Abstract
This review describes the photophysics and photochemistry of various diimine rhenium(I) tricarbonyl complexes. The exceptionally diverse photophysical behavior of these complexes is largely dependent on the nature of their lowest excited states. These excited states and the excited-state characteristics can be easily changed by varying the substituents on either the diimine ligands or the ancillary ligands. The prolificacy of the photophysical and photochemical properties of diimine rhenium(I) tricarbonyl complexes allows for a range of important applications such as light-emitting devices, sensors, probes for photo-polymerization, optical switches, nonlinear optical materials, radiopharmaceuticals, carbon dioxide reduction and supramolecular chemistry. We have covered the studies that best characterize the state of the field as far as the most significant fundamental photochemical advances, and the applications of the photochemistry of rhenium complexes.
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References
Holten D, Bocian DF, Lindsey JS (2002) Acc Chem Res 35:57
Remacle F, Levine RD (2001) J Phys Chem B 105:2153
Yeow EKL, Steer RP (2003) Phys Chem Chem Phys 5:97
Yeow EKL, Steer RP (2003) Chem Phys Lett 377:391
Geoffroy GL, Wrighton MS (1979) Organometallic photochemistry. Academic, New York
Wrighton M, Morse DL (1974) J Am Chem Soc 96:998
Lees AJ (1987) Chem Rev 87:711
Lees AJ , Sun SS in McCleverty JA , Meyer TJ (Eds) (2004) Comprehensive coordination chemistry II , Vol 2. Elsevier , Oxford, UK , p 731
Kirgan RA, Sullivan BP, Rillema DP in Balzani V, Campagna S (Eds) (2007) Top Curr Chem 281:45
Lees AJ (1995) Comments Inorg Chem 17:319
Chen P, Meyer TJ (1998) Chem Rev 98:1439
Stufkens DJ (1992) Comments Inorg Chem 13:359
Vogler A, Kunkely H (2000) Coord Chem Rev 200–202:991
Balzani V, Juris A, Venturi M, Campagna S, Serroni S (1996) Chem Rev 96:759
Schanze KS, Walters KA (2000) Photoinduced electron transfer in metal-organic dyads. In: Ramamurthy V, Schanze KS (Eds) Organic and Inorganic Photochemistry. Molecular and Supramolecular Photochemistry Series, Vol 2, Chap 3. Marcel Dekker, New York, p 75
Schanze KS, MacQueen DB, Perkins TA, Cabana LA (1993) Coord Chem Rev 122:63
Worl LA, Duesing R, Chen P, Della Ciana L, Meyer TJ (1991) J Chem Soc Dalton Trans:849
Stufkens DJ, Vlček A Jr (1998) Coord Chem Rev 177:127
Kalyanasundaram K (1992) Photochemistry of polypyridine and porphyrin complexes, Chap 10. Academic, New York, p 321
Caspar JV, Meyer TJ (1983) J Phys Chem 87:952
Takeda H, Koike K, Inoue H, Ishitani O (2008) J Am Chem Soc 130:2023
Abdel-Shafi AA, Bourdelande JL, Ali SS (2007) Dalton Trans:2510
Belliston-Bittner W, Dunn AR, Nguyen YHL, Stuehr DJ, Winkler JR, Gray HB (2005) J Am Chem Soc 127:15907
Hayashi Y, Kita S, Brunschwig BS, Fujita E (2003) J Am Chem Soc 125:11976
Hwang J-S, Chang J-S, Park S-F, Ikeue K, Anpo M (2005) Top Cat 35:311
Kumar A, Sun SS, Lees AJ (2008) Coord Chem Rev 252:922
Sun SS, Less AJ (2002) Coord Chem Rev 230:171
Sun SS, Lees AJ (2000) Chem Commun:1687
Mizuno T, Fukumatsu T, Takeuchi M, Shinkai S (2000) J Chem Soc Perkin Trans 1:407
Keefe MH, Sloan RV, Hupp JT, Czaplewski KF, Snurr RQ, Stern CL (2000) Langmuir 16:3964
Bakir M, McKenzie JAM (1997) J Chem Soc Dalton Trans:3571
De Silva AP, Gunaratne HQN, Gunnlaugsson T, Huxley AJM, McCoy CP, Rademacher JT, Rice TE (1997) Chem Rev 97:1515
Demas JN, DeGraff BA (1991) Anal Chem 63:A829
Lees AJ (1998) Coord Chem Rev 177:3
Lees AJ (2001) Luminescent metal complexes as spectroscopic probes of monomer/polymer environments. In: Ramamurthy V, Schanze KS (Eds) Optical Sensors and Switches. Molecular and Supramolecular Photochemistry Series, Vol 7, Chap 5. Marcel Dekker, New York, p 209
Sun SS, Lees AJ (2002) Organometallics 21:39
Polo AS, Itokazu MK, Frin KM, Patrocnio AOT, Iha NYM (2006) Coord Chem Rev 250:1669
Argazzi R, Bertolasi E, Chiorboli C, Bignozzi CA, Itokazu MK, Iha NYM (2001) Inorg Chem 40:6885
Lewis JD, Perutz RN, Moore JN (2000) J Chem Soc Chem Commun:1865
Sun SS, Robson E, Dunwoody N, Silva AS, Brinn IM, Lees AJ (2000) J Chem Soc Chem Commun:201
Fernandez-Acebes A, Lehn JM (1999) Chem Eur J 5:3285
Yam VWW, Lau VCY, Wu LX (1998) J Chem Soc Dalton Trans:1461
Schanze KS, Lucia LA, Cooper M, Walters KA, Ji HF, Sabina O (1998) J Phys Chem A 102:5577
Beyeler A, Belser P, De Cola L (1997) Angew Chem Int Ed Engl 36:2779
Yam VWW, Lau VCY, Cheung KK (1995) J Chem Soc Chem Commun:259
Lundin NJ, Blackman AG, Gordon KC, Officer DL (2006) Angew Chem Int Ed 45:2582
Li X Zhang D, Li W, Chu B, Han l, Zhu J, Su Z, Bi D, Wang D, Yang D, Chen Y (2008) Appl Phys Lett 92:083302
Liu C, Li J, Li B, Hong Z, Zhao F, Liu S, Li W (2006) Appl Phys Lett 89:243511
Si z, Li J, Li B, Zhao F, Liu S, Li W (2007) Inorg Chem 46:6155
Ranjan S, Lin S-Y, Hwang K-C, Chi Y, Ching W-L, Liu C-S (2003)Inorg Chem 42:1248
Zhang Y, Huang z, Zeng W, Cao Y (2008) Polymer 49:1211
Lee P-I, Hsu SL-C, Chung C-T (2006) Synth Metals 156:907
Zhang J, Chu BW-K, Zhu N, Yam VW-W (2007) Organometallics 26:5423
Yam VWW, Yang Y, Yang HP, Cheung KK (1999) Organometallics 18:5252
Briel O, Sunkel K, Krossing I, Noth H, Schmalzlin E, Meerholz K, Brauchle C, Beck W (1999) Eur J Inorg Chem:483
Bourgault M, Baum K, Le Bozec H, Pucetti G, Ledoux I, Zyss J (1998) New J Chem:517
Victor RF, Correia I, Videira M, Marques F, Paulo A, Pessoa JC, Viola G, Martins GG, Santos I (2008)Chem Bio Chem 9:131
Ma D-L, Che C-M, Siu F-M, Yang M, Wong K-Y (2007) Inorg Chem 46:740
Ruiz GT, Juliarena MP, Lezna RO, Wolcan E, Feliz MR, Ferraudi G (2007) J Chem Soc Dalton Trans:2020
Reece SY, Nocera DG (2005) J Am Chem Soc 127:9448
Stoeffler HD, Thornton NB, Temkin SL, Schanze KS (1995) J Am Chem Soc 117:7119
Fuks L, Gniazdowska E, Meiczkowski J, Sadlej-Sosnowska N (2008) Polyhedron 27:1353
Tzanopoulou S, Pirmettis IC, Patsis G, Paaravatou-Petsotas M, Livaniou E, Papadopoulos M, Pelecanou M (2006) J Med Chem 49:5408
Dunn AR, Belliston-Bittner W, Winkler JR, Getzoff ED, Stuehr DJ, Gray HB (2005) J Am Chem Soc 127:5169
Zhang J, Vittal JJ, Henderson W, Wheaton JR, Hall IH, Hor TSA, Yan YK (2002) J Organomet Chem 650:123
Pietzsch H-J, Gupta A, Reisgys M, Drews A, Seifert S, Syhre R, Spies H, Alberto R, Abram U, Schubiger PA, Johannsen B (2000) Bioconjugate Chem 11:414
Stoyanov SR, Villegas JM, Cruz AJ, Lockyear LL, Reibenspies JH, Rillema DP (2005) J Chem Theory Comput 1:95
Villegas JM, Stoyanov SR, Huang W, Rillema DP (2005) Inorg Chem 44:2297
Villegas JM, Stoyanov SR, Huang W, Rillema DP (2005) Dalton Trans:1042
Gabrielsson A, Busby M, Matousek P, Towrie M, Hevia E, Cuesta L, Perez J, Zális S, Vlček A Jr (2006) Inorg Chem 45:9789
Kirgen R, Simpson M, Moore C, Day J, Bui L, Tanner C, Rillema DP (2007) Inorg Chem 46:6464
Zhao G-J, Zhou X, Liu T, Zheng Q-C, Bai F-Q, Zhang H-X (2008) J Mol Struct Theochem 855:52
Machura B, Kruszynski R (2007) J Organomet Chem 692:4161
Baiano JA, Kessler RJ, Lumpkin RS, Munley MJ, Murphy WR Jr (1995) J Phys Chem 99:17680
Hino JK, Della Ciana L, Dressick WJ, Sullivan BP (1992) Inorg Chem 31:1072
Kalyanasundaram K (1986) J Chem Soc Faraday Trans 2 82:2401
Schoonover JR, Strouse GF (1998) Chem Rev 98:1335
Schoonover JR, Bignozzi CA, Meyer TJ (1997) Coord Chem Rev 165:239
Schoonover JR, Strouse GF, Dyer RB, Bates WD, Chen P, Meyer TJ (1996) Inorg Chem 35:273
George MW, Johnson FPA, Westwell JR, Hodges PM, Turner JJ (1993) J Chem Soc Dalton Trans:2977
Walters KA, Dattelbaum DM, Ley KD, Schoonover JR, Meyer TJ, Schanze KS (2001) J Chem Soc Chem Commun:1834
Schoonover JR, Chen P, Bates WD, Dyer RB, Meyer TJ (1994) Inorg Chem 33:793
Chen P, Curry M, Meyer TJ (1989) Inorg Chem 28:2271
Shaver RJ, Perkovic MW, Rillema DP, Woods C (1995) Inorg Chem 34:5446
Katz NE, Mecklenburg SL, Graff DK, Chen P, Meyer TJ (1994) J Phys Chem 98:8959
Chen P, Westmoreland TD, Danielson E, Schanze KS, Anthon D, Neveux PE Jr, Meyer TJ (1987) Inorg Chem 26:1116
Chen P, Duesing R, Graff DK, Meyer TJ (1991) J Phys Chem 95:5850
Schoonover JR, Strouse GF, Chen P, Bates WD, Meyer TJ (1993) Inorg Chem 32:2618
Vlček A Jr , Busby M (2006) Coord Chem Rev 250:1755
Wang Y, Schanze KS (1996) J Phys Chem 100:5408
Trammell S, Goodson PA, Sullivan BP (1996) Inorg Chem 35:1421
Wang Y, Lucia LA, Schanze KS (1995) J Phys Chem 99:1961
Lucia LA, Wang Y, Nafisi K, Netzel TL, Schanze KS (1995) J Phys Chem 99:11801
Wang Y, Schanze KS (1993) Chem Phys 176:305
Wang Y, Hauser BT, Rooney MM, Burton RD, Schanze KS (1993) J Am Chem Soc 115:5675
Rossenaar BD, Stufkens DJ, Vlcek A Jr (1996) Inorg Chem 35:2902
Giordano PJ, Fredericks SM, Wrighton MS, Morse DL (1978) J Am Chem Soc 100:2257
Wallace L, Rillema DP (1993) Inorg Chem 32:3836
Wallace L, Jackman DC, Rillema DP, Merkert JW (1995) Inorg Chem 34:5210
Leasure RM, Sacksteder L, Nesselrodt D, Reitz GA, Demas JN, DeGraff BA (1991) Inorg Chem 30:3722
Del Guerzo AD, Leroy S, Fages F, Schmehl RH (2002) Inorg Chem 41:359
Ziessel R, Juris A, Venturi M (1998) Inorg Chem 37:5061
Baba AI, Shaw JR, Simon JA, Thummel RP, Schmehl RH (1998) Coord Chem Rev 171:43
Schoonover JR, Bates WD, Meyer TJ (1995) Inorg Chem 34:6421
Vlcek A Jr (1998) Coord Chem Rev 177:219
Koike K, Okoshi N, Hori H, Takeuchi K, Ishitani O, Clark IP, George MW, Johnson FPA, Turner JJ (2002) J Am Chem Soc 124:11448
Koike K, Tanabe J, Toyama S, Tsubaki H, Sakamoto K, Westwell JR, Johnson FPA, Hori H, Saitoh H, Ishitani O (2000) Inorg Chem 39:2777
Hightower SE, Corcoran RC, Sullivan BP (2005) Inorg Chem 44:9601
Sato S, Sekine A, Ohashi Y, Ishitani O, Blanco-Rodriguez AM, Vlček A Jr, Unno T, Koike K (2007) Inorg Chem 46:3531
Del Negro AS, Woessner SM, Sullivan BP, Dattelbaum DM, Schoonover JR (2001) Inorg Chem 40:5056
Rossenaar BD, Kleverlaan CJ, Stifkens DJ, Sskam A (1994) J Chem Soc Chem Commun:63
Gabrielsson A, Blanco-Rodríguez AM, Matousek P, Towrie M, Vlček A Jr (2006) Organometallics 25:2148
Wenger OS, Henling LM, Day MW, Winkler JR, Gray HB (2004) Inorg Chem 43:2043
Yam VW-W, Yang Y, Zhang J, Chu BW-K, Zhu N (2001) Organometallics 20:4911
Busby M, Matousek P, Towrie M, Vlček A Jr (2007) Inorganica Chimica Acta 360:885
Lewis JD, Perutz RN, Moore JN (2004) J Phys Chem A 108:9037
Yam VW-W, Ko C-C, Wu L-X, Wong KM-C, Cheung K-K (2000) Organometallics 19:1820
Ko C-C, Wu L-X, Wong KM-C, Zhu N, Yam VW-W (2004) Chem Eur J 10:766
Lee PH-M, Ko C-C, Zhu N, Yam VW-W, (2007) J Am Chem Soc 129:6058
Ko C-C, Kwok W-M, Yam VW-W, Phillips DL (2006) Chem Eur J 12:5840
Yam VW-W, Ko C-C, Zhu N (2004) J Am Chem Soc 126:12734
Manimaran B, Thanasekaren P, Rajendran T, Lin R-J, Chang I-J,Lee G-H, Peng S-M, Rajagopal S, Lu K-L (2002) Inorg Chem 41:5323
Woessner SM, Helms JB, Shen Y, Sullivan BP (1998) Inorg Chem 37:5406
Thanasekaren P, Liao R-T, Manimaran B, Liu Y-H, Chou P-T, Rajagopal S, Lu K-L (2006) J Phys Chem A 110:10683
Rajendran T, Manimaran B, Liao R-T, Lin R-J, Thanasekaran P, Lee G-H, Peng S-M, Liu Y-H, Chang I-J, Rajgopal S, Lu K-L (2003) Inorg Chem 42:6388
Sun S-S, Lees AJ (2000) J Am Chem Soc 122:8956
Sun S-S, Lees AJ (1999) Inorg Chem 38:4181
Slone RV, Hupp JT, Stern CL, Albrecht-Schmitt TE (1996) Inorg Chem 35:4096
Lee SJ, Lin W, (2002) J Am Chem Soc 124:4554
Benkstein KD, Hupp JT, Stern CL (1998) J Am Chem Soc 120:12982
Vogler A, Kisslinger J (1986) Inorg Chim Acta 115:193
Benkstein KD, Hupp JT, Stern CL (2002) Angew Chemie Int Ed Eng 39:2891
Benkstein KD, Stern CL, Splan KE, Johnson RC, Walters KA, Vanhelmont FWM, Hupp JT (2002)Eur J Inorg Chem :2818
Slone RV, Yoon DI, Calhoun RM, Hupp JT (1995) J Am Chem Soc 117:11813
Sun S-S, Anspach JA, Lees AJ (2002) Inorg Chem 41:1862
Sathiyendiran M, Liao R-T, Thanasekaran P, Luo T-T, Venkataramanan NS, Lee G-H, Peng S-M, Lu K-L (2006) Inorg Chem 45:10052
Slone RV, Hupp JT (1997) Inorg Chem 36:5422
Sun S-S, Lees AJ (2001) Inorg Chem 40:3154
Splan KE, Massari AM, Morris GA, Sun S-S, Reina E, Nguyen ST, Hupp JT (2003) Eur J Inorg Chem :2348
Kumar A, Sun S-S, Lees AJ (2008) Coord Chem Rev 252:922
de Wolf P, Heath S, Thomas J (2002) J Chem Soc Chem Commun:2540
Sun S-S, Lees AJ (2001) Chem Commun:103
Manimaran B, Rajendran T, Lu Y-L, Lee G-H, Peng S-M, Lu K-L (2001) Eur J Inorg Chem:633
Amendola V, Bacchilega D, Costa I, Gianelli L, Montalti M, Pallavicini P, Perotti A, Prodi L, Zaccheroni N (2003) J Photochem Photobiol A: Chem 159:249
Lam MHW, Lee DYK, Man KW, Lau CSW (2000) J Mater Chem 10:1825
Cattaneo M, Fagalde F, Katz NE (2006) Inorg Chem 45:6884
Beer PD, Timoshenko V, Maestri M, Passaniti P, Balzani V (1999) J Chem Soc Chem Commun:1755
Sun S-S, Lees AJ, Zavalij PY (2003) Inorg Chem 42:3445
Pelleteret D, Fletcher NC, Doherty AP (2007) Inorg Chem 46:4386
Li, M-J, Ko C-C, Duan G-P, Zhu N, Yam VW-W (2007) Organometallics 26:6091
Lo KK-W, Hui W-K (2005) Inorg Chem 44:1992
Lo KK-W, Hui W-K (2002) J Am Chem Soc 124:9344
Lo KK-W, Hui W-K, Chung C-K, Tsang KH-K, Lee TK-M, Li C-K, Lau JS-Y, Ng DC-M (2006) Coord Chem Rev 250:1724
Grubber, HJ Kada HG, Riener CK, Harms GS, Ahrer W, Dax TG, Knaus HG, (2000) Bioconjugate Chem 11:696
Lin T-P, Chen C-Y, Wen Y-S, Sun S-S (2007) Inorg Chem 46:9201
Wang K, Huang L, Gao L, Jin L, Huang C (2002) Inorg Chem 41:3353
Yam VW-W, Li B, Yang Y, Chu BW-K, Wong KM-C, Cheung K-K (2003) Eur J Inorg Chem:4035
Dinolfo, PH Coropceanu V, Bredas J-L, Hupp JT, (2006) J Am Chem Soc 128:12592
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Kumar, A., Sun, SS., Lees, A.J. (2009). Photophysics and Photochemistry of Organometallic Rhenium Diimine Complexes. In: Lees, A. (eds) Photophysics of Organometallics. Topics in Organometallic Chemistry, vol 29. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3418_2009_2
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