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The electronic spectra of the hexafluoro complexes of the first transition series

  • G. C. Allen
  • K. D. Warren
Conference paper
Part of the Structure and Bonding book series (STRUCTURE, volume 9)

Keywords

Electronic Spectrum Transition Series Orbital Degeneracy Ligand Field Theory Nephelauxetic Effect 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Jørgensen, C. K.: Acta Chem. Scand. 12, 1539 (1958).Google Scholar
  2. 2.
    von Schnering, H. G.: Z. Anorg. Allgem. Chem. 353, 1 (1967).CrossRefGoogle Scholar
  3. 3.
    Jørgensen, C. K.: Absorption Spectra and Chemical Bonding in Complexes. London: Pergamon Press 1962.Google Scholar
  4. 4.
    Ballhausen, C. J.: Introduction to Ligand Field Theory. New York: McGraw-Hill Book Co., Inc. 1962.Google Scholar
  5. 5.
    Figgis, B. N.: Introduction to Ligand Fields. New York: Interscience Publishers 1966.Google Scholar
  6. 6.
    Bethe, H.: Ann. Physik 3, 133 (1929).CrossRefGoogle Scholar
  7. 7.
    Condon, E. U., Shortley, G. H.: The Theory of Atomic Spectra. London: Cambridge University Press 1963.Google Scholar
  8. 8.
    Orgel, L. E.: J. Chem. Phys. 23, 1004 (1955).CrossRefGoogle Scholar
  9. 9.
    Tanabe, Y., Sugano, S.: J. Phys. Soc. Japan 9, 753, 766 (1954).Google Scholar
  10. 10.
    Griffith, J. S.: The Theory of Transition Metal Ions. London: Cambridge University Press 1964.Google Scholar
  11. 11.
    Dunn, T. M., McClure, D. S., Pearson, R. G.: Some Aspects of Crystal Field Theory. London: Harper Row 1965.Google Scholar
  12. 12.
    Kettle, S. F. A.: Coordination Compounds. London: Nelson 1969.Google Scholar
  13. 13.
    Cotton, F. A.: Chemical Applications of Group Theory. New York: Interscience Publishers 1963.Google Scholar
  14. 14.
    Liehr, A. D., Ballhausen, C. J.: Ann. Phys. (N. Y.) 6, 134 (1959).CrossRefGoogle Scholar
  15. 15.
    Eisenstein, J. C.: J. Chem. Phys. 34, 1628 (1961).CrossRefGoogle Scholar
  16. 16.
    Schroeder, K. A.: J. Chem. Phys. 37, 1587, 2553 (1962).CrossRefGoogle Scholar
  17. 17.
    Jørgensen, C. K.: Acta Chem. Scand. 12, 903 (1958).Google Scholar
  18. 18.
    Orgel, L. E.: Quart. Rev. 11, 381 (1957).CrossRefGoogle Scholar
  19. 19.
    Offenhartz, P. O'D.: J. Am. Chem. Soc. 91, 5699 (1969).CrossRefGoogle Scholar
  20. 20.
    Wolfsberg, M., Helmholz, L.: J. Chem. Phys. 20, 837 (1952).CrossRefGoogle Scholar
  21. 21.
    Ballhausen, C. J., Gray, H. B.: Molecular Orbital Theory. New York: W. A. Benjamin, Inc. 1964.Google Scholar
  22. 22.
    Basch, H., Viste, A., Gray, H. B.: J. Chem. Phys. 44, 10 (1966).CrossRefGoogle Scholar
  23. 23.
    Roothaan, C. C. J.: Rev. Mod. Phys. 23, 69 (1951).CrossRefGoogle Scholar
  24. 24.
    Dahl, J. P., Ballhausen, C. J.: Advan. Quantum Chem. 4, 170 (1968).Google Scholar
  25. 25.
    Pople, J. A., Santry, D. P., Segal, G. A.: J. Chem. Phys. 43, S129 (1965).CrossRefGoogle Scholar
  26. 26.
    Fenske, R. F., Caulton, K. G., Radtke, D. D., Sweeney, C. C: Inorg. Chem. 5, 951 (1966).CrossRefGoogle Scholar
  27. 27.
    Brown, R. D., Roby, K. R.: Theoret. Chim. Acta (Berlin) 16, 175, 194 (1970).CrossRefGoogle Scholar
  28. 28.
    Jørgensen, C. K.: Orbitals in Atoms and Molecules. New York: Academic Press 1962.Google Scholar
  29. 29.
    Stein, L., Neil, J. M., Alms, G. R.: Inorg. Chem. 8, 2472 (1969).CrossRefGoogle Scholar
  30. 30.
    Bedon, H. D., Hatfield, W. E., Horner, S. M., Tyree, S. Y.: Inorg. Chem. 4, 743 (1965).CrossRefGoogle Scholar
  31. 31.
    Reisfeld, M. J., Asprey, L. B., Penneman, R. A.: J. Mol. Spectry. 29, 109 (1969).CrossRefGoogle Scholar
  32. 32.
    Kortüm, G.: Reflectance Spectroscopy. Berlin-Heidelberg-New York: Springer 1969.Google Scholar
  33. 33.
    —, Schottler, H.: Z. Elektrochem. 57, 353 (1953).Google Scholar
  34. 34.
    Ehrlich, P., Pietzka, G.: Naturwissenschaften 40, 509 (1953).CrossRefGoogle Scholar
  35. 35.
    Bright, N. F. H., Wurm, J. G.: Can. J. Chem. 36, 615 (1958).CrossRefGoogle Scholar
  36. 36.
    Bedon, H. D., Horner, S. M., Tyree, S. Y.: Inorg. Chem. 3, 647 (1964).CrossRefGoogle Scholar
  37. 37.
    Van Vleck, J. H.: J. Chem. Phys. 7, 61 (1939).CrossRefGoogle Scholar
  38. 38.
    Fowles, G. W. A., Russ, B. T.: J. Chem. Soc. (A) 517 (1967).Google Scholar
  39. 39.
    Nyholm, R. S., Sharpe, A. G.: J. Chem. Soc. 579 (1952).Google Scholar
  40. 40.
    Babel, D.: Struct. Bonding 3, 1 (1967).CrossRefGoogle Scholar
  41. 41.
    Ballhausen, C. J., Winther, F.: Acta Chem. Scand. 13, 1729 (1959).Google Scholar
  42. 42.
    Machin, D. J., Murray, K. S.: J. Chem. Soc. (A) 1498 (1967).—See also Clark, R. J. H.: J. Chem. Soc. 417 (1964).Google Scholar
  43. 43.
    Clark, H. C., Sadana, Y. N.: Can. J. Chem. 42, 50 (1964).CrossRefGoogle Scholar
  44. 44.
    Pryce, M. H. L., Runciman, W. A.: Discussions Faraday Soc. 26, 34 (1958).CrossRefGoogle Scholar
  45. 45.
    Warren, K. D.: unpublished matrices.Google Scholar
  46. 46.
    Figgis, B. N., Lewis, J., Mabbs, F. E., Webb, G. A.: J. Chem. Soc. (A) 1411 (1966).Google Scholar
  47. 47.
    Gruen, D. M., McBeth, R. L.: J. Phys. Chem. 66, 57 (1962).CrossRefGoogle Scholar
  48. 48.
    Christensen, O. T.: J. Prakt. Chem. 35, 163 (1887).Google Scholar
  49. 49.
    Peacock, R. D.: J. Chem. Soc. 4684 (1957).Google Scholar
  50. 50.
    —: Progr. Inorg. Chem. 2, 193 (1960).CrossRefGoogle Scholar
  51. 51.
    Figgis, B. N., Lewis, J.: Progr. Inorg. Chem. 6, 37 (1964).CrossRefGoogle Scholar
  52. 52.
    Wood, D. L., Ferguson, J., Knox, K., Dillon, J. F.: J. Chem. Phys. 39, 890 (1963).CrossRefGoogle Scholar
  53. 53.
    Ferguson, J., Knox, K., Wood, D. L.: J. Chem. Phys. 35, 2236 (1961) and 37, 193 (1962).CrossRefGoogle Scholar
  54. 54.
    Schläfer, H. L., Gausmann, H., Zander, H. U.: Inorg. Chem. 6, 1528 (1967).CrossRefGoogle Scholar
  55. 55.
    —, Witzke, H.: J. Chem. Phys. 46 1423 (1967).CrossRefGoogle Scholar
  56. 56.
    Furlani, C., Ciana, A.: Ann. Chim. (Rome) 48, 286 (1958).Google Scholar
  57. 57.
    Dingle, R.: J. Mol. Spectry. 9, 426 (1962).CrossRefGoogle Scholar
  58. 58.
    —: Inorg. Chem. 4, 1287 (1965).CrossRefGoogle Scholar
  59. 59.
    Hatfield, W. E., Parker, W. E.: Inorg. Nucl. Chem. Letters 1, 7 (1965).CrossRefGoogle Scholar
  60. 60.
    Oelkrug, D.: Ber. Bunsenges. Physik. Chem. 70, 736 (1966).Google Scholar
  61. 61.
    Davis, T. S., Fackler, J. P., Weeks, M. J.: Inorg. Chem. 7, 1894 (1968).Google Scholar
  62. 62.
    Hatfield, W. E., Fay, R. C., Pfluger, C. E., Piper, T. S.: J. Am. Chem. Soc. 85, 265 (1963).CrossRefGoogle Scholar
  63. 63.
    Klemm, W., Huss, E.: Z. Anorg. Allgem. Chem. 258, 221 (1949).Google Scholar
  64. 64.
    Knox, K., Mitchell, D. W.: J. Inorg. Nucl. Chem. 21, 253 (1961).CrossRefGoogle Scholar
  65. 65.
    Klemm, W., Krause, J., Wahl, K., Weise, E., Brandt, W.: Forschungsber. Wirtsch.-u. Verkehrsministeriums Nordrhein-Westfalen No. 160 (1955).Google Scholar
  66. 66.
    Unpublished measurements by G. A. M. El-Sharkarwy.Google Scholar
  67. 67.
    Yamata, H., Kato, A.: Bull. Chem. Soc. Japan 41, 2220 (1968).CrossRefGoogle Scholar
  68. 68.
    Grey, J. T.: J. Am. Chem. Soc. 68, 605 (1946).CrossRefGoogle Scholar
  69. 69.
    Hoppe, R.: Rec. Trav. Chim. 75, 569 (1956).CrossRefGoogle Scholar
  70. 70.
    Klemm, W., Brandt, W., Hoppe, R.: Z. Anorg. Allgem. Chem. 308, 179 (1961).CrossRefGoogle Scholar
  71. 71.
    Cotton, F. A., Meyers, M. D.: J. Am. Chem. Soc. 82, 5023 (1960).CrossRefGoogle Scholar
  72. 72.
    — — J. Am. Chem. Soc. 82, 5027 (1960).CrossRefGoogle Scholar
  73. 73.
    Figgis, B. N., Nyholm, R. S.: J. Chem. Soc. 338 (1959).Google Scholar
  74. 74.
    Allen, G. C., Warren, K. D.: Inorg. Chem. 8, 1895 (1969).CrossRefGoogle Scholar
  75. 75.
    Barraclough, C. G.: Trans. Faraday Soc. 62, 1033 (1966).CrossRefGoogle Scholar
  76. 76.
    Nelson, P. G.: private communication.Google Scholar
  77. 77.
    Knox, K., Shulman, R. G., Sugano, S.: Bull. Am. Phys. Soc. 5, 415 (1960).Google Scholar
  78. 78.
    Bode, H., Voss, E.: Z. Anorg. Allgem. Chem. 290, 1 (1957).CrossRefGoogle Scholar
  79. 79.
    Dove, M. F. A.: private communication.Google Scholar
  80. 80.
    Hoppe, R., Homann, R.: Naturwissenschaften 53, 501 (1966).CrossRefGoogle Scholar
  81. 81.
    Weinland, R. F., Lauenstein, O.: Z. Anorg. Allgem. Chem. 20, 40 (1899).Google Scholar
  82. 82.
    Liebe, W., Weise, E., Klemm, W.: Z. Anorg. Allgem. Chem. 311, 281 (1961).CrossRefGoogle Scholar
  83. 83.
    Cavell, R. G., Clark, H. C.: J. Chem. Soc. 2692 (1962).Google Scholar
  84. 84.
    Clark, R. J. H.: The Chemistry of Titanium and Vanadium, pp. 180–1. Amsterdam: Elsevier 1968.Google Scholar
  85. 85.
    Allen, G. C., El-Sharkarwy, G. A. M.: Inorg. Nucl. Chem. Letters 6, 493 (1970).CrossRefGoogle Scholar
  86. 86.
    Fowles, G. W. A., Walton, R. A.: J. Inorg. Nucl. Chem. 27, 735 (1965).CrossRefGoogle Scholar
  87. 87.
    Kilty, P. A., Nicholls, D.: J. Chem. Soc. 4915 (1965).Google Scholar
  88. 88.
    Machin, D. J., Murray, K. S.: J. Chem. Soc. (A) 1330 (1967).Google Scholar
  89. 89.
    Bridson, B. J., Lester, T. E., Walton, R. A.: Spectrochim. Acta (A) 23, 1969 (1967).Google Scholar
  90. 90.
    Bereman, R. D., Brubaker, C. H.: Inorg. Chem. 8, 2480 (1969).CrossRefGoogle Scholar
  91. 91.
    Huss, E., Klemm, W.: Z. Anorg. Allgem. Chem. 262, 25 (1950).Google Scholar
  92. 92.
    Bode, H., Voss, E.: Z. Anorg. Allgem. Chem. 286, 136 (1956).CrossRefGoogle Scholar
  93. 93.
    Klemm, W.: Bull. Soc. Chim. France 10, 1325 (1956).Google Scholar
  94. 94.
    Bode, H., Wendt, W.: Z. Anorg. Allgem. Chem. 269, 165 (1952).CrossRefGoogle Scholar
  95. 95.
    Hoppe, R., Liebe, W., Dähne, W.: Z. Anorg. Allgem. Chem. 307. 276 (1961).CrossRefGoogle Scholar
  96. 96.
    Allen, G. C., El-Sharkarwy, G. A. M., Warren, K. D.: Inorg. Nucl. Chem. Letters 5, 725 (1969).CrossRefGoogle Scholar
  97. 97.
    Reisfeld, M. J., Matwiyof, N. A., Asprey, L. B.: private communication (from M. J. R.).Google Scholar
  98. 98.
    Matwiyof, N. A., Asprey, L. B.: Chem. Commun. 75 (1970).Google Scholar
  99. 99.
    Flint, C. D.: Chem. Commun. 482 (1970). See also Pfeil, A.: Spectrochim. Acta (A) 26, 1341 (1970).Google Scholar
  100. 100.
    Novotny, D. S., Sturgeon, G. D.: Inorg. Nucl. Chem. Letters 6, 455 (1970).CrossRefGoogle Scholar
  101. 101.
    Moews, P. C.: Inorg. Chem. 5, 5 (1966).CrossRefGoogle Scholar
  102. 102.
    Cotton, F. A., Wilkinson, G.: Advanced Inorganic Chemistry. New York: Interscience Publishers 1962.Google Scholar
  103. 103.
    Allen, G. C., Warren, K. D.: Inorg. Chem. 8, 1902 (1969).CrossRefGoogle Scholar
  104. 104.
    Hoppe, R.: Angew. Chem. 62, 339 (1950).Google Scholar
  105. 105.
    Henkel, H., Hoppe, R., Allen, G. C.: J. Inorg. Nucl. Chem. 31, 3855 (1969).CrossRefGoogle Scholar
  106. 106.
    Westland, A. D., Hoppe, R., Kaseno, S. S. J.: Z. Anorg. Allgem. Chem. 338, 319 (1965).CrossRefGoogle Scholar
  107. 107.
    Bougon, R.: Compt. Rend. (C) 267, 681 (1968).Google Scholar
  108. 108.
    Allen, G. C., Warren, K. D.: Inorg. Chem. 8, 753 (1969).CrossRefGoogle Scholar
  109. 109.
    Reisfeld, M. J.: J. Mol. Spectry. 29, 120 (1969).CrossRefGoogle Scholar
  110. 110.
    Allen, G. C., Warren, K. D.: J. Mol. Spectry. 33, 180 (1970).CrossRefGoogle Scholar
  111. 111.
    Hinze, J., Jaffe, H. H.: J. Chem. Phys. 38, 1834 (1963).CrossRefGoogle Scholar
  112. 112.
    Tondello, E., De Michelis, G., Oleari, L., Di Sipio, L.: Coord. Chem. Rev., 2, 65 (1967).CrossRefGoogle Scholar
  113. 113.
    Jørgensen, C. K.: Helv. Chim. Acta, Fasciculus Extraordinarius Alfred Werner 131 (1967).Google Scholar
  114. 114.
    Racah, G.: Lunds Universitets Årsskrift N. F. 50, No. 21, 31 (1954).Google Scholar
  115. 115.
    Jørgensen, C. K.: Progr. Inorg. Chem. 4, 73 (1962).CrossRefGoogle Scholar
  116. 116.
    —: Struct. Bonding 1, 3 (1966).Google Scholar
  117. 117.
    Stevens, K. W. H.: Proc. Roy. Soc. (London) A219 542 (1953).Google Scholar
  118. 118.
    Balt, S., Verwey, A. M. A.: Spectrochim. Acta (A) 23, 2069 (1967).CrossRefGoogle Scholar
  119. 119.
    Chester, A. W., Heiba, El-A., Dessau, R. M., Koehl, W. J.: Inorg. Nucl. Chem. Letters 5, 277 (1969).CrossRefGoogle Scholar
  120. 120.
    Walton, R. A., Brisdon, B. J.: Spectrochim. Acta (A) 23, 2222 (1967).CrossRefGoogle Scholar
  121. 121.
    Sartori, G., Cervone, E., Cancellari, P.: Rend. Accad. Lincei 35, 226 (1963).Google Scholar
  122. 122.
    Di Sipio, L., Tondello, E., De Michelis, G., Oleari, L.: Inorg. Chem. 9, 927 (1970).CrossRefGoogle Scholar
  123. 123.
    Kotani, M.: J. Phys. Soc. Japan 4, 293 (1949).Google Scholar
  124. 124.
    Figgis, B. N.: Trans. Faraday Soc. 56, 1553 (1960).CrossRefGoogle Scholar
  125. 125.
    —: Trans. Faraday Soc. 57, 198, 204 (1961).CrossRefGoogle Scholar
  126. 126.
    Jørgensen, C. K.: Mol. Phys. 2, 309 (1959).CrossRefGoogle Scholar
  127. 127.
    —: Mol. Phys. 2, 43 (1963).CrossRefGoogle Scholar
  128. 128.
    —: Solid State Phys. 13, 375 (1962).Google Scholar
  129. 129.
    Moffitt, W., Goodman, G. L., Fred, M., Weinstock, B.: Mol. Phys. 2, 109 (1959).CrossRefGoogle Scholar
  130. 130.
    Jørgensen, C. K.: Acta Chem. Scand. 16. 793 (1962).CrossRefGoogle Scholar
  131. 131.
    Dunn, T. M.: In: Modern Coordination Chemistry, edited by J. Lewis and R. G. Wilkins: New York: Interscience Publishers 1960.Google Scholar
  132. 132.
    Liehr, A. D., Ballhausen, C. J.: Ann. Phys. (N. Y.) 3, 304 (1958).CrossRefGoogle Scholar
  133. 133.
    Bartlett, M., Palenik, C. J.: Chem. Commun. 416 (1970).Google Scholar
  134. 134.
    Fackler, J. P., Holah, D. G.: Inorg. Chem. 4, 954 (1965).CrossRefGoogle Scholar
  135. 135.
    Holmes, O. G., McClure, D. S.: J. Chem. Phys. 26, 1686 (1957).CrossRefGoogle Scholar
  136. 136.
    Elliott, H., Hathaway, B. J., Slade, R. C.: Inorg. Chem. 5, 669 (1966).CrossRefGoogle Scholar
  137. 137.
    Allen, G. C., Warren, K. D.: unpublished observations.Google Scholar

Copyright information

© Springer-Verlag 1971

Authors and Affiliations

  • G. C. Allen
    • 1
  • K. D. Warren
    • 1
  1. 1.Department of ChemistryUniversity CollegeCardiffWales, Great Britain

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