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Average One-Center Two-Electron Exchange Integrals and Exchange Interactions

  • Susanne MossinEmail author
  • Høgni WeiheEmail author
Chapter
Part of the Structure and Bonding book series (STRUCTURE, volume 106)

Abstract

We show how the introduction of the average one-center two-electron exchange integral, which is closely related to Jørgensens spin-pairing energy parameter, facilitates comparison of the Heisenberg-Dirac-van Vleck exchange parameter for different transition metal dimers. The formalism is illustrated on μ-oxo-dimanganese(III) and μ-oxo-dichromium(III) complexes in which the oxo bridge is the important exchange pathway.

Exchange interactions Spin-pairing energy 

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Copyright information

© Springer-Verlag Berlin Heidelberg 2004

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of CopenhagenCopenhagen

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