Abstract
The most fundamental structure involved in molecular electronics is a molecular transport junction, consisting of one (ideally) or more molecules extending between two electrodes. These junctions combine the fundamental process of intramolecular electron transfer with the mixing of molecular and continuum levels at the electrodes and the nonequilibrium process of voltage-driven currents. Much of this book is devoted to the complicated but significant behaviors that arise from this conjunction. This introductory chapter attempts to sketch some of the principles and also some of the unresolved issues that characterize molecular transport junctions.
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Jortner, J., Nitzan, A., Ratner, M.A. (2006). Foundations of Molecular Electronics – Charge Transport in Molecular Conduction Junctions. In: Cuniberti, G., Richter, K., Fagas, G. (eds) Introducing Molecular Electronics. Lecture Notes in Physics, vol 680. Springer, Berlin, Heidelberg . https://doi.org/10.1007/3-540-31514-4_2
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