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Vibrational Spectroscopy of SOP Modes in ZnO Doped with CoO, MnO and Fe2O3

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Proceedings of the III Advanced Ceramics and Applications Conference

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Abstract

Nanocrystalline samples of ZnO doped with CoO, MnO and Fe2O3 were synthesized by traditional wet chemical method followed by calcinations. Samples where characterized by X-ray diffraction to determine composition of the samples (ZnO, Co3O4, Mn3O4, ZnMn2O4, ZnMnO3, ZnFe2O4 and Fe2O3) and the mean crystalline size (from 8 to 156 nm, depending on the sample). In this paper we report the experimental Raman scattering spectra (from 100 to 1600 cm−1 and from 200 to 1600 cm−1) with surface optical phonons (SOP) in range of 496−575 cm−1. This shows the change of position of SOP modes with crystalline size and change of intensity of SOP modes with change of concentration of doping elements. The phonon of registered phase’s exhibits effects connected to phase concentration, while the SOP phonon mode exhibit significant confinement effect.

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Acknowledgment

This work was supported under Agreement of of Scientific Collaboration between Polish Academy of Science and Serbian Academy of Sciences and Arts. The work in Serbia was supported by Serbian Ministry of Education, Science and Technological Development (Project 45003) and in Poland by National Science Center granted under decision No. DEC-2011/01/B/ST5/06602.

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Authors and Affiliations

  1. Institute of Physics, University of Belgrade, Belgrade, Serbia

    B. Hadžić, N. Romčević, J. Trajić, R. Kostić, G. Stanišić & D. Timotijević

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  1. B. Hadžić
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  2. N. Romčević
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  3. J. Trajić
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  4. R. Kostić
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  5. G. Stanišić
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  6. D. Timotijević
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Correspondence to B. Hadžić .

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Editors and Affiliations

  1. Department of Materials, Faculty of Engg, Imperial College London, London, United Kingdom

    William E. Lee

  2. University of Stuttgart, Stuttgart, Germany

    Rainer Gadow

  3. Faculty of Electronic Engineering, University of Nis, Nis, Serbia

    Vojislav Mitic

  4. Institute of Technical Sciences, Serbian Academy of Sciences and Arts, Belgrade, Serbia

    Nina Obradovic

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Hadžić, B., Romčević, N., Trajić, J., Kostić, R., Stanišić, G., Timotijević, D. (2016). Vibrational Spectroscopy of SOP Modes in ZnO Doped with CoO, MnO and Fe2O3 . In: Lee, W., Gadow, R., Mitic, V., Obradovic, N. (eds) Proceedings of the III Advanced Ceramics and Applications Conference. Atlantis Press, Paris. https://doi.org/10.2991/978-94-6239-157-4_11

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  • DOI: https://doi.org/10.2991/978-94-6239-157-4_11

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  • Print ISBN: 978-94-6239-156-7

  • Online ISBN: 978-94-6239-157-4

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