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Polymer-Based Monolithic Porous Composite

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Proceedings of the III Advanced Ceramics and Applications Conference

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Abstract

Porous monolithic glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA) copolymer [PGME] and three composite samples with alumina (PGME/alumina) were synthesized by radical copolymerization in a cast and functionalized by reaction of diethylene triamine (deta) with epoxy groups in GMA. All the samples were characterized using FTIR-ATR spectroscopy, SEM, AFM, solid state NMR, thermogravimetry and mercury porosimetry. Additionally, amino functionalized PGME/alumina with the highest alumina content (PGME/alumina50-deta) was loaded with chromium [Cr(VI)] ions. Kinetics of Cr(VI) sorption was investigated in batch static experiments, at 298 K and pH = 2, for various initial concentrations (C i  = 0.5, 1.5 and 2.5 mM) and analyzed using three kinetic models. Cr(VI) sorption by PGME/alumina50-deta obeys the PSO kinetic model, while IPD model suggests some degree of intraparticle pore diffusion control.

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Acknowledgment

This work has been funded by Serbian Ministry of Education, Science and Technological Development through the projects (III 43009, ON 172015, III 45001, TR 34026 and TR 32008).

Author information

Authors and Affiliations

  1. Centre of Chemistry, Institute of Chemistry, Technology and Metallurgy (ICTM), University of Belgrade, Njegoševa 12, 11000, Belgrade, Serbia

    Aleksandra B. Nastasović & Bojana M. Ekmeščić

  2. Centre of Catalysis and Chemical Engineering, Institute of Chemistry, Technology and Metallurgy (ICTM), University of Belgrade, Njegoševa 12, 11000, Belgrade, Serbia

    Tatjana B. Novaković & Zorica M. Vuković

  3. Centre of Microelectronic Technology, Institute of Chemistry, Technology and Metallurgy (ICTM), University of Belgrade, Njegoševa 12, 11000, Belgrade, Serbia

    Danijela V. Ranđelović

  4. Department of Chemical Dynamics and Permanent Education, Vinča Institute of Nuclear Sciences, University of Belgrade, P.O. Box 522, 11001, Belgrade, Serbia

    Danijela D. Maksin

  5. Institute of General and Physical Chemistry, University of Belgrade, Studentski Trg 12-16, 11000, Belgrade, Serbia

    Zoran P. Miladinović

Authors
  1. Aleksandra B. Nastasović
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  2. Tatjana B. Novaković
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  3. Zorica M. Vuković
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  4. Bojana M. Ekmeščić
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  5. Danijela V. Ranđelović
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  6. Danijela D. Maksin
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  7. Zoran P. Miladinović
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Corresponding author

Correspondence to Aleksandra B. Nastasović .

Editor information

Editors and Affiliations

  1. Department of Materials, Faculty of Engg, Imperial College London, London, United Kingdom

    William E. Lee

  2. University of Stuttgart, Stuttgart, Germany

    Rainer Gadow

  3. Faculty of Electronic Engineering, University of Nis, Nis, Serbia

    Vojislav Mitic

  4. Institute of Technical Sciences, Serbian Academy of Sciences and Arts, Belgrade, Serbia

    Nina Obradovic

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Nastasović, A.B. et al. (2016). Polymer-Based Monolithic Porous Composite. In: Lee, W., Gadow, R., Mitic, V., Obradovic, N. (eds) Proceedings of the III Advanced Ceramics and Applications Conference. Atlantis Press, Paris. https://doi.org/10.2991/978-94-6239-157-4_17

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  • DOI: https://doi.org/10.2991/978-94-6239-157-4_17

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