Skip to main content

Phosphors and White LED Packaging

  • Chapter
  • First Online:
III-Nitride Based Light Emitting Diodes and Applications

Part of the book series: Topics in Applied Physics ((TAP,volume 133))

Abstract

Both phosphors and the LED packaging play a crucial role in optical properties of white LEDs. The selection criteria of the host lattice, activator ions as well as phosphors utilized in white LEDs are firstly discussed, followed by the overview of the technologically important phosphors, including yttrium aluminum garnets, alkaline earth orthosilicates, alkaline earth sulfides/thiogallets, and (oxo)nitridosilicates (i.e., nitrides). Typically, (oxo)nitridosilicate phosphors are highlighted and introduced in this chapter as they have significantly red-shifted photoluminescence spectra, abundant emission colors and high reliability. Then, the LED packaging configurations, such as “phosphor-in-cup,” “remote-phosphor,” and quantum dot (QD) white LEDs, are discussed in terms of their luminous efficacy, color rendering index, and color temperature. Finally, some issues on phosphors (materials searching, color tuning, particle size, and geometry) and white LEDs (packaging configurations and reliability assessments) are addressed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 189.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 249.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 249.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Y. Narukawa, M. Ichikawa, D. Sanga, M. Sano, T. Mukai, White light emitting diodes with super-high luminous efficacy. J. Phys. D Appl. Phys. 43(35), 354002 (2010)

    Article  Google Scholar 

  2. http://www.cree.com/news-and-events/cree-news/press-releases/2012/april/120412-254-lumen-per-watt

  3. J.K. Kim, E.F. Schubert, Transcending the replacement paradigm of solid-state lighting. Opt. Express 16, 21835–21842 (2008)

    Article  ADS  Google Scholar 

  4. M.R. Krames, O.B. Shckekin, R. Mueller-Mach, G.O. Mueller, L. Zhou, G. Harbers, M.G. Craford, Status and future of high-power light-emitting diodes for solid state lighting. J. Displ. Technol. 3, 160–175 (2007)

    Article  ADS  Google Scholar 

  5. W.M. Yen, S. Shionoya, H. Yamamoto, Phosphor Handbook, 2nd edn. (CRC Press, Boca Raton, 2006)

    Book  Google Scholar 

  6. R.J. Xie, Y.Q. Li, N. Hirosaki, H. Yamamoto, Nitride Phosphors and Solid State Lighting (CRC Press, Boca Raton, 2010)

    Google Scholar 

  7. P.F. Smet, A.B. Parmentier, D. Poelman, Selecting coversion phosphors for white light-emitting diodes. J. Electrochem. Soc. 158, R37–R54 (2011)

    Article  Google Scholar 

  8. A. Pavese, G. Artioli, M. Prencipe, X-ray single-crystal diffraction study of pyrope in the temperature 30-973 K. Am. Mineral. 80, 457–464 (1995)

    Article  ADS  Google Scholar 

  9. E.P. Meagher, The crystal structures of pyrope and grossularite at elevated temperatures. Am. Mineral. 60, 218–228 (1975)

    Google Scholar 

  10. S. Nakamura, S.F. Chichibu, Introduction to Nitride Semiconductor Blue Lasers and Light Emitting Diodes (Taylor & Francis, London, 2000)

    Google Scholar 

  11. G. Blasse, A. Bril, A new phosphor for flying spot cathode-ray tubes for color television: yellow emitting Y3Al5O12:Ce3+. Appl. Phys. Lett. 11, 53–55 (1967)

    Article  ADS  Google Scholar 

  12. A.A. Setlur, W.J. Heward, Y. Gao, A.M. Srivastava, R.G. Chandran, M.V. Shankar, Crystal chemistry and luminescence of Ce3+-doped Lu2CaMg2(Si, Ge)3O12 and its use in LED based lighting. Chem. Mater. 18, 3314–3322 (2006)

    Article  Google Scholar 

  13. J. Silver, R. Withnall, Color conversion phosphors for LEDs, in Luminescent Materials and Applications, ed. by A. Kitai (Wiley, 2008)

    Google Scholar 

  14. V. Banchmann, C. Ronda, A. Meijerink, Temperature quenching of yellow Ce3+ luminescence in YAG:Ce. Chem. Mater. 21, 2077–2084 (2009)

    Article  Google Scholar 

  15. J. Ueda, S. Tanabe, T. Nakanishi, Analysis of Ce3+ luminescence quenching in solid solutions between Y3Al5O12 and Y3Ga5O12 by temperature dependence of photoconductivity measurement. J. Appl. Phys. 110, 053102 (2011)

    Article  ADS  Google Scholar 

  16. W.W. Holloway, M. Kestigian, Optical properties of cerium-activated garnet crystals. J. Opt. Soc. Am. 59, 60–63 (1969)

    Article  ADS  Google Scholar 

  17. H.S. Jang, W.B. Im, D.C. Lee, D.Y. Jeon, S.S. Kim, Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs. J. Lumin. 126, 371–377 (2007)

    Article  Google Scholar 

  18. Y.S. Lin, R.S. Liu, B.M. Cheng, Investigation of the luminescent properties of Tb3+-substituted YAG:Ce,Gd phosphors. J. Electrochem. Soc. 152(6), J41–J45 (2005)

    Article  Google Scholar 

  19. A.A. Setlur, W.J. Heward, M.E. Hannah, U. Happek, Incorporation of Si4+-N3- into Ce3+-doped garnets for warm white LED phosphors. Chem. Mater. 20, 6277–6283 (2008)

    Article  Google Scholar 

  20. H.S. Jang, J.H. Kang, Y.H. Won, K.M. Chu, D.Y. Jeon, Origin of the discrepancy between photoluminescence brightness of TAG: Ce and electroluminescence brightness of TAG:Ce-based white LED expected from phosphor brightness. Opt. Lett. 33(18), 2140–2142 (2008)

    Article  ADS  Google Scholar 

  21. Y. Shimomura, T. Honma, M. Shigeiwa, T. Akai, K. Okamoto, N. Kijima, Photoluminescence and crystal structure of green-emitting Ca3Sc2Si3O12:Ce3+ phosphors for white light emitting diodes. J. Electrochem. Soc. 154, J35–J38 (2007)

    Article  Google Scholar 

  22. A.A. Setlur, W.J. Heward, Y. Gao, A.M. Srivastava, R.G. Chandran, M.V. Shankar, Crystal chemistry and luminescence of Ce3+ -doped Lu2CaMg2(Si, Ge)3O12 and its use in LED based lighting. Chem. Mater. 18, 3314–3322 (2006)

    Article  Google Scholar 

  23. J.L. Wu, G. Gundiah, A.K. Cheetham, Structure-property correlations in Ce-doped garnet phosphors for use in solid state lighting. Chem. Phy. Lett. 441, 250–254 (2007)

    Article  ADS  Google Scholar 

  24. T.L. Barry, Fluorescence of Eu2+ activated phase in binary alkaline earth orthosilicate system. J. Electrochem. Soc. 115, 1181–1183 (1968)

    Article  Google Scholar 

  25. G. Blasse, W.L. Wanmaker, J.W. Vrugt, A. Bril, Fluorescence of Eu2+-activated silicates. Philips Res. Repts. 23, 189–200 (1968)

    Google Scholar 

  26. J.K. Park, C.H. Kim, S.H. Park, H.D. Park, S.Y. Chois, Application of strontium silicate yellow phosphor for white light-emitting diodes. Appl. Phys. Lett. 84, 1647–1649 (2004)

    Article  ADS  Google Scholar 

  27. J.K. Park, K.J. Choi, J.H. Yeon, S.J. Lee, C.H. Kim, Embodiment of the warm white-light-emitting diodes by using a Ba2+ codoped Sr3SiO5: Eu phosphor. Appl. Phys. Lett. 88, 043511 (2006)

    Article  ADS  Google Scholar 

  28. H.S. Jang, D.Y. Yeon, Yellow-emitting Sr3SiO5:Ce3+, Li+ phosphor for white-light-emitting diodes and yellow-light-emitting diodes. Appl. Phys. Lett. 90, 041906 (2007)

    Article  ADS  Google Scholar 

  29. T.L. Barry, Luminescent properties of Eu2+ and Eu2++Mn2+ activated BaMg2Si2O7. J. Electrochem. Soc. 117, 381–385 (1968)

    Article  Google Scholar 

  30. W.J. Yang, L.Y. Luo, T.M. Chen, Luminescence and energy transfer of Eu- and Mn-coactivated CaAl2Si2O8 as a potential phosphor for white-light UVLED. Chem. Mater. 17, 3883–3888 (2005)

    Article  Google Scholar 

  31. J.S. Kim, P. Jeon, J.C. Choi, Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor. Appl. Phys. Lett. 84, 2931–2933 (2004)

    Article  ADS  Google Scholar 

  32. M.P. Saradi, U.V. Varadaraju, Photoluminescence studies on Eu2+-activated Li2SrSiO4—a potential orange-yellow phosphor for solid-state lighting. Chem. Mater. 18, 5267–5272 (2006)

    Article  Google Scholar 

  33. Y. Hu, W. Zhuang, H. Ye, S. Zhang, Y. Fang, X. Huang, Preparation and luminescent properties of (Ca1-xSrx)S:Eu2+ red-emitting phosphor for white LED. J. Lumin. 111, 139–145 (2005)

    Article  Google Scholar 

  34. D. Poelman, J.E. Haecke, P.F. Smet, Advances in sulfide phosphors for displays and lighting. J. Mater. Sci.: Mater. Electron. 20, S134–S138 (2009)

    Google Scholar 

  35. T.E. Peter, J.A. Baglio, Luminescence and structural properties of thiogallate phosphors Ce3+ and Eu2+ activated phosphors. Part I. J. Electrochem. Soc. 119, 230–236 (1972)

    Article  Google Scholar 

  36. R. Mueller-March, G.O. Mueller, M.R. Krames, T. Trottier, High-power phosphor-converted light-emitting diodes based on III-nitrides. IEEE J. Sel. Topics Quantum Electron 8, 339–345 (2002)

    Article  Google Scholar 

  37. Y.R. Do, K.Y. Ko, S.H. Na, Y.D. Huh, Luminescence properties of potential Sr1-xCaxGa2S4: Eu green and greenish-yellow-emitting phosphors for white LED. J. Electrochem. Soc. 153, H142–H146 (2006)

    Article  Google Scholar 

  38. R.-J. Xie, N. Hirosaki, Silicon-based oxynitride and nitride phosphors for white LEDs—a review. Sci. Tech. Adv. Mater. 8, 588–600 (2007)

    Article  Google Scholar 

  39. W. Schnick, Nitridosilicates, oxonitridosilicates (sions), and oxonitridoaluminosilicates (sialons)—new materials with promising properties. Int. J. Inorg. Mater. 3, 1267–1272 (2001)

    Article  Google Scholar 

  40. M. Zeuner, S. Pagano, W. Schnick, Nitridosilicates and oxonitridosilicates: from ceramic materials to structural and functional diversity. Angew. Chem. Int. Ed. 50, 7754–7775 (2011)

    Article  Google Scholar 

  41. G.Z. Cao, R. Metselaar, α’-sialon ceramics, a review. Chem Mater. 3, 242–252 (1991)

    Article  Google Scholar 

  42. J.W.H. van Krevel, J.W.T. van Rutten, H. Mandal, H.T. Hintzen, R. Metselaar, Luminescence properties of terbium-, cerium-, or europium-doped α-sialon materials. J. Solid State Chem. 165, 19–24 (2002)

    Article  ADS  Google Scholar 

  43. R.-J. Xie, M. Mitomo, K. Uheda, F.F. Xu, Y. Akimune, Preparation and luminescence spectra of calcium- and rare-earth (R = Eu, Tb, and Pr)-codoped α-SiAlON ceramics. J. Am. Ceram. Soc. 85, 1229–1234 (2002)

    Article  Google Scholar 

  44. R.-J. Xie, N. Hirosaki, K. Sakuma, Y. Yamamoto, M. Mitomo, Eu2+-doped Ca-alpha-SiAlON: a yellow phosphor for white light-emitting diodes. Appl. Phys. Lett. 84, 5404–5406 (2004)

    Article  ADS  Google Scholar 

  45. R.-J. Xie, N. Hirosaki, M. Mitomo, Y. Yamamoto, T. Suehiro, Optical properties of Eu2+ in α-SiAlON. J. Phys. Chem. B 108, 12027–12031 (2004)

    Article  Google Scholar 

  46. R.-J. Xie, N. Hirosaki, M. Mitomo, K. Takahashi, K. Sakuma, Highly efficient white-light-emitting diodes fabricated with short-wavelength yellow oxynitride phosphors. Appl. Phys. Lett. 88, 101104 (2006)

    Article  ADS  Google Scholar 

  47. R.-J. Xie, N. Hirosaki, M. Mitomo, K. Sakuma, N. Kimura, Wavelength-tunable and thermally stable Li-α-SiAlON: Eu2+ oxynitride phosphors for white light-emitting diodes. Appl. Phys. Lett. 89, 241103 (2006)

    Article  ADS  Google Scholar 

  48. K. Sakuma, K. Omichi, N. Kimura, M. Ohashi, D. Tanaka, N. Hirosaki, Y. Yamamoto, R.-J. Xie, T. Suehiro, Warm-white light-emitting diode with yellowish orange SiAlON ceramic phosphor. Opt. Lett. 29, 2001–2003 (2004)

    Article  ADS  Google Scholar 

  49. T. Ekstrom, M. Nygen, SiAlON ceramics. J. Am. Ceram. Soc. 75, 259–276 (1992)

    Article  Google Scholar 

  50. K.H. Jack, Review—sialons and related nitrogen ceramics. J. Mater. Sci. 11, 1135–1158 (1976)

    Article  ADS  Google Scholar 

  51. H. Hirosaki, R.-J. Xie, K. Kimoto, T. Sekiguchi, Y. Yamamoto, T. Suehiro, M. Mitomo, Characterization and properties of green-emitting β-SiAlON:Eu2+ powder phosphors for white light-emitting diodes. Appl. Phys. Lett. 86, 211905-1–211905-3 (2005)

    Article  ADS  Google Scholar 

  52. R.-J. Xie, N. Hirosaki, H.L. Li, Y.Q. Li, M. Mitomo, Synthesis and photoluminescence properties of α-sialon:Eu2+ (Si6-zAlzOzN8-z:Eu2+)—a promising green oxynitride phosphor for white light-emitting diodes. J. Electrochem. Soc. 154, J314–J319 (2007)

    Article  Google Scholar 

  53. Y.Q. Li, N. Hirosaki, R.-J. Xie, T. Takeda, M. Mitomo, Crystal and electronic structures, luminescence properties of Eu2+-doped Si6−zAlzOzN8−z and MySi6−zAlz−yOz+yN8−z−y (M = 2Li, Mg, Ca, Sr, Ba). J. Solid State Chem. 181, 3200–3210 (2008)

    Article  ADS  Google Scholar 

  54. K. Kimoto, R.-J. Xie, Y. Matsui, K. Ishizuka, N. Hirosaki, Direct observation of single dopant atom in light-emitting phosphor of β-SiAlON:Eu2+. Appl. Phys. Lett. 94, 041908 (2009)

    Article  ADS  Google Scholar 

  55. R.-J. Xie, N. Hirosaki, T. Takeda, Wide color gamut backlight for liquid crystal displays using three-band phosphor-converted white light-emitting diodes. Appl. Phys. Express 2, 022401 (2009)

    Article  ADS  Google Scholar 

  56. K. Uheda, N. Hirosaki, Y. Yamamoto, A. Naoto, T. Nakajima, H. Yamamoto, Luminescence properties of a red phosphor, CaAlSiN3:Eu2+, for white light-emitting diodes. Electrochem. Solid State Lett. 9, H22–H25 (2006)

    Article  Google Scholar 

  57. X.Q. Piao, T. Horikawa, H. Hanzawa, K. Machida, Characterization and luminescence properties of Sr2Si5N8:Eu2+ phosphor for white light-emitting-diode illumination. Appl. Phys. Lett. 88, 161908 (2006)

    Article  ADS  Google Scholar 

  58. Y.Q. Li, J.E.J. van Steen, J.W.H. van Krevel, G. Botty, A.C.A. Delsing, F.J. DiSalvo, G. de With, H.T. Hintzen, Luminescence properties of red-emitting M2Si5N8:Eu2+ (M = Ca, Sr, Ba) LED conversion phosphors. J. Solid State Compd. 417, 273–279 (2006)

    Google Scholar 

  59. C.J. Duan, X.J. Wang, W.M. Otten, A.C.A. Delsing, J.T. Zhao, H.T. Hintzen, Preparation, electronic structure, and photoluminescence properties of Eu2+- and Ce3+/Li+-activated alkaline earth silicon nitride MSiN2 (M = Sr, Ba). Chem. Mater. 20, 1597–1605 (2008)

    Article  Google Scholar 

  60. H. Watanabe, H. Wada, K. Seki, M. Itou, N. Kijima, Synthetic method and luminescence properties of SrxCa1-xAlSiN3:Eu2+ mixed nitride phosphors. J. Electrochem. Soc. 155, F31–F36 (2008)

    Article  Google Scholar 

  61. K. Takahashi, N. Hirosaki, R.-J. Xie, M. Harada, K. Yoshimura, Y. Tomomura, Luminescence properties of blue La1-xCexAl(Si6-zAlz)(N10-zOz)(z ~ 1) oxynitrides phosphors and their application in white light-emitting diode. Appl. Phys. Lett. 91, 091923 (2007)

    Article  ADS  Google Scholar 

  62. T. Suehiro, N. Hirosaki, R.-J. Xie, T. Sato, Blue-emitting LaSi3N5:Ce3+ fine powder phosphor for UV-converting white light diodes. Appl. Phys. Lett. 95, 051903 (2009)

    Article  ADS  Google Scholar 

  63. K. Inoue, N. Hirosaki, R.-J. Xie, T. Takeda, Highly efficient and thermally stable blue-emitting AlN:Eu2+ phosphor for ultraviolet white light-emitting diodes. J. Phys. Chem. C 133, 9392–9397 (2009)

    Article  Google Scholar 

  64. V. Bachmann, C. Ronda, O. Oeckler, W. Schnick, Meijerink., Color point tuning for (Sr, Ca, Ba)SiON: Eu for white light LEDs. Chem. Mater. 21, 316–325 (2009)

    Article  Google Scholar 

  65. C. Braun, M. Seibald, S.L. Börger, O. Oeckler, T.D. Boyko, A. Moewes, G. Miehe, A. Tuckes, W. Schnick, Material properties and structural characterization of M3Si6O12N2:Eu2+ (M = Ba, Sr)—a comprehensive study on a promising green phosphor for pc-LEDs. Chem. Euro. J. 16, 9646–9657 (2010)

    Article  Google Scholar 

  66. O. Oeckler, J.A. Kechele, H. Koss, P.J. Schmidt, W. Schnick, Sr5Al5+xSi21-xN35-xO2+x:Eu2+ (x ≈ 0)—a novel green phosphor for white light pcLEDs with disordered intergrowth structure. Chem. Eur. J. 15, 5311–5319 (2009)

    Article  Google Scholar 

  67. K. Shioi, Y. Michiue, N. Hirosaki, R.-J. Xie, T. Takeda, Y. Matsushita, M. Tanaka, Y.Q. Li, Synthesis and photoluminescence of a novel Sr-SiAlON:Eu2+ blue-green phosphor (Sr14Si68-sAl6+sOsN106-s:Eu2+ (s ≈ 7)). J. Alloy Compds. 509, 332–337 (2011)

    Article  Google Scholar 

  68. Y. Fukuda, K. Ishida, I. Mitsuishi, S. Nunoue, Luminescence properties of Eu2+-doped green-emitting Sr-Sialon phosphor and its application to white light-emitting diodes. Appl. Phys. Express. 2, 012401 (2009)

    Article  ADS  Google Scholar 

  69. T. Suerhiro, N. Hirosaki, R.-J. Xie, Synthesis and photoluminescent properties of (La, Ca)3Si6N11:Ce3+ fine powder phosphors for solid-state lighting. ACS Appl. Mater. Interf. 3(3), 811–816 (2011)

    Article  Google Scholar 

  70. Y.Q. Li, N. Hirosaki, R.-J. Xie, T. Takeda, M. Mitomo, Yellow-orange-emitting CaAlSiN3:Ce3+ phosphor: structure, photoluminescence, and application in white LEDs. Chem. Mater. 20, 6704–6714 (2008)

    Article  Google Scholar 

  71. R.-J. Xie, N. Hirosaki, T. Suehiro, F.-F. Xu, M. Mitomo, A simple, efficient synthetic route to Sr2Si5N8:Eu2+-based red phosphors for white lighting-emitting diodes. Chem. Mater. 18, 5578–5583 (2006)

    Article  Google Scholar 

  72. J. Ruan, R.-J. Xie, N. Hirosaki, T. Takeda, Nitrogen gas pressure sintering and photoluminescence properties of orange-red SrAlSi4N7:Eu2+ phosphors for white light-emitting diode. J. Am. Ceram. Soc. 94(2), 536–542 (2011)

    Article  Google Scholar 

  73. A.H. Munsell, A Color Notation, 1st edn. (Munsell Color Company, Baltimore, MD, 1905); A.H. Munsell, Atlas of the Munsell Color System (Wadsorth-Howland & Company, Malden, MA, 1915)

    Google Scholar 

  74. Y. Ohno, Color rendering and luminous efficacy of white LED spectra, in Proceedings of SPIE, vol. 5530, ed. by I.T. Ferguson, N. Narendran, S.P. DenBaars, J.C. Carrano (SPIE, Bellingham, 2004), pp. 88–98

    Google Scholar 

  75. A. Zukauskas, R. Vaicekauskas, F. Ivanauskas, R. Gaska, M.S. Shur, Optimization of white polychromatic semiconductor lamps. Appl. Phys. Lett. 80, 234–236 (2002)

    Article  ADS  Google Scholar 

  76. A. Zukauskas, M.S. Shur, R. Gaska, Introduction to Solid State Lighting (Wiley, New York, 2002)

    Google Scholar 

  77. R.W.G. Hunt, M.R. Pointer, Measuring Colour (Wiley, New York, 2011)

    Book  Google Scholar 

  78. V.L. Colvin, M.C. Schlamp, A.P. Alivisatos, Light-emitting diodes made from cadmium selenide nanocrystals and a semiconducting polymer. Nature 370, 354–357 (1994)

    Article  ADS  Google Scholar 

  79. B. Damilano, N. Grandjean, F. Semond, J. Massies, M. Leroux, From visible to white light emission by GaN quantum dots on Si(111) substrate. Appl. Phys. Lett. 75, 962–964 (1999)

    Article  ADS  Google Scholar 

  80. B. Damilano, N. Grandjean, F. Semond, J. Massies, M. Leroux, Violet to orange room temperature luminescence from GaN quantum dots on Si(111) substrates. Phys. Status Solidi B 216, 451–455 (1999)

    Article  ADS  Google Scholar 

  81. Y. Li, A. Rizzo, R. Cingolani, G. Gigli, White-light-emitting diodes using semiconductor nanocrystals. Microchim. Acta 159, 207–215 (2007)

    Article  Google Scholar 

  82. A.J. Shields, Semiconductor quantum light sources. Nat. Photonics 1(215), 1–18 (2007)

    MathSciNet  Google Scholar 

  83. I.K. Park, J.Y. Kim, M.K. Kwon, C.Y. Cho, J.H. Lim, S.J. Park, Phosphor-free white light-emitting diode with laterally distributed multiple quantum wells. Appl. Phys. Lett. 92, 091110-1 (2008)

    Google Scholar 

  84. J.K. Kim, H. Luo, E.F. Schubert, J. Cho, C. Sone, Y. Park, Strongly enhanced phosphor efficiency in GaInN white light-emitting diodes using remote phosphor configuration and diffuse reflector cup. Jpn. J. Appl. Phys. 44(21), L649–L651 (2005)

    Article  ADS  Google Scholar 

  85. N. Kimura, K. Sakuma, S. Hirafune, K. Asano, N. Hirosaki, R.-J. Xie, Extrahigh color rendering white light-emitting diode lamps using oxynitride and nitride phosphors excited by blue light-emitting diode. Appl. Phys. Lett. 90, 051109 (2007)

    Article  ADS  Google Scholar 

  86. K. Sakuma, N. Hirosaki, N. Kimura, M. Ohashi, R.-J. Xie, Y. Yamamoto, T. Suehiro, K. Asano, D. Tanaka, White light-emitting diode lamps using oxynitride and nitride phosphor materials. IEICE Trans. Electron. E88-C, 2057–2064 (2005)

    Google Scholar 

  87. H.S. Jang, W.B. Im, D.Y. Jeon, J.S. Lee, Tunable full-color-emitting La0.827Al11.9O19.09:Eu2+, Mn2+ phosphor for application to warm white-light-emitting diodes. Appl. Phys. Lett. 89, 231909 (2006)

    Article  ADS  Google Scholar 

  88. M. Zhang, J. Wang, W. Ding, Q. Zhang, Q. Su, A novel white light-emitting diode (w-LED) fabricated with Sr6BP5O20:Eu2+ phosphors. Appl. Phys. B 86, 647–651 (2007)

    Article  ADS  Google Scholar 

  89. J.H. Zhang, X. Zhang, X. Sun, Y. Luo, S. Lu, X.J. Wang, White light emitting diode by using α-Ca2P2O7:Eu2+, Mn2+ phosphor. Appl. Phys. Lett. 90, 261113 (2007)

    Article  ADS  Google Scholar 

  90. S.H. Park, H.S. Yoon, H.M. Boo, H.G. Jang, K.H. Lee, W.B. Im, Efficiency and thermal stability enhancement of Sr2SiO4:Eu2+ phosphor via Bi3+ codoping for solid state white lighting. J. Jpn. Appl. Phys. 51, 022602 (2012)

    ADS  Google Scholar 

  91. R.-J. Xie, N. Hirosaki, N. Kimura, K. Sakuma, M. Mitomo, 2-phosphor-converted white light-emitting diodes using oxynitride/nitride phosphors. Appl. Phys. Lett. 90, 191101 (2007)

    Article  ADS  Google Scholar 

  92. S.E. Brinkley, N. Pfaff, K.A. Denault, Z.J. Zhang, H.T. Hintzen, R. Seshadri, S. Nakamura, S.P. DenBaars, Robust thermal performance of Sr2Si5N8:Eu2+: an efficient red emitting phosphor for light emitting diode based white lighting. Appl. Phys. Lett. 99, 241106 (2011)

    Article  ADS  Google Scholar 

  93. R. Mueller-Mach, G. Mueller, M.R. Krames, H.A. Hoppe, F. Stadler, W. Schnick, T. Juestel, P. Schmidt, Highly efficient all-nitride phosphor-converted white light emitting diode. Phy. Status Solidi (A) 202, 1727–1732 (2005)

    Article  ADS  Google Scholar 

  94. H. Watanabe, H. Wada, K. Seki, M. Itou, N. Kijima, Synthetic method and luminescence properties of SrxCa1-xAlSiN3:Eu2+ mixed nitride phosphors. J. Electrochem. Soc. 155, F31–F36 (2008)

    Article  Google Scholar 

  95. A.A. Setlur, E.V. Radkov, C.S. Henderson, J.H. Her, A.M. Srivastava, N. Karkada, M.S. Kishore, N.P. Kumar, D. Aesram, A. Deshpande, B. Kolodin, L.S. Grigorov, U. Happek, Energy-efficient, high-color-rendering LED lamps using oxyfluoride and fluorite phosphors. Chem. Mater. 22, 4076–4082 (2010)

    Article  Google Scholar 

  96. C.C. Yang, C.M. Lin, Y.J. Chen, Y.T. Wu, S.R. Chuang, R.S. Liu, S.F. Hu, Highly stable three-band white light from an InGaN-based blue light-emitting diode chip precoated with (oxy)nitride green/red phosphors. Appl. Phys. Lett. 90, 123503 (2007)

    Article  ADS  Google Scholar 

  97. W.B. Im, N.N. Fellows, S.P. DenBaars, R. Seshadri, Y.I. Kim, LaSr2AlO5, a versatile host compound for Ce3+-based yellow phosphors: structural tuning of optical properties and use in solids state white lighting. Chem. Mater. 21, 2957–2966 (2009)

    Article  Google Scholar 

  98. H.S. Jang, Y.H. Won, D.Y. Jeon, Improvement of electroluminescent properties of blue LED coated with highly luminescent yellow-emitting phosphors. Appl. Phys. B 95, 715–720 (2009)

    Article  ADS  Google Scholar 

  99. J.K. Kim, H. Luo, E.F. Schubert, J. Cho, C. Sone, Y. Park, Strongly enhanced phosphor efficiency in GaInN white light-emitting diodes using remote phosphor configuration and diffuse reflector cup. Jpn. J. Appl. Phys. 44(21), L649–L651 (2005)

    Article  ADS  Google Scholar 

  100. H.T. Huang, Y.P. Huang, C.C. Tsai, Planar lighting system using array of blue LEDs to excite yellow remote phosphor film. J. Display Technol. 7(1), 44–51 (2011)

    Article  ADS  Google Scholar 

  101. Y. Zhu, N. Narendran, Investigation of remote-phosphor white light-emitting diodes with multi-phosphor layers. Jpn. J. App. Phys. 49, 100203 (2010)

    Article  ADS  Google Scholar 

  102. S. Nishiura, S. Tanabe, K. Fujioka, Y. Fujimoto, Properties of transparent Ce:YAG ceramic phosphors for white LED. Opt. Mater. 33, 688–691 (2011)

    Article  ADS  Google Scholar 

  103. S. Tanabe, S. Fujita, S. Yoshihara, A. Sakamoto, S. Yamamoto, YAG glass-ceramic phosphor for white LED (II): luminescence characteristics. Proc. SPIE 5941, 594112-1 (2005)

    Google Scholar 

  104. S. Fujita, S. Yoshihara, A. Sakamoto, S. Yamamoto, S. Tanabe, YAG glass-ceramic phosphor for white LED (I): background and development. Proc. SPIE 5941, 594111-1 (2005)

    Google Scholar 

  105. W.C. Cheng, S.Y. Huang, C.C. Tsai, J.S. Liou, J.H. Chang, J. Wang, W.H. Cheng, The efficacy study of Ce:YAG doped low-temperature glass for white LED modules, in Proceedings of the 16th Opto-electronics and Communication Conference, 2011, pp. 481–482

    Google Scholar 

  106. J. Wang, C.C. Tsai, W.C. Cheng, M.H. Chen, C.H. Chung, W.H. Cheng, High thermal stability of phosphor-converted white light-emitting diodes employing Ce:YAG-doped glass, IEEE. J. Sel. Topics Quantum Electron. 17(3), 741–746 (2011)

    Article  Google Scholar 

  107. A.P. Alivisators, Perspectives on the physical chemistry of semiconductor nanocrystals. J. Phys. Chem. 100, 13226–13239 (1996)

    Article  Google Scholar 

  108. M.J. Bowers, J.R. McBridge, S.J. Rosenthal, White-light emission from magic-sized cadmium selenide nanocrystals. J. Am. Chem. Soc. 127, 378 (2005)

    Article  Google Scholar 

  109. H.S. Jang, H. Yang, S.W. Kim, J.Y. Han, S.G. Lee, D.Y. Jeon, White light-emitting diodes with excellent color rendering based on organically caped CdSe quantum dots and Sr3SiO5:Ce3+,Li+ phosphors. Adv. Mater. 20, 2696–2702 (2008)

    Article  Google Scholar 

  110. W. Chung, K. Park, H.J. Yu, J. Kim, B.Y. Chun, S.H. Kim, White emission using mixtures of CdSe quantum dots and PMMA as a phosphor. Opt. Mater. 32, 515–521 (2010)

    Article  ADS  Google Scholar 

  111. E. Jang, S. Jun, H. Jang, J. Lim, B. Kim, Y. Kim, White-light-emitting diodes with quantum dot color converters for display backlights. Adv. Mater. 22(28), 3076–3080 (2010)

    Article  Google Scholar 

  112. H.S. Chen, C.K. Hus, H.Y. Hong, InGaN-CdSe-ZnSe quantum dots white LEDs. Photon. Technol. Lett. 18, 193–195 (2006)

    Article  ADS  Google Scholar 

  113. A. Lita, A.L. Washington II, L. Van de Burgt, G.F. Strouse, A.E. Stiegman, Stable efficient solid-state white-light-emitting phosphors with a high scotopic/photopic ratio fabricated from fused CdSe-silica nanocomposites. Adv. Mater. 22, 3987–3991 (2010)

    Article  Google Scholar 

  114. Y. Zhang, C. Xie, H. Su, J. Liu, S. Pickering, Y. Wang, W.W. Yu, J. Wang, Y. Wang, J. Hahm, N. Dellas, S.E. Mohney, J. Xu, Employing heavy metal-free colloidal quantum dots in solution-processed white light-emitting diodes. Nano Lett. 11, 329–332 (2011)

    Article  ADS  Google Scholar 

  115. http://www.qled-info.com/nanosys-qdef-led-backlight-technology-at-sid-2011/

  116. N.T. Tran, J.P. You, F.G. Shi, Effect of phosphor particle size on luminous efficacy of phosphor-converted white LEDs. J. Lightwave Technol. 27, 5145–5150 (2009)

    Article  ADS  Google Scholar 

  117. Y.C. Lin, J.P. You, N.T. Tran, Y. He, F.G. Shi, Packaging of phosphor based high power white LEDs: effects of phosphor concentration and packaging configuration. J. Electron Packing. 133, 011009 (2011)

    Article  Google Scholar 

  118. J.P. You, N.T. Tran, F.G. Shi, Light extraction enhanced white light-emitting diodes with multi-layered phosphor configuration. Opt. Express 18, 5055–5060 (2010)

    Article  ADS  Google Scholar 

  119. Y.H. Won, H.S. Jang, K.W. Cho, Y.S. Song, D.Y. Jeon, H.K. Kwon, Effect of phosphor geometry on the luminous efficiency of high-power white light-emitting diodes with excellent color rendering property. Opt. Lett. 34, 1–3 (2009)

    Article  ADS  Google Scholar 

  120. M. Meneghini, A. Tazzoli, G. Mura, G. Meneghesso, E. Zanoni, A review on the physical mechanisms that limit the reliability of GaN-based LEDs. IEEE Trans. Electron Dev. 57, 108–118 (2010)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Rong-Jun Xie .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2017 Springer Nature Singapore Pte Ltd.

About this chapter

Cite this chapter

Xie, RJ., Hirosaki, N. (2017). Phosphors and White LED Packaging. In: Seong, TY., Han, J., Amano, H., Morkoç, H. (eds) III-Nitride Based Light Emitting Diodes and Applications. Topics in Applied Physics, vol 133. Springer, Singapore. https://doi.org/10.1007/978-981-10-3755-9_14

Download citation

Publish with us

Policies and ethics