lowest gelatinization temperatures, 63.12 (to) and 68.59°C (tp); however all waxy rice starches did not show significantly different gelatinization enthalpy change (10.25–11.09 J/g). The molecular weight of samples ranged from 4.55×107 to 5.15×107 g/mol. Baegseolchal had the highest proportion (30.02%) of shorter branch chains (DP 6–12) but the lowest proportion of DP 13–24.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Juliano BO. The chemical basis of rice grain quality. pp. 69–90. In: Proceeding of the Workshop on Chemical Aspects of Rice Grain Quality. Webb BD, Blakeney AB (eds). International Rice Research Institute, Manila, Philippines (1979)

    Google Scholar 

  2. Jeong EG, Lee CK, Choi YH, Kim JT, Kim S, Son JR. Identification of chalkiness development of milled waxy rice grains with harvest times and the moisture contents. Korean J. Crop Sci. 53: 58–63, (2008)

    Google Scholar 

  3. Bao J, Corke H, Sun M. Genetic diversity in the physicochemical properties of waxy rice (Oryza sativa L.) starch. J. Sci. Food Agr. 84: 1299–1306, (2004)

    Article  CAS  Google Scholar 

  4. Shi M, Gao Q. Physicochemical properties, structure and in vitro digestion of resistant starch from waxy rice starch. Carbohyd. Polym. 84: 1151–1157, (2011)

    Article  CAS  Google Scholar 

  5. Jiranuntakul W, Puttanlek C, Rungsardthong V, Puncha-arnon S, Uttapap D. Microstructural and physicochemical properties of heatmoisture treated waxy and normal starches. J. Food Eng. 104: 246–258, (2011)

    Article  CAS  Google Scholar 

  6. Jane J. Chen YY, Lee LF, McPherson AE, Wong KS, Radosavlijevic M, Kasemsuwan T. Effects of amylopectin branch chain length and amylose content on the gelatinization and pasting properties of starch. Cereal Chem. 76: 629–637, (1999)

    Article  CAS  Google Scholar 

  7. Vandeputte GE, Vermeylen R, Geeroms J, Delcour JA. Rice starch. I. Structural aspects provide insight into crystallinity characteristics and gelatinization behavior of granular starch. J. Cereal Sci. 38: 43–52, (2003)

    Article  CAS  Google Scholar 

  8. Song YC, Cho JH, Lee JH, Kwak DY, Park NB, Yeo US, Kim CS, Jeon MG, Lee JY, Lee GH, Ha WG, Lee JS, Jung KH, Cho YH, Kang HW. A glutinous rice variety with multiple disease resistance ‘Baegokchal’. Korean J. Breed. Sci. 45: 31–37, (2013)

    Article  Google Scholar 

  9. Rural Development Administration. The information of waxy rice cultivars. Available from: http://www.nongsaro.go.kr. Accessed March 30, 2015

    Google Scholar 

  10. Choi YH, Kang MY. Texture and retrogradation characteristics of injeulmi made by different varieties of waxy rice. J. Korean Soc. Food Sci. Nutr. 28: 837–844, (1999)

    Google Scholar 

  11. Park IM, Ibanez AM, Zhong F, Shoemaker CF. Gelatinization and pasting properties of waxy and non-waxy rice starches. Starch–Stärke 59: 388–396, (2007)

    Article  Google Scholar 

  12. You SY, Lim ST, Lee JH, Chung HJ. Impact of molecular and crystalline structure on in vitro digestibility of waxy rice starches. Carbohyd. Polym. 112: 729–735, (2014)

    Article  CAS  Google Scholar 

  13. Song JY, Park JH, Shin M. The effects of annealing and acid hydrolysis on resistant starch level and the properties of cross-linked RS4 rice starch. Starch–Stärke 63: 147–153, (2011)

    Article  CAS  Google Scholar 

  14. AACC. Approved Methods of the AACC 10th ed. Method 44–15A. American Association of Cereal Chemists, St Paul, MN, USA (2000)

    Google Scholar 

  15. AACC. Approved Methods of the AACC 10th ed. Method 46–11A. American Association of Cereal Chemists, St Paul, MN, USA (2000)

    Google Scholar 

  16. AACC. Approved Methods of the AACC 10th ed. Method 08–01. American Association of Cereal Chemists, St Paul, MN, USA (2000)

    Google Scholar 

  17. AACC. Approved Methods of the AACC 10th ed. Method 30-10. American Association of Cereal Chemists, St Paul, MN, USA (2000)

    Google Scholar 

  18. Gibson TS, Solah VA, McCleary BV. A procedure to measure amylose in cereal starches and flours with concanavalin A. J. Cereal Sci. 25: 111–119, (1997)

    Article  CAS  Google Scholar 

  19. Medcalf MD, Gilles KA. Wheat starches. I. Comparison of physicochemical properties. Cereal Chem. 42: 558–568, (1965)

    CAS  Google Scholar 

  20. Schoch TJ. Swelling power and solubility of granular starches. Vol. IV, pp. 106–108. In: Method in Carbohydrate Chemistry. Roy L (ed). Academic Press, Waltham, MA, USA (1964)

    Google Scholar 

  21. Evers AD, Stevens DJ. Starch damage in advances in cereal science and technology. Vol. VII, pp. 321–349. In: Advances in Cereal Science and Technology. Pomeranz Y. (ed). American Association of Cereal Chemists Inc., St Paul, MN, USA (1985)

    Google Scholar 

  22. Yoo SH, Lee CS, Kim BS, Shin M. The properties and molecular structures of gusiljatbam starch compared to those of acorn and chestnut starches. Starch–Stärke 64: 339–347, (2012)

    Article  CAS  Google Scholar 

  23. Shih FF. An update on the processing of high-protein rice products. Mol. Nutr. Food Res. 47: 420–424, (2003)

    Google Scholar 

  24. Oh SM, No JH, Shin M. Gelatinization properties and molecular structure of waxy rice starches isolated from Korean japonica and indica cultivars. Korean J. Food Cook. Sci. 30: 716–725, (2014)

    Article  Google Scholar 

  25. Song J, Lee CK, Youn JT, Kim SL, Kim DS, Kim JH, Jeong EG, Suh SJ. Relationship among alkali digestive value, amylopectin fine structure and physical properties of cooked rice. Korean J. Crop Sci. 53: 320–325, (2008)

    Google Scholar 

  26. Choi HJ, Kim WS, Shin M. Properties of Korean amaranth starch compared to waxy millet and waxy sorghum starches. Starch–Stärke 56: 469–477, (2004)

    Article  CAS  Google Scholar 

  27. Wani AA, Singh P, Shah MA, Schweiggert-Weisz U, Gul K, Wani IA. Rice starch diversity: Effects on structural, morphological, thermal, and physicochemical properties-A review. Compr. Rev. Food Sci. Food Saf. 11: 417–436, (2012)

    Article  CAS  Google Scholar 

  28. Zhang Q, Abe T, Ando H, Sasahara T. Classification of glutinous rice (Oryza sativa L.) starches based on x-ray diffraction pattern. Ann. Bot.-London 72: 551–557, (1993)

    Article  CAS  Google Scholar 

  29. Hanashiro I, Abe J, Hizukuri S. A periodic distribution of the chain length of amylopectin as revealed by high-performance anion exchange chromatography. Carbohyd. Res. 283: 151–159, (1996)

    Article  CAS  Google Scholar 

  30. Noda T, Takahata Y, Sato T, Suda I, Morishita T, Ishiguro K, Yamakawa O. Relationships between chain length distribution of amylopectin and gelatinization properties within the same botanical origin for sweet potato and buckwheat. Carbohyd. Polym. 37: 153–158, (1998)

    Article  CAS  Google Scholar 

  31. Chung JH, Han JA, Yoo B, Seib PA, Lim ST. Effects of molecular size and chain profile of waxy cereal amylopectin on paste rheology during retrogradation. Carbohyd. Polym. 71: 365–371, (2008)

    Article  CAS  Google Scholar 

  32. Shi YC, Seib PA. The structure of four waxy starches related to gelatinization and retrogradation. Carbohyd. Polym. 227: 131–145, (1992)

    Article  CAS  Google Scholar 

  33. Singh H, Lin JH, Huang WH, Chang YH. Influence of amylopectin structure on rheological and retrogradation properties of waxy rice starches. J. Cereal Sci. 56: 367–373, (2012)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Malshick Shin.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Oh, S.M., Shin, M. Physicochemical properties and molecular structures of Korean waxy rice starches. Food Sci Biotechnol 24, 791–798 (2015). https://doi.org/10.1007/s10068-015-0103-2

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10068-015-0103-2

Keywords

Navigation