Abstract
The ESR method was used in a study of crystal phosphors activated with one element forming centers of different kinds. It was found that the trigonal Mn2+ centers in ZnS:Mn were characterized by |b0 2| = 117 Oe and appeared exclusively in the surface layer of a crystal after the diffusion of the activator at T ≥ 1100°C. The Eu2+ ions in ZnS:Eu formed trigonal and cubic centers and were responsible for characteristic luminescence bands. Strong optical and y-ray excitation of ruby caused exchange of electrons between the Cr3+ centers which resulted in the formation of the Cr2+ and Cr4+ centers. Crystals of Na2ZnGeO4: Mn exhibited two types of Mn2+ center, each of which occupied four equivalent positions differing in respect of the orientation of the axes, hi this case, the symmetry plane was (100).
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Arkhangel’skii, G.E. (1976). Nonisostructural Paramagnetic Centers in One-Activator Crystal Phosphors. In: Basov, N.G. (eds) Luminescence Centers in Crystals. The Lebedev Physics Institute Series, vol 79. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8884-5_3
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