Abstract
The influence of chelating agents (organic acids with different structures) on iron oxides and hydroxyapatite nanoparticle (NP) morphology obtained by two different synthetic procedures (precipitation method and hydrothermal synthesis) were studied. The relationship between the synthetic conditions and the nature of the growth limiters or NP morphology regulation agents was considered. The mechanism of the NP growth regulation and the general peculiarities of this process for materials with different chemical natures are also discussed. It was concluded that the use of chelating agents dramatically changes the NP size and shape and the degree of modification is determined by the binding force between chelating agent and ions on NP surfaces.
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Acknowledgements
This study was financially supported by RFBR (research project no. 13-03-00943-a).
Research was performed at the Centre of X-ray Diffraction Studies and Innovative Technologies of Composite Nanomaterials, Center of Chemical Analysis and Materials Research, and Centre for Optical and Laser Materials Research of St. Petersburg State University.
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Osmolowskaya, O.M. (2016). Regulation of HAP and Iron Oxide Nanoparticle Morphology Using Chelating Agents. In: Frank-Kamenetskaya, O., Panova, E., Vlasov, D. (eds) Biogenic—Abiogenic Interactions in Natural and Anthropogenic Systems. Lecture Notes in Earth System Sciences. Springer, Cham. https://doi.org/10.1007/978-3-319-24987-2_36
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DOI: https://doi.org/10.1007/978-3-319-24987-2_36
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