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The Relevance of Spatial Variation in the Electromagnetic Vector Potential for Surface Raman Scattering

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Vibrations at Surfaces

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Abstract

The influence of the non-local optical properties of metal surfaces on the Raman scattering cross-section is discussed. The importance of considering the quadrupole term in the induced dipole moment is demonstrated. A new enhancement mechanism, based on the influence of the charge fluctuation in the chemisorption bond on the local phonon field, is proposed.

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Author information

Authors and Affiliations

  1. Fritz-Haber-Institut, Max-Planck-Gesellschaft, Faradayweg 4-6, D-1000, Berlin 33, Germany

    J. K. Sass & H. Neff

  2. Institut für Theoretische Physik, Freien Universität, Berlin Arnimallee,3, D-1000, Berlin 33, West Germany

    S. Holloway

  3. Lash Miller Chemical Laboratories and Erindale College, University of Toronto, Toronto, Ontario, M5S 1A1, Canada

    M. Moskovits

Authors
  1. J. K. Sass
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  2. H. Neff
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  3. S. Holloway
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  4. M. Moskovits
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Editor information

Editors and Affiliations

  1. Facultés Universitaires Notre-Dame de la Paix, Namur, Belgium

    R. Caudano , J.-M. Gilles  & A. A. Lucas ,  & 

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© 1982 Plenum Press, New York

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Sass, J.K., Neff, H., Holloway, S., Moskovits, M. (1982). The Relevance of Spatial Variation in the Electromagnetic Vector Potential for Surface Raman Scattering. In: Caudano, R., Gilles, JM., Lucas, A.A. (eds) Vibrations at Surfaces. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-4058-4_42

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  • DOI: https://doi.org/10.1007/978-1-4684-4058-4_42

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-4060-7

  • Online ISBN: 978-1-4684-4058-4

  • eBook Packages: Springer Book Archive

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