Conclusion
Morphology-dependent resonances are found in other structures of high symmetry,(48) and so their possible existence in biological systems should not be ignored. The presence of such resonances should alter the rates of decay of excited species. A considerable amount of work remains to be done on investigating the optical properties of small, regularly shaped objects. Continuing studies of fluorescence from such systems may lead to improved probes of the microscopic environment of molecules, remote sensing techniques, and surface probes to investigate both solid and liquid surfaces. The study of interactions higher intensity is almost sure to produce a host of interesting effects. The work described in this chapter will hopefully introduce a reader to the field, and we have endeavored to make the citations as current as possible in order to allow the interested reader to follow subsequent developments.
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References
R. E. Benner, P. W. Barber, J. F. Owen, and R. K. Chang, Observation of structure resonances in the fluorescence of microspheres, Phys. Rev. Lett. 44, 475–478 (1980).
L. M. Folan, S. Arnold, and S. D. Druger, Enhanced energy transfer within a microparticle, Chem. Phys. Lett. 118, 322–327 (1985).
S. Arnold and L. M. Folan, Fluorescencespectrometer for a single electrodynamically levitated microparticle, Rev. Sci. Instrum 57, 2250–2253 (1986).
L. M. Folan and S. Arnold, Determination of molecular orientation at the surface of an aerosol particle by morphology-dependent photoselection, Opt. Lett. 13, 1–3 (1988).
D. Axelrod, Carbocyanine dye orientation in red cell membrane studied by microscopic fluorescence polarization, Biophys. J. 26, 557–573 (1979).
P. R. Conwell, C. K. Rushforth, R. E. Benner, and S. C. Hill, Efficient automated algorithm for the sizing of dielectric microspheres using the resonance spectrum, J. Opt. Soc. Am. A 1, 1181–1187 (1984).
G. Mie, Contributions to the optics of turbid media,especiallycolloidalsuspensions of metals, Ann. Physik 25, 377–445 (1908).
C. F. Bohren and D. R. Huffman, Absorption and Scattering of Light by Small Particles, Chapter 4, Wiley Interscience, New York (1983).
B.J. Messinger, K. Ulrich von Raben, R. K. Chang, and P. W. Barber, Local fields at the surface of noble-metal microspheres, Phys. Rev. B 24, 649–657 (1981).
N. L. Thompson, H. M. McConnell, and Thomas P. Burghardt, Order in supported phospholipid monolayers detected by dichroism or fluorescence excited with polarized evanescent illumination, Biophys. J. 46, 739–747 (1984).
S. Earnshaw, On the nature of the molecular forces which regulate the constitution of the luminiferious ether, Trans. Cambridge Phil. Soc. 7, 97–112 (1842).
S. Arnold, Spectroscopy of single levitated micron sized particles, in: Optical Effects Associated with Small Particles (P. W. Barber and R. K. Chang, eds.), World Scientific, New York (1988).
W. Nauhauser, M. Hohenstatt, P. Toschek, and H. Dehmelt, Localized visible Ba+ monoion oscillator, Phys. Rev. A 22, 1137 (1980).
S. Arnold and N. Hessel, Photoemission from single electrodynamically levitated micro-particles, Rev. Sci. Instrum. 56, 2066–2069 (1985).
A. Ashkin, J. M. Dziedzic, J. E. Bjorkholm, and S. Chu, Observation of a single-beam gradient force optical trap for dielectric particles, Opt. Lett. 11, 288–290 (1986).
A. Ashkin and J. M. Dziedzic, Optical trapping and manipulation of viruses and bacteria, Science 235, 1517–1520 (1987).
T. N. Buican, M. J. Smyth, H. A. Crissman, G. C. Salzman, C. C. Stewart, and J. C. Martin, Automated single-cell manipulation and sorting by light trapping, Appl. Opt. 26, 5311–5316 (1987).
S. Arnold and L. M. Folan, Spherical void electrodynamical levitator, Rev. Sci. Instrum. 58, 1732–1735 (1987).
E. L. Kyser, L. F. Collins, and N. Herbert, Design of an impulse ink jet, J. Appl. Photogr. Eng. 7, 73–79 (1981).
P. Chylek, V. Ramaswamy, A. Ashkin, and J. M. Dziedzic, Simultaneous determination of refractive index and size of spherical dielectric particles from light scattering data, Appl. Opt. 22, 2302–2307 (1983).
A. Ruaudel-Teixier and M. Vandevyver, Energy transfer in dye monomolecular layers, Thin Solid Films 68, 129–133 (1980).
J. I. Gersten and A. Nitzan. Spectroscopic properties of molecules interacting with small dielectric particles, J. Chem. Phys. 75, 1139–1152 (1981).
J. I. Gersten and A. Nitzan, Accelerated energy transfer between molecules near a solid particle, Chem. Phys. Lett. 104, 31–37 (1984).
X. M. Hua, J. I. Gersten, and A. Nitzan, Theory of energy transfer between molecules near solid state particles, J. Chem. Phys. 83, 3650–3659 (1985).
M. Kerker, D.-S. Wang, and H. Chew, Surface enhanced Raman scattering (SERS) by molecules absorbed at spherical particles: errata, Appl. Opt. 19, 4159–4174 (1980).
P. J. McNulty, H. Chew, and M. Kerker, in: Aerosol Microphysics I W. H. Marlow, ed.), Chapter 4, Springer-Verlag, New York (1980).
R. Ruppin, Decay of an excited molecule near a small metal sphere, J.Chem.Phys. 6, 1681–1684 (1982).
H. Chew, Transition rates of atoms near spherical surfaces, J. Chem. Phys. 87, 1355–1360 (1987).
S. D. Druger and P. J. McNulty, Radiation pattern of fluorescence from molecules embedded in small particles: General case, Appl. Opt. 22, 75–82 (1983).
S. D. Druger, S. Arnold, and L. M. Folan, Theory of enhanced energy transfer between molecules embedded in spherical dielectric particles, J. Chem. Phys. 87, 2649–2659 (1987).
R. R. Chance, A. Prock, and R. Silby, Molecular fluorescence and energy transfer near surfaces, in: Advances in Chemical Physics, Vol. XXXVII I. Prigogine and S. A. Rice, eds.), pp. 1–65, Wiley, New York (1978).
D. A. Weitz, S. Garoff, C. D. Hanson, T. J. Gramila, and J. I. Gersten, Fluorescent lifetimes of molecules on silver island films, Opt. Lett. 7, 89 (1982).
H. M. Lai, P. T. Leung, and K. Young, Electromagnetic decay rates into narrow resonances in an optical cavity, Phys. Rev. A 37, 1597 (1988).
H.-M. Tzeng K. F. Wall, M. B. Long, and R. K. Chang, Laser emission from individual droplets at wavelengths corresponding to morphology-dependent resonances Opt. Lett. 9, 499–501 (1984).
J. B. Snow, S.-X. Qian, and R. K. Chang, Stimulated Raman scattering from individual water and ethanol droplets at morphology-dependent resonances, Opt. Lett. 10, 37–39 (1985).
S.-X. Qian, J. B. Snow, and R. K. Chang, Coherent Raman mixing and coherent anti-Stokes Raman scattering from individual micrometer-sized droplets, Opt. Lett. 10, 499–501 (1985).
S. Arnold, K. M. Leung, and A. B. Pluchino, Optical bistability of an aerosol particle, Opt. Lett. 11, 800–802 (1986).
J. R. Lakowicz, private communication.
H. Chew and D.-S. Wang, Double resonance in fluorescent and Raman scattering by molecules in small particles, Phys. Rev. Lett. 49, 490–492 (1982).
T. Förster, Intermolecular energy transfer and fluorescence, Ann. Physik. 2, 55–75 (1948).
L. Dexter, Atheory of sensitized luminescence insolids J.Chem.Phys. 21, 836–850 (1953).
J. Perrin, Fluorescence andmolecularinduction byresonance, C. R.Acad. Sci. 184, 1097–1100 (1927).
V. M. Agranovich and M. D. Galanin, Electronic Excitation Energy Transferin Condensed Matter Chapter 2, North-Holland, New York (1982).
J. B. Birks, Photophysics of Aromatic Molecules, pp. 567–576, Wiley, London (1970).
L. Stryer and R. P. Haugland, Energy transfer: a spectroscopic ruler, Proc. Natl. Acad. Sci. U.S.A. 58, 719–726 (1967).
J. R. Lakowicz, Principles of Fluorescence Spectroscopy, Chapter 10, Plenum, New York (1983).
J.-Z. Zhang, D. H. Leach, and R. K. Chang, Photon lifetime with in a droplet: Temporal determination of elastic and stimulated Raman scattering, Opt. Lett. 13, 270–272 (1988).
P. W. Barber, J. F. Owen, and R. K. Chang, Resonant scattering for characterization of axisymmetric dielectric objects, IEEE Trans. Antennas Propagation, AP-30, 168–172 (1982).
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Folan, L.M., Arnold, S. (2002). Microparticle Fluorescence and Energy Transfer. In: Lakowicz, J.R. (eds) Topics in Fluorescence Spectroscopy. Topics in Fluorescence Spectroscopy, vol 3. Springer, Boston, MA. https://doi.org/10.1007/0-306-47059-4_8
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