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The weird world of nanoscale gold

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Abstract

Protagonists in the emerging field of nanotechnology have as their objective the design, construction and study of useful devices based on nanoscale materials and objects. Objects or structures that have at least one important dimension in the range 0.5 to perhaps 50 nm may be considered to be in the nanoscale domain. These sizes lie far below the 200 nm or so that can be resolved with an optical microscope, and are closer in size to the 0.3 nm diameter of individual atoms. The field of nanotechnology is attracting keen interest at present. The excitement is motivated by the observation that control of matter at the nanoscale holds the promise of, amongst others, faster computing, better medicines, and more useful materials. In this paper, the physical phenomena on which this optimism is based are broadly discussed and explained. Where appropriate, examples of the rather different and curious properties of gold at the nanoscale are used to illustrate the points covered.

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References

  1. R. Feynman,Engineering and Science, 1960,23, 22, reprinted in Miniaturization, H.D. Gilbert ed., Reinhold, New York, 1961, pp.282-296

    Google Scholar 

  2. G. Binnig and H. Rohrer,Surface Science, 1983,126, 236

    Article  CAS  Google Scholar 

  3. E. Drexler,Engines of Creation, Anchor-Doubleday, New York, 1987

    Google Scholar 

  4. R. Cingolani, R. Rinaldi, G. Maruccio and A. Biasco,Physica E, 2002,13, 1229

    Article  CAS  Google Scholar 

  5. S. Xiao, F. Liu, A.E. Rosen, J.F. Hainfeld, N.C. Seeman, K. Musier-Forsyth and R.A. Kiehl,J. of Nanoparticle Research, 2002,4, 313

    Article  CAS  Google Scholar 

  6. M.C. Daniel and D. Astruc,Chem. Review, 2004,104, 293

    Article  CAS  Google Scholar 

  7. M.B. Cortie, London Bullion Association Precious Metals Conference, 21–22nd May 2001, Istanbul, Turkey, LBMA, London, 2001, pp.165–172

  8. D. Tománek,Physica B: Condensed Matter, 2002,323(1–4), 86

    Article  Google Scholar 

  9. J. Erlebacher, M.J. Aziz, A. Karma, N. Dimitrov and K. Sieradzki,Nature, 22nd March 2001,410, 450

    Article  CAS  Google Scholar 

  10. M. Cortie and E. van der Lingen, Gold 2003, 28th September-1st October 2003, Vancouver

  11. M.B. Cortie and E. Van der Lingen,Materials Forum, 2002,26, 1

    CAS  Google Scholar 

  12. C. Cretu and E van der Lingen,Gold Bulletin, 1999,32(4), 115

    Article  CAS  Google Scholar 

  13. M. Quinten,J. of Cluster Science, 1999,10(2), 319

    Article  CAS  Google Scholar 

  14. C.R. Martin and D.T. Mitchell, Analytical Chemistry News & Features, 1st May 1998, 322A

  15. A.P. Alivisatos, Scientific American, September 2001, 67

  16. D. Compton, L. Cornish and E. van der Lingen,Gold Bulletin, 2003,36(1), 10

    Article  CAS  Google Scholar 

  17. S.J. Oldenburg, J.B. Jackson, S.L. Westscott and N.J. Halas, AppliedPhysics Letters, 1999,75(19), 2897

    CAS  Google Scholar 

  18. K.L. Kelly, E. Coronado, L.L. Zhao and G.C. Schatz,J. Phys. Chem. B, 2003,107, 668

    Article  CAS  Google Scholar 

  19. H.H. Read,Rutley's Elements of Mineralogy, Thomas Murby & Co, London, 26th Edition, 1970

    Google Scholar 

  20. C.L. Cleveland, U. Landman, T.G. Schaaf and M.N. Shafigullin,Phys. Rev. Letters, 1997,79, 1873

    Article  CAS  Google Scholar 

  21. A.L. Mackay,Acta Cryst., 1962,15, 916

    Article  CAS  Google Scholar 

  22. J. Turkevich,Gold Bulletin, 1985,18(3), 86

    Article  CAS  Google Scholar 

  23. H.B. Liu, J.A. Ascencio, M. Perez-Alvarez and M.J. Yacaman,Surface Science, 2001,491, 88

    Article  CAS  Google Scholar 

  24. K. Dick, T. Dhanasekaran, Z. Xhang and D. Meisel,J. Am. Chem. Soc, 2002,124(10), 2312

    Article  CAS  Google Scholar 

  25. S. Ismail, K. Deppert, T. Junno, C. Kortegaard, H. Larne, M.H. Magnusson, C. Thelander and I. Samuelson,J. of Nanoparticle Research, 2002,4, 351

    Article  CAS  Google Scholar 

  26. W. Eberhardt,Surface Science, 2002,500, 242

    Article  CAS  Google Scholar 

  27. R.C. Ashoori,Nature, 1st February 1996,379, 413

    Article  CAS  Google Scholar 

  28. R.P. Andres, T. Bein, M. Dorogi, S. Feng, J.I. Henderson, C.P. Kubiak, W. Mahoney, R.G. Osifchin and R. Reifenberger,Science, 1996,272, 1323

    Article  CAS  Google Scholar 

  29. S.A. Stockman et al, MRS Fall Meeting, 2-6th December 2002, Boston, USA, L8.1

  30. D.N. Madsen, K. Mølhave, R. Mateiu, A. Rasmussen, M. Brorson, C.J.H. Jacobsen and P. Bøggild,Nano Letters, 2003,3(1), 47

    Article  CAS  Google Scholar 

  31. M. Valden, X. Lai and D.W. Goodman,Science, 1998,281(5583), 1647

    Article  CAS  Google Scholar 

  32. R.W. Siegel, Scientific American, December 1996, 42

  33. Y.Y. Lim and M.M. Chaudhri,Philos. Mag.A, 2002,82(10), 2071

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute for Nanoscale Technology, University of Technology Sydney, PO Box 123, 2007, Broadway, NSW, Australia

    Michael B. Cortie

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  1. Michael B. Cortie
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Professor Michael Cortie is the Director of the Institute for Nanoscale Technology, at University of Technology, Sydney, where he specialises in the science and technology of precious metals.

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Cortie, M.B. The weird world of nanoscale gold. Gold Bull 37, 12–19 (2004). https://doi.org/10.1007/BF03215512

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