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Influence of Preparation Method on SOP Modes in ZnO Doped with CoO Nanoparticles

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Abstract

The aim of the present work is to study influence of preparation method on samples characteristics, creation and behavior of surface optical phonons (SOP) modes with change of concentration of doping elements by micro Raman spectroscopy. Nanocrystalline samples of ZnO(Co) were prepared by use of traditional wet chemistry method followed by calcinations and the microwave assisted hydrothermal synthesis. The phase composition of the samples (ZnO, Co3O4, ZnCo2O4) and the mean crystalline size (14–300 nm) were determined using X-ray diffraction measurements. In this paper we report the experimental spectra of Raman scattering (from 100 to 1600 cm−1) for both type of samples. Main characteristic of experimental Raman spectrum are: sharp peak at 436 cm−1 and broad multi phonon structure at ~1150 cm−1, typical for ZnO; sharp peaks at 194, 482, 521, 618 and 691 cm−1 typical for Co3O4 and sharp peaks at 185, 475, 520, 610 and 690 cm−1 typical for ZnCo2O4 nanoparticles. The phonon of registered phase’s exhibit effects connected to phase concentration, while the SOP phonon mode exhibit significant confinement effect.

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Acknowledgments

This work was supported under Agreement of Scientific Collaboration between Polish Academy of Science and Serbian Academy of Sciences and Arts. The work in Serbia was supported by Serbian Ministry of Education, Science and Technological Development (Project 45003) and in Poland by National Science Center granted under decision No. DEC-2011/01/B/ST5/06602.

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Authors and Affiliations

  1. Institute of Physics, University of Belgrade, Belgrade, Serbia

    B. Hadžić, M. Romčević, J. Trajić, G. Stanišić & D. Timotijević

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  1. B. Hadžić
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  2. M. Romčević
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  3. J. Trajić
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  4. G. Stanišić
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  5. D. Timotijević
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Correspondence to B. Hadžić .

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Editors and Affiliations

  1. Department of Materials, Faculty of Engg, Imperial College London Department of Materials, Faculty of Engg, London, United Kingdom

    Bill Lee

  2. University of Stuttgart , Stuttgart, Germany

    Rainer Gadow

  3. Faculty of Electronic Engg, University of Nis Faculty of Electronic Engg, Niš, Serbia

    Vojislav Mitic

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Hadžić, B., Romčević, M., Trajić, J., Stanišić, G., Timotijević, D. (2017). Influence of Preparation Method on SOP Modes in ZnO Doped with CoO Nanoparticles. In: Lee, B., Gadow, R., Mitic, V. (eds) Proceedings of the IV Advanced Ceramics and Applications Conference. Atlantis Press, Paris. https://doi.org/10.2991/978-94-6239-213-7_17

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  • DOI: https://doi.org/10.2991/978-94-6239-213-7_17

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