Hydrogen CARS thermometry in H2–N2 mixtures at high pressure and medium temperatures: influence of linewidths models

Abstract.

In order to improve the accuracy of H₂ CARS thermometry, H₂ Q-branch CARS spectra have been recorded for various H₂–N₂ mixtures in a high-pressure cell at different pressures and temperatures (up to 40 bar and 875 K). Due to the low spectral resolution of broadband CARS experiments, the relevant spectral lineshape factor is the linewidth ratio Γ(Q(3))/Γ(Q(1)), since Q(1) and Q(3) are the most intense lines of the Q-branch spectrum in this temperature range. For the first time, the speed-inhomogeneous effects are accounted for in the simulation of the CARS profiles. The evaluated temperatures are in good agreement with reference values obtained by thermocouples. The specific role on the accuracy of H₂ CARS thermometry of the speed inhomogeneity is carefully analyzed, in connection with the influence of the nitrogen concentration.