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Effect of Pore Size Distribution on the Prediction of Multicomponent Adsorption Equilibria

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Part of the book series: The Kluwer International Series in Engineering and Computer Science ((SECS,volume 356))

Abstract

A heterogeneous multicomponent adsorption isotherm model is proposed to describe the adsorption equilibrium of gases in activated carbon. This model uses a micropore size distribution concept to explain the system heterogeneity. The pore size is related to the adsorbate-adsorbent interaction energy by the Lennard-Jones potential [1]. The size exclusion effect is taken into account in the competition of different species for a given pore. The isotherm parameters extracted from single-component data fitting are used to predict the binary and ternary adsorption equilibrium. The model predictions are tested with the experimental data available in the literature [2].

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References

  1. Everett, D. H. and Powl, J. C., J. Chem. Soc. Faraday Trans. I. 72, 619–636 (1976).

    Article  CAS  Google Scholar 

  2. Reich, R., Ziegler, W. T. and Rogers, K. A., Ind. Eng. Chem. Process Des. Dev., 19, 336–344 (1980).

    Article  CAS  Google Scholar 

  3. Ross, S. and Olivier, J. P., J. Phys. Chem., 65, 608–615 (1961).

    Article  CAS  Google Scholar 

  4. Valenzuela, D.P., Myers, A.L., Talu, O. and Zwiebel, I., AIChE J., 34, 397–402 (1988).

    Article  CAS  Google Scholar 

  5. Jagiello, J. and Schwarz, J. A., J. Colloid Interface Sci., 154, 225–237 (1992).

    Article  CAS  Google Scholar 

  6. Jagiello, J. and Schwarz, J. A., Langmuir, 9, 2513–2517 (1993).

    Article  CAS  Google Scholar 

  7. Kapoor, A., Ritter, J. A. and Yang, R. T., Langmuir, 6, 660–664 (1990).

    Article  CAS  Google Scholar 

  8. Hu, X. and Do, D. D., Langmuir; 9, 2530–2536 (1993).

    Article  CAS  Google Scholar 

  9. IMSL Library, version 1.1 1989.

    Google Scholar 

  10. Reid, R. C, Prausnitz, J. M. and Polling, B. E., The Properties of Gases and Liquids, 4th ed, McGraw-Hill, New York, 1987.

    Google Scholar 

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© 1996 Kluwer Academic Publishers

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Hu, X., Do, D.D. (1996). Effect of Pore Size Distribution on the Prediction of Multicomponent Adsorption Equilibria. In: LeVan, M.D. (eds) Fundamentals of Adsorption. The Kluwer International Series in Engineering and Computer Science, vol 356. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1375-5_48

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  • DOI: https://doi.org/10.1007/978-1-4613-1375-5_48

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8594-6

  • Online ISBN: 978-1-4613-1375-5

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