Abstract
Carrier mobility is a basic parameter of organic semiconductors. In this paper, hole mobility of zinc phthalocyanine (ZnPc) thin films was determined by light-intensity-dependent current–voltage characteristics. Firstly, built-in voltage, Vbi, of the organic diode with the structure of “ITO/zinc phthalocyanine (ZnPc)/2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP)/Al” was measured as 0.45 V by using saturation photovoltage method. Based on the value of Vbi, the hole mobility of ZnPc thin film was (1.619 ± 0.06) × 10−6 cm2 V−1 s−1 by fitting the measured photocurrent–voltage characteristic with the established theory of space-charge-limited photocurrent conduction. The measured carrier mobility coincides with that reported in other literature.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Liu, M., Michael, B.J., Henry, J.S.: Efficient planar heterojunction perovskite solar cells by vapour deposition. Nature 501, 395–398 (2013)
Cole, A., McIlroy, R.J., Thorpe, S.C., Cook, M.J., McMurdo, J., Ray, A.K.: Substituted phthalocyanine gas sensors. Sens. Actuators B 13, 416–419 (1993)
Ikram, I.M., Rabinal, M.K., Muliman, B.G.: A laboratory experiment to measure the built-in potential of a p–n junction by a photosaturation method. Eur. J. Phys. 30, 127–134 (2009)
Mihailetchi, V.D., Wildeman, J., Blom, P.M.W.: Space-charge limited photocurrent. Phys. Rev. Lett. 94, 126602 (2005)
Wiley, W.C., McLaren, I.H.: Time-of-flight mass spectrometer with improved resolution. Rev. Sci. Instrum. 26, 1150 (1955)
Pinner, D.J., Friend, R.H., Tessler, N.: Transient electroluminescence of polymer light emitting diodes using electrical pulses. J. Appl. Phys. 86, 5116 (1999)
Tyler, B.: Organic optoelectronic devices employing small molecules. Ph.D. Dissertation, Arizona State University (2014)
Wang, Y., Ma, C., Wang, R., Li, R., Peng, Y.: Model of mixing ratio dependence of built-in voltages in organic bulk heterojunction solar cells. J. Optoelectron. Adv. Mater. 13, 165 (2011)
Huang, F., Peng, Y., Xu, K., Lv, W., Xu, S., Wang, Y., Tang, Y., Wei, Y., Yang, Y., Liu, G.: Simultaneous determination of built-in voltage and charge carrier mobility in organic diodes from light intensity dependent current–voltage characteristics. J. Phys. D Appl. Phys. 50, 205106 (2017)
Wojdyła, M., Derkowska, B., Łukasiak, Z., Bała, W.: Absorption and photoreflectance spectroscopy of zinc phthalocyanine (ZnPc) thin films grown by thermal evaporation. Mater. Lett. 60, 3441–3446 (2006)
Widmer, J., Fischer, J., Tress, W., Leo, K., Riede, M.: Electric potential mapping by thickness variation: a new method for model-free mobility determination in organic semiconductor thin films. Org. Electron. 14, 3460–3471 (2013)
Acknowledgements
This work was supported by National Key R&D Program of China Grant No. 2016YFF0203605, and the Natural Science Foundation of Zhejiang Province Grant No. LY18F050009 and LY18F040007.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Ye, Y. et al. (2020). Determining Hole Mobility of Zinc Phthalocyanine Thin Films by Light-Intensity-Dependent Current–Voltage Characteristics. In: Peng, Y., Dong, X. (eds) Proceedings of 2018 International Conference on Optoelectronics and Measurement. Lecture Notes in Electrical Engineering, vol 567. Springer, Singapore. https://doi.org/10.1007/978-981-13-8595-7_29
Download citation
DOI: https://doi.org/10.1007/978-981-13-8595-7_29
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-13-8594-0
Online ISBN: 978-981-13-8595-7
eBook Packages: EngineeringEngineering (R0)