Skip to main content

Development of Calcium Phosphate Inhibitng Polymers for Cooling Water Applications

  • Chapter
Calcium Phosphates in Biological and Industrial Systems

Abstract

The precipitation and deposition of mineral scales on heat exchangers resulting from dissolved ions is a common problem in the use of water for industrial processes such as coooling, boiler, desalination, geothermal, secondary oil recovery utilizing water flooding techniques, and clothing washing machines. The scales consist primarily of phosphates, sulfates, carbonates, and silicates of alkaline earth metal, particularly calcium and magnesium. The insulating nature of scales on heat exchanger surfaces results in lost heat transfer efficiency and tube failures.1 The major cause of RO system failures is membrane fouling by mineral scales and suspended matter, which results from the accumulation of foulants on the surfaces of semipermeable membranes. The effects of fouling in RO system can lead to membrane replacement, loss in production, poor quality, and reduced quantity of produced water.2

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Water Formed Scale Deposits, Cowen, J. C. and Weintritt (Eds.), Gulf Publishing Company, Houston, Texas, 1976.

    Google Scholar 

  2. Reverse Osmosis: Membrane Technology, Water Chemistry, and Industrial Applications, Amjad, Z. (Ed.), Van Nostrand Reinhold, New York, NY, 1992.

    Google Scholar 

  3. Freedman L. Phosphate-Based Corrosion Inhibitors, Hercules Incorporated, Technical Report, Wilmington, Delaware, 1982

    Google Scholar 

  4. Zuhl R, Amjad Z, Masler W. A novel polymeric material for use in minimizing calcium phosphate fouling in industrial water systems, Cooling Tower Institute, 1987 Annual Meeting, Paper No. TP-87, Houston, Texas, 1987

    Google Scholar 

  5. Hoots JE and Crucil, GA. Role of polymers in the mechanisms and performance of alkaline cooling water programs, CORROSION/86, Paper No. 13, NACE, Houston, Texas, 1986

    Google Scholar 

  6. Fivizzani KP, Dubin L, Fair BE, Hoots JE. Managanese Stabilization by Polymers for Cooling Water Systems, CORROSION/89 Paper No. 433, NACE, Houston, Texas, 1989

    Google Scholar 

  7. Amjad Z, Pugh J, Zibrida J, Zuhl R. Polymer performance in cooling water: the influence of process variables, Materials Performance 1997;36:32–38

    Google Scholar 

  8. Smyk EB, Hoots JE, Fivizzani KP, Fulks KE. The design and application of polymers in cooling water programs, CORROSION/88, Paper No. 14, NACE, Houston, Texas, 1988

    Google Scholar 

  9. Fontana MG and Greene, NR Corrosion Engineering, McGraw Hill, New York, 1978

    Google Scholar 

  10. Amjad Z. Constant composition study of dicalcium phosphate dihydrate crystal growth in the presence of poly(acrylic acid), Langmuir, 1989;5:1222–1225

    Article  Google Scholar 

  11. Amjad Z. Performance of polymeric additives as hydroxyapatite crystal growth inhibitors, Phosphorous Research Bulletin, 1995;5:1–12

    Google Scholar 

  12. Amjad Z. Inhibition of Calcium Fluoride Crystal Growth by polyelectrolytes, Langmuir, 1991;7:2405–2408

    Article  Google Scholar 

  13. Amjad Z. Kinetics of crystal growth of calcium sulfate dihydrate: the influence of polymer composition, molecular weight, and solution pH, Can. J. Chem. 1988;66:1529

    Article  Google Scholar 

  14. Amjad, Z. Inhibition of barium sulfate precipitation: effects of additives, solution pH, and supersaturation, Water Treatment, 1994;9:47–56

    Google Scholar 

  15. Amjad Z and Masler W. The inhibition of calcium sulfate dihydrate crystal growth by polyacrylates and the Influence of Molecular Weight, CORROSION/85, Paper No. 357, NACE, Houston, TX 1985

    Google Scholar 

  16. Amjad Z. Calcium sulfate dihydrate (gypsum) scale formation on heat exchanger surfaces: the influence of scale inhibitors, J. Colloid Interface Sci. 1988;123:523–536

    Article  Google Scholar 

  17. Amjad Z. Effect of precipitation inhibitors on calcium phosphate scale formation, Can J of Chem 1988;67:850–856

    Article  Google Scholar 

  18. Amjad Z. Performance of polymers as precipitation inhibitors for calcium phosphonate, Tenside, 1997, 2:102–107

    Google Scholar 

  19. Williams FV and Ruehrwein RA. Effect of polyelectrolytes on the precipitation of calcium carbonate, J Amer Chem Soc 1957;79:4898–4900

    Article  Google Scholar 

  20. Wilson D. Influence of Molecular Weight on Selection and Application of Polymeric Scale Inhibitors, CORROSION/94, Paper No. 48, NACE International, Houston, TX 1994

    Google Scholar 

  21. Howie-Meyers CL, Yu K, Elliott D, Vasudevan T, Aronson MP, Ananthapadamanabhan KP, Somasundaran P. “Crystal Growth Inhibition of Hydroxyapatite by Polycarboxylates: Role of Calcium and Polymer Molecular Weight”. In: Mineral Scale Formation and Inhibition, Amjad, Z. Ed., Plenum Publishing Corporation, New York, NY 1995.

    Google Scholar 

  22. Hahn WM and Robertson ST. Control of iron and silica with polymeric dispersants, Paper No. IWC-90–29, Fifty-First Annual Meeting, International Water Conference, Pittsburgh, PA 1990

    Google Scholar 

  23. Hogue RD. Sensitivity of the DequestR phosphonates to elevated levels of calcium, Report No. 8433, Monsanto Company, September 13,1976

    Google Scholar 

  24. Browning FH and Fogler AS. Effect of precipitation conditions on the formation of calcium-HEDP precipitates, Langmuir 1996;12:5231–5238

    Article  Google Scholar 

  25. Masler WF and Amjad Z. Advances in the control of calcium phosphonate with a novel polymeric inhibitor, CORROSION/88, Paper No. 11, NACE, Houston, TX 1988

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1998 Springer Science+Business Media New York

About this chapter

Cite this chapter

Amjad, Z. (1998). Development of Calcium Phosphate Inhibitng Polymers for Cooling Water Applications. In: Amjad, Z. (eds) Calcium Phosphates in Biological and Industrial Systems. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-5517-9_16

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-5517-9_16

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-7521-0

  • Online ISBN: 978-1-4615-5517-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics