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Core Levels and Final States

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Photoelectron Spectroscopy

Part of the book series: Advanced Texts in Physics ((ADTP))

Abstract

Photoemission produces a final state that is lacking one electron with respect to the initial state. Therefore, PES always measures final-state energies which can be related to initial-state energies only after some theoretical considerations. The problem is illustrated in Fig. 2.1. On the left-hand side are shown the one-electron orbital energies —ε in the ground state of the neon atom. On the right-hand side are the final state configurations, as measured by PES for the same atom.1 These are, of course, hole-state energies. The relation between these two sets of energy levels is far from trivial. However, one should add that the orbital energies (left side) cannot be measured. In general, one can only measure the energy levels given on the right-hand side, which are (many-body) hole-state energies [2.1].

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References

  1. A good description of the breakdown of the one-electron picture in PES has been given in G. Wendin: Structure and Bonding 45 ( Springer, Berlin, Heidelberg 1981 )

    Google Scholar 

  2. K. Siegbahn, C. Nordling, R. Fahlman, R. Nordberg, K. Hamrin, J. Hedman, G. Johansson, T. Bergmark, S.-E. Karlsson, I. Lindgren, B. Lindberg: In Nova Acta Regiae Sci. Soc., Upsaliensis, Ser IV, 20 (1967) K. Siegbahn, C. Nordling, G. Johansson, J. Hedman, P.F. Heden, K. Hamrin, U. Gelius, T. Bergmark, L.O. Werme, R. Manne, Y. Baer: ESCA-Applied to Free Molecules ( North-Holland, Amsterdam 1969 )

    Google Scholar 

  3. W.C. Price: In Electron Spectroscopy: Theory, Techniques and Applications I, ed. by C.R. Brundle, A.D. Baker ( Academic, New York 1977 )

    Google Scholar 

  4. W.L. Jolly: In Electron Spectroscopy: Theory, Techniques and Applications I, ed. by C.R. Brundle, A.D. Baker ( Academic, New York 1977 )

    Google Scholar 

  5. H.W.B. Skinner: Proc. Roy. Soc. (London) A135, 84 (1932)

    Article  CAS  Google Scholar 

  6. C.E. Moore: Ionization potentials and ionization limits derived from the analysis of optical spectra. Nat. Stand. Ref. Data Sev., NBS, 34 (1970); and Atomic energy levels. Nat. Stand. Ref. Data Sev., NBS 35/I (1971) and US Nat. Bur. Stand. Circ. No.467 (1958) Vols.I-III

    Google Scholar 

  7. E.M. Baroody: J. Opt. Soc. Am. 62, 1528 (1972)

    Article  CAS  Google Scholar 

  8. L. Pauling: The Nature of the Chemical Bond (Oxford Univ. Press, Oxford 1950 )

    Google Scholar 

  9. P. Finn, R.K. Pearson, J.M. Hollander, W.L. Jolly: Inorg. Chem. 10, 378 (1971)

    Article  Google Scholar 

  10. L. Hedin, A. Johansson: J. Phys. B2, 1336 (1969)

    CAS  Google Scholar 

  11. W.L. Jolly: Discuss. Faraday Soc. 54, 13 (1972)

    Article  Google Scholar 

  12. D.W. Davis, D.A. Shirley: Chem. Phys. Lett. 15, 185 (1972)

    Article  CAS  Google Scholar 

  13. W.L. Jolly, W.B. Perry: J. Amer. Chem. Soc. 95, 5442 (1973) W.L. Jolly, W.B. Perry: Inorg. Chem. 13, 2686 (1974)

    CAS  Google Scholar 

  14. J.C. Slater: Quantum Theory of Molecules and Solids, Vol.IV ( McGraw Hill, New York 1974 )

    Google Scholar 

  15. M. Born: Verh. dt. phys. Ges. 21, 13 and 679 (1919) F. Haber: Verh. dt. phys. Ges. 21, 750 (1919)

    Google Scholar 

  16. C.S. Fadley, S.B.M. Hagstroem, J.M. Hollander, M.P. Klein, D.A. Shirley: J. Chem. Phys. 48, 3779 (1968)

    Article  CAS  Google Scholar 

  17. N.F. Mott, R.W. Gurney: Electronic Processes in Ionic Crystals ( Dover, New York 1964 ) p. 56

    Google Scholar 

  18. P.H. Citrin, T.D. Thomas: J. Chem. Phys. 57, 4446 (1972)

    Article  CAS  Google Scholar 

  19. G.K. Wertheim, D.N.E. Buchanan, J.E. Rowe, P.H. Citrin: Surf. Sci. Lett. 319, L41 (1994).

    Article  CAS  Google Scholar 

  20. M. Cardona, L. Ley: In Photoemission in Solids I ed. by M. Cardona, L. Ley,Topics Appl. Phys., Vol.26 (Springer, Berlin, Heidelberg 1978) Chap.1

    Google Scholar 

  21. R.C. Martin, D.A. Shirley: In Electron Spectroscopy: Theory, Techniques and Applications I, ed. by C.R. Brundle, A.D. Baker ( Academic, New York 1977 )

    Google Scholar 

  22. C.S. Fadley: In Electron Spectroscopy: Theory, Techniques and Applications II, ed. by C.R. Brundle, A.D. Baker ( Academic, New York 1978 )

    Google Scholar 

  23. T. Koopmans: Physica 1, 104 (1933)

    Article  CAS  Google Scholar 

  24. J.C. Slater, J.B. Mann, T.M. Wilson, J.H. Wood: Phys. Rev. 184, 672 (1969)

    Article  CAS  Google Scholar 

  25. U. Gelius: J. Electron Spectrosc. 5, 985 (1974)

    Article  CAS  Google Scholar 

  26. D.A. Shirley: Chem. Phys. Lett. 16, 220 (1972)

    Article  CAS  Google Scholar 

  27. B. Johansson: J. Phys. F 4, L169 (1974)

    Article  CAS  Google Scholar 

  28. B. Johansson, N. Mârtensson: Phys. Rev. B 21, 4427 (1980)

    Article  CAS  Google Scholar 

  29. B. Johansson: Phys. Rev. B 20, 1315 (1979)

    Article  CAS  Google Scholar 

  30. P. Steiner, S. Hüfner: Solid State Commun. 37, 79 1981); Acta Met. 29, 1885 (1981)

    Google Scholar 

  31. P. Steiner, S. Hüfner, N. Mârtensson, B. Johansson: Solid State Commun. 37, 73 (1981)

    Article  CAS  Google Scholar 

  32. P. Steiner, S. Hüfner: Solid State Commun. 37, 279 (1981)

    Article  CAS  Google Scholar 

  33. C.P. Flynn: J. Phys. F 10, L 315 (1980)

    Google Scholar 

  34. W.C. Martin, R. Zalubas, L. Hagan: Atomic energy levels — The rare earth elements, Nat. Bur. Stand. (U.S.) Ref. Data Ser. 60 U.S.GPO, Washington, DC (1978)

    Google Scholar 

  35. U.L. Van der Sluis, L.J. Nugent: J. Opt. Soc. Am. 64, 687 (1974)

    Google Scholar 

  36. J.F. Herbst, D.N. Lowry, R.E. Watson: Phys. Rev. B 6, 1913 (1972)

    Google Scholar 

  37. J.F. Herbst, R.E. Watson, J.W. Wilkins: Phys. Rev. B 13, 1439 (1976)

    Article  CAS  Google Scholar 

  38. J.F. Herbst, R.E. Watson, J.W. Wilkins: Phys. Rev. B 17, 3089 (1978)

    Article  CAS  Google Scholar 

  39. J.K. Lang, Y. Baer, P.A. Cox: J. Phys. Metal. Phys. 11, 121 (1981)

    Article  CAS  Google Scholar 

  40. S. Hüfner, P. Steiner: Valence Instabilities, ed. by P. Wachter, H. Boppart ( North-Holland, Amsterdam 1982 ) p. 263

    Google Scholar 

  41. M.R. Norman, D.D. Koelling, A.J. Freeman, H.J.F. Janssen, B.I. Min, T. Oguchi, Y. Ling: Phys. Rev. Lett. 53, 1673 (1984)

    Article  CAS  Google Scholar 

  42. S. Hüfner, P. Steiner: Z. Physik B 46, 37 (1982)

    Article  Google Scholar 

  43. O. Gunnarsson, K. Schönhammer: Phys. Rev. Lett. 50, 604 (1983)

    Article  CAS  Google Scholar 

  44. O. Gunnarsson, K. Schönhammer: Phys. Rev. B 28, 4315 (1983)

    Article  CAS  Google Scholar 

  45. D.M. Wieliczka, C.G. Olson, D.W. Lynch: Phys. Rev. Lett. 52, 2180 (1984)

    Article  CAS  Google Scholar 

  46. G. Kalkowski, E.V. Sampathkumaran, C. Laubschat, M. Dornke, G. Kaindl:Solid State Commun. 55, 977 (1985)

    Article  CAS  Google Scholar 

  47. R.D. Parks, S. Raan, M.L. Den Boer, M.L. Chang, G.P. Williams: Phys. Rev. Lett. 52, 2176 (1984)

    Article  CAS  Google Scholar 

  48. S. Hüfner: J. Phys. F 16, L31 (1986)

    Article  Google Scholar 

  49. O. Gunnarsson, K. Schönhammer: In Handbook on the Physics and Chemistry of Rare Earths, Vol.10, ed. by K.A. Gschneidner, L. Eyring, S. Hüfner ( Elsevier Science, New York 1987 )

    Google Scholar 

  50. J.H. van Vleck: Phys. Rev. 45, 405 (1934)

    Article  Google Scholar 

  51. G.K. Wertheim, S. Hüfner, H.J. Guggenheim: Phys. Rev. B 7, 556 (1973)

    Google Scholar 

  52. S. Hüfner, G.K. Wertheim: Phys. Rev. B 7, 2333 (1973)

    Google Scholar 

  53. R.L. Cohen, G.K. Wertheim, A. Rosencwaig, H.J. Guggenheim: Phys. Rev. B 5, 1037 (1972)

    Article  Google Scholar 

  54. D.A. Shirley: In Photoemission in Solids,ed. by M. Cardona, L.Ley, Topics Appl. Phys., Vol.26 (Springer, Berlin, Heidelberg 1978) Chap.4

    Google Scholar 

  55. F.R. McFeely, S.P. Kowalczyk, L. Ley. D.A. Shirley: Phys. Lett. A 49, 301 (1974)

    Article  Google Scholar 

  56. B.W. Veal, A.P. Paulikas: Phys. Rev. Lett. 51, 1995 (1983)

    Google Scholar 

  57. B.W. Veal, A.P. Paulikas: Phys. Rev. B 31, 5399 (1985)

    Article  CAS  Google Scholar 

  58. D.K.G. de Boer, C. Haas, G.A. Sawatzky: Phys. Rev. B 29, 4401 (1984)

    Article  Google Scholar 

  59. V. Kinsinger, I. Sander, P. Steiner, R. Zimmermann, S. Hüfner: Solid State Commun. 73, 527 (1990)

    Google Scholar 

  60. K. Okada, A. Kotani, B.T. Thole: J. Electron Spectrosc. Relat. Phenom. 58, 325 (1992)

    Google Scholar 

  61. S.J. Oh, G.H. Gweon, J.G. Park: Phys. Rev. Lett. 68, 2850 (1992)

    Google Scholar 

  62. V. Kinsinger, R. Zimmermann, S. Hüfner, P. Steiner: Z. Physik B 89, 21 (1992)

    Google Scholar 

  63. P.S. Bagus, G. Pacchioni, F. Parmigiani: Chem. Phys. Lett. 207, 569 (1993)

    Google Scholar 

  64. K. Okada, A. Kotani, V. Kinsinger, R. Zimmermann, S. Hüfner: J. Phys. Soc. Jpn. 63, 2410 (1994)

    Google Scholar 

  65. K. Karlsson, O. Gunnarsson, O. Jepsen: J. Phys. Condens. Mat. 4, 895 (1992); 4, 2801 (1992)

    Google Scholar 

  66. J.C. Parlebas, M.A. Khan, T. Uozurni, K. Okada, A. Kotani: ISSP Report, Ser. A, No. 2902 (1994)

    Google Scholar 

  67. K. Okada, A. Kotani: J. Electron Spectrosc. Relat. Phenom. 54, 313 (1990)

    Article  Google Scholar 

  68. B. Hermsmeier, C.S. Fadley, M.O. Krause, J. Jimenez-Mier, P. Gerard, S.T. Manson: Phys. Rev. Lett. 61, 2592 (1988)

    Article  CAS  Google Scholar 

  69. A.J. Freeman, B.I. Min, M.R. Norman: In Handbook on the Physics and Chemistry of Rare Earths,ed. by K.A. Gschneidner, L. Eyring, S. Hüfner (Elsevier Science, New York 1987) Vol.10.

    Google Scholar 

  70. S. Hüfner: Optical Properties of Transparent Rare Earth Compounds ( Academic, New York 1978 )

    Google Scholar 

  71. F. Patthey, B. Delley, W.D. Schneider, Y. Baer: Phys. Rev. Lett. 55, 1918 (1985)

    Article  Google Scholar 

  72. S. Hiifner, L. Schlapbach: Z. Physik B 64, 417 (1986)

    Article  Google Scholar 

  73. M. Campagna, G.K. Wertheim, Y. Baer: In Photoemission in Solids II, ed. by Ley, M. Cardona, Topics Appl. Phys., Vol.27 (Springer, Berlin, Heidelberg 1979 ) Chap.4 M. Campagna, G.K. Wertheim, E. Bucher: Structure and Bonding 30, 99 (Springer, Berlin, Heidelberg 1976 )

    Google Scholar 

  74. J.N. Chazaviel, M. Campagna, G.K. Wertheim, P.Y. Schmidt: Solid State Commun. 19, 725 (1976)

    Article  Google Scholar 

  75. P.A. Cox: Structure and Bonding 24, 59 ( Springer, Berlin, Heidelberg 1975 )

    Google Scholar 

  76. A. Zunger, A.J. Freeman: Phys. Rev. B 15, 2901 (1977)

    Article  Google Scholar 

  77. M.R. Norman, D.D. Koelling, A.J. Freeman: Phys. Rev. B 31, 6251 (1985)

    Article  CAS  Google Scholar 

  78. M.R. Norman: Phys. Rev. B 31, 6261 (1985)

    Article  CAS  Google Scholar 

  79. M.R. Norman, D.D. Koelling, A.J. Freeman: Phys. Rev. B 32, 7748 (1985)

    Article  CAS  Google Scholar 

  80. B.1. Min, H.J.F. Jansen, T. Oguchi, A.J. Freeman: J. Mag. Mag. Mat. 61, 139 (1986)

    Article  Google Scholar 

  81. M.R. Norman, A.J. Freeman: Phys. Rev. B 33, 8896 (1986)

    Article  CAS  Google Scholar 

  82. A. Fröhlisch, N. Warsdahl, J. Hasselströhm, O. Karis, D. Menzel, N. Miirtensson, A. Nielsson: Phys. Ref. Lett. 81, 1730 (1998)

    Google Scholar 

  83. M. Scheffler, A.M. Bradshaw: In The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis, ed. by D.A. King, D.P. Woodruff ( Elsevier, Amsterdam 1983 )

    Google Scholar 

  84. S. Kowalczyk: Thesis, Univ. of California, Berkeley, Calif. (1976)

    Google Scholar 

  85. S.A. Flodstroem, C.W.B. Martinson, R.Z. Bachrach, S.B.M. Hagstroem, R.S. Bauer: Phys. Rev. Lett. 40, 907 (1978)

    Article  Google Scholar 

  86. T.C. Chiang, G. Kaindl, T. Mandel: Phys. Rev. B 33, 695 (1986)

    Article  CAS  Google Scholar 

  87. G.K. Wertheim, S.B. DiCenzo, D.N.E. Buchanan: Phys. Rev. B 33, 5384 (1986)

    Article  CAS  Google Scholar 

  88. S.B. DiCenzo, G.K. Wertheim: Comments Solid State Phys. 11, 203 (1985)

    CAS  Google Scholar 

  89. G.K. Wertheim: Z. Phys. B 66, 53 (1987)

    Article  CAS  Google Scholar 

  90. Angewandte Oberfldchenanalyse,ed. by M. Grasserbauer, H.J. Dudek, M.F. Ebel (Springer, Berlin, Heidelberg 1986)

    Google Scholar 

  91. P. Steiner, H. Höchst, S. Hüfner: In Photoemission in Solids II, ed. by L.Ley,M. Cardona, Topics Appl. Phys., Vol. 27 ( Springer, Berlin, Heidelberg 1979 )

    Google Scholar 

  92. R.F. Reilman, A. Msezane, S.T. Manson: J. Electr. Spectr. 8, 389 (1976)

    Article  CAS  Google Scholar 

  93. J.J. Yell, I. Lindau: Atomic Data and Nuclear Data Tables 32, 1 (1985)

    Article  Google Scholar 

  94. J.H. Scofield: J. Electron Spec. 8, 129 (1976)

    Article  CAS  Google Scholar 

  95. D.R. Penn: J. Electron Spec. 9, 29 (1976)

    Article  CAS  Google Scholar 

  96. J. Electron Spectrosc. Relat. Phenom. 100 (1999)

    Google Scholar 

  97. V.I. Nefedov in Ref. [2.91]

    Google Scholar 

  98. A. Jablonski, C.J. Powell in Ref. [2.91]

    Google Scholar 

  99. M.P. Seah in Ref. [2.91]

    Google Scholar 

  100. D. Briggs, M.P. Seah (Eds.), Practical Surface Analysis (Wiley, Chichester 1990 ), Vols. I and II

    Google Scholar 

  101. J.N. Andersen, T. Balasubramanian, C.-O. Almbladh, L.I. Johansson, R. Nyholm: Phys. Rev. Lett. 86, 4398 (2001)

    Article  CAS  Google Scholar 

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  1. Fakultät für Physik und Elektrotechnik, Fachrichtung 7.2 — Experimentalphysik, Universität des Saarlandes, Postfach 151150, 66041, Saarbrücken, Germany

    Professor Dr. Stefan Hüfner

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Hüfner, S. (2003). Core Levels and Final States. In: Photoelectron Spectroscopy. Advanced Texts in Physics. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-09280-4_2

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