Abstract
The control and modification of reactivity through incorporation of molecules into organized assemblies remains an area of considerable interest. A specific subarea that has attracted recent interest concerns reactivity of molecules incorporated into host-guest systems. In this context, we have investigated the photochemical behavior of a large number of organic molecules in micellar and cyclodextrin media. The photochemical Norrish type I and type II reactions of cyclodextrin and micellar bound benzoin alkyl ethers have been explored. The irradiation in micellar and cyclodextrin media leads to a large change in product distribution from that found in benzene and methanol. Conformational and cage effects have been proposed to be responsible for the dramatic alteration in the photobehavior.
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© 1989 Plenum Press, New York
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Devanathan, S., Reddy, G.D., Ramamurthy, V. (1989). Modification of Photochemical Reactivity By Incorporation of Reactants into Hydrophobic Pockets and Cavities: Conformational and Cage Effects. In: Mittal, K.L. (eds) Surfactants in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0839-3_13
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DOI: https://doi.org/10.1007/978-1-4613-0839-3_13
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