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Reaction of hydrogen chloride with halides of quaternary ammonium salts

  • Inorganic and Analytical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The solubility of (n-C4H9)4NCl and (n-C4H9)4NBr in benzene was determined at 25°.

  2. 2.

    The interaction of gaseous HCl with tetra-substituted ammonium halides was investigated. A decrease in the dimensions of the anion and an increase in the dimensions of the cation promote interaction.

  3. 3.

    The behavior of the reaction products of HCl with tetra-substituted ammonium halides in benzene was investigated. In the case of salts sparingly soluble in benzene, the presence of a correlation between the aggregated state of the reaction products of HCl with the salts at 25° and their solubility in benzene at the same temperature was established.

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Authors and Affiliations

  1. Institute of Electrochemistry, Academy of Sciences USSR, USSR

    N. M. Aplatova, Yu. M. Kessler & A. I. Gorbanev

Authors
  1. N. M. Aplatova
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  2. Yu. M. Kessler
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  3. A. I. Gorbanev
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Additional information

The article is published as the result of a resolution of the conference of Editors-in-Chief of the journals of the Academy of Sciences USSR on July 12, 1962, as the dissertation work-of N. M. Aplatova.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8 pp. 1369–1372, August, 1964

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Aplatova, N.M., Kessler, Y.M. & Gorbanev, A.I. Reaction of hydrogen chloride with halides of quaternary ammonium salts. Russ Chem Bull 13, 1283–1286 (1964). https://doi.org/10.1007/BF00850319

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  • DOI: https://doi.org/10.1007/BF00850319

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