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Anion Sensing pp 125-162 | Cite as

Anion Sensing by Metal-Based Receptors

  • Paul D. BeerEmail author
  • Simon R. Bayly
Chapter
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 255)

Abstract

Metal-based receptors are an important and expanding class of molecules in anion sensing. This review describes the subject with specific focus on the metal-containing subunit’s function in determining their anion sensing properties. In general the metal ion is used as a photo- and/or electrochemical reporter group, an anion recognition site and/or as a simple structural component. Metal-based receptors, particularly where the metal ion performs a combination of these roles, exhibit a range of functionality not available to purely organic structures. The most recent advances in the field are also detailed including the use of metallo-receptors in dendrimer, functionalised nanoparticle and surface-bound anion sensors.

Anion recognition Organometallic receptors Transition metal receptors Electrochemical sensors Optical sensors 

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Authors and Affiliations

  1. 1.Department of Chemistry, Inorganic Chemistry LaboratoryUniversity of OxfordOxfordUK

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