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Polyelectrolyte Block Copolymer Micelles

  • Chapter
Polyelectrolytes with Defined Molecular Architecture II

Part of the book series: Advances in Polymer Science ((POLYMER,volume 166))

Abstract

Polyelectrolyte block copolymers form micelles and vesicles in aqueous solutions. Micelle formation and micellar structure depends on various parameters like block lengths, salt concentration, pH, and solvent quality. The synthesis and properties of more complicated block and micellar architectures such as triblock- and graft copolymers, Janus micelles, and core-shell cylinder brushes are reviewed as well. Investigations reveal details of the interactions of polyelectrolyte layers and electro-steric stabilization forces.

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Abbreviations

A:

insoluble polymer block

B:

soluble polymer block

b :

grafting distance

c s :

salt concentration

l B :

Bijerrum length

Nagg :

aggregation number

N A :

degree of polymerization of the soluble block

N B :

degree of polymerization of the insoluble block

N L :

Avogadros number

p m :

packing factor

R c :

micellar core radius

R m :

overall micellar radius

z:

micellar charge

κ −1 :

Debye length

ν:

Flory exponent

P2VP:

poly(2-vinylpyridine)

P4VP:

poly(4-vinylpyridine)

PAA:

poly(acrylic acid)

PAi:

poly(N,N-dimethylaminoisoprene)

PB:

poly(butadiene)

PCEVE:

poly(chloroethyl vinylether)

PEE:

poly(ethylethylene)

PEO:

poly(ethyleneoxide)

PMAA:

poly(methacrylic acid)

PMMA:

poly(methyl methacrylate)

PtBS:

poly(tert-butylstyrene)

PPO:

poly(propyleneoxide)

PS:

poly(styrene)

PnBA:

poly(n-butylacrylate)

PSSH:

poly(styrene sulfonic acid)

PSSNa:

poly(Na-styrenesulfonate)

P2VPHCl:

poly(2-vinypyridinium hydrochloride)

P2VPMeI:

poly(N-methyl-2-vinylpyridinium iodide)

P4VPQ:

quaternized poly(4-vinylpyridine)

DLS:

dynamic light scattering

FFF:

field flow fractionation

MALS:

multi-angle light scattering

SANS:

small-angle neutron scattering

SEM:

scanning electron microscopy

SFM:

scanning force microscopy

SLS:

static light scattering

TEM:

transmission electron microscopy

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Authors and Affiliations

  1. Institut für Physikalische Chemie, Universität Hamburg, Bundesstrasse 45, 20146 , Hamburg, Germany

    Stephan Förster

  2. Makromolekulare Chemie II and Bayreuther Zentrum für Kolloide und Grenzflächen, Universität Bayreuth, 95440 , Bayreuth, Germany

    Volker Abetz & Axel H. E. Müller

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  1. Stephan Förster
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  2. Volker Abetz
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  3. Axel H. E. Müller
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Correspondence to Stephan Förster .

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Manfred Schmidt

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Förster, S., Abetz, V., Müller, A.H.E. Polyelectrolyte Block Copolymer Micelles. In: Schmidt, M. (eds) Polyelectrolytes with Defined Molecular Architecture II. Advances in Polymer Science, vol 166. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b11351

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  • DOI: https://doi.org/10.1007/b11351

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