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Chiral Diazaligands for Asymmetric Synthesis pp 271–288Cite as

Chiral-at-Metal Complexes as Asymmetric Catalysts

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Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 15))

Abstract

In general, asymmetric catalysts are based on the combination of a chiral organic ligand and a metal ion. Here we show that future research should also focus on complexes in which the chirality resides only at the metal center, as the result of a given topology of coordination of achiral ligands to the metal ion. Here we make a brief presentation of the methods available for preparing such compounds as well as the very few examples of enantioselective reactions catalyzed by chiral-at-metal complexes.

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Authors and Affiliations

  1. Laboratoire de Chimie et Biochimie des Centres Rédox Biologiques, UMR Université J. Fourier-CEA-CNRS no 5047, CEA-Grenoble, DRDC/CB, 17 rue des Martyrs, 38054, Grenoble Cedex 9, France

    Marc Fontecave, Olivier Hamelin & Stéphane Ménage

Authors
  1. Marc Fontecave
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  2. Olivier Hamelin
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  3. Stéphane Ménage
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Corresponding author

Correspondence to Marc Fontecave .

Editor information

Marc Lemaire Pierre Mangeney

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Fontecave, M., Hamelin, O., Ménage, S. Chiral-at-Metal Complexes as Asymmetric Catalysts. In: Lemaire, M., Mangeney, P. (eds) Chiral Diazaligands for Asymmetric Synthesis. Topics in Organometallic Chemistry, vol 15. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b136353

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