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Structure and bonding in inorganic derivatives of β-diketones

  • D. W. Thompson
Conference paper
Part of the Structure and Bonding book series (STRUCTURE, volume 9)

Keywords

Chelate Ring Benzenoid Resonance Hydroxy Ketone Metal Acetylacetonates Enol Tautomer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Laar, C.: Ber. 18, 648 (1885).Google Scholar
  2. 2.a)
    Burdett, J. L., Rodgers, M. T.: J. Am. Chem. Soc. 86, 2105 (1964); b)Burdett, J. L., Rodgers, M. T.: Can. J. Chem. 43, 1516 (1965).CrossRefGoogle Scholar
  3. 3.
    Combes, A.: Compt. Rend. 105, 871 (1887).Google Scholar
  4. 4.
    Morgan, G. T., Moss, H. W.: J. Chem. Soc. 105, 189 (1914).Google Scholar
  5. 5.
    Fackler, J. P., Jr.: Progr. Inorg. Chem. 7, 361 (1967).CrossRefGoogle Scholar
  6. 6.
    Hashimoto, F., Tanaka, J., Nagakura, S.: J. Mol. Spectry. 10, 410 (1963).CrossRefGoogle Scholar
  7. 7.
    Roof, R. B.: Acta Cryst. 9, 78 (1956).CrossRefGoogle Scholar
  8. 8.
    Lingafelter, E. C., Braun, R. L.: J. Am. Chem. Soc. 88, 2951 (1966).CrossRefGoogle Scholar
  9. 9.
    Moshier, R. W., Siewer, R. E.: Gas Chromatography of Metal Chelates, Appendix I. Pergamon 1965.Google Scholar
  10. 10.a)
    Collman, J. P.: In: Reactions of Coordinated Ligands, p. 78. Washington, D. C.: American Chemical Society 1963; b) Collman, J. P.: Angew. Chem. Intern. Ed. Engl. 4, 132 (1965).Google Scholar
  11. 11.
    Selbin, J.: Chem. Rev. 65, 153 (1965).CrossRefGoogle Scholar
  12. 12.
    Lingafelter, E. C.: Coord. Chem. Rev. 1, 151 (1966).CrossRefGoogle Scholar
  13. 13.
    Bonati, F.: Organometal. Chem. Rev. 1, 379 (1966).Google Scholar
  14. 14.
    Allred, A. L., Thompson, D. W.: Inorg. Chem. 7, 1196 (1968).CrossRefGoogle Scholar
  15. 15.
    Van Leeuwen, P. W. N. M.: Rec. Trav. Chim. 87, 396 (1968).CrossRefGoogle Scholar
  16. 16.
    Kakamura, Y., Kawaguchi, S.: Chem. Commun. 716 (1968).Google Scholar
  17. 17.
    West, R.: J. Am. Chem. Soc. 80, 3246 (1958).CrossRefGoogle Scholar
  18. 18.
    Howe, J. J., Collins, W. T., Pinnavaia, T. J.: J. Am. Soc. Chem. 91, 5378 (1969).CrossRefGoogle Scholar
  19. 19.
    Werner, A.: Ber. 34, 2584 (1901).Google Scholar
  20. 20. a)
    Figgis, B. N., Lewis, J., Long, R. F., Mason, K., Nyholm, R. S., Pauling, P. J., Robertson, G. B.: Nature 195, 1278 (1962); b) Mason, R., Robertson, G. B., Pauling, P. J.: J. Chem. Soc. 485 (1969).CrossRefGoogle Scholar
  21. 21.
    Lewis, J., Long, R. F., Oldham, C.: J. Chem. Soc. 6750 (1965).Google Scholar
  22. 22.
    Nakamoto, K., Behnke, G. T.: Inorg. Chem. 6, 440 (1967).CrossRefGoogle Scholar
  23. 23.
    Gibson, D.: Coord. Chem. Rev. 4, 225 (1969).CrossRefGoogle Scholar
  24. 24.
    Hartman, F. A., Kilmer, M., Wjocieki, A.: Inorg. Chem. 6, 34 (1967).CrossRefGoogle Scholar
  25. 25.
    Swallow, M. A. G., Truter, M. R.: Proc. Roy. Soc. (London) A, 254, 205 (1960).Google Scholar
  26. 26. a)
    Hargreaves, R. W., Truter, M. R.: Chem. Commun. 473 (1968). b) Hargreaves, R. W., J. Chem. Soc. A 2282 (1968).Google Scholar
  27. 27.
    Wilkinson, G., Cotton, F. A.: Advanced Inorganic Chemistry, 2nd ed., p. 1036. New York: McCraw-Hill 1966.Google Scholar
  28. 28.
    Parshall, G. W., Jones, F. N.: J. Am. Chem. Soc. 87, 535 (1965).Google Scholar
  29. 29.
    Watson, W. H., Lin, C.: Inorg. Chem. 5, 1074 (1966).CrossRefGoogle Scholar
  30. 30.
    Dahl, L., communication to Robertson, I., Truter, M. R.: J. Chem. Soc. A 309 (1967). This latter reference report the crystal structure of bis(3-methylacetylacetonato) copper(II).Google Scholar
  31. 31.
    a) Allen, G., Lewis, J., Long, R. F., Oldham, C.: Nature 202, 589 (1964); b) Gibson, D., Lewis, J., Oldham, C.: J. Chem. Soc. A 72 (1967).CrossRefGoogle Scholar
  32. 32.
    Behnke, G. T., Nakomoto, J.: Inorg. Chem. 7, 2030 (1968).CrossRefGoogle Scholar
  33. 33.
    a) Morgan, G. T., Drew, H. D. K.: J. Chem. Soc. 117, 1456 (1920). b) Morgan, G. T., Drew, H. D. K. 121, 922 (1922).Google Scholar
  34. 34.
    Dewar, D. H., Fergusson, J. E., Hentschel, P. R., Wilkins, C. J., Williams, P. P.: J. Chem. Soc. 688 (1964).Google Scholar
  35. 35.
    Asmussen, R. W.: Thesis Copenhagen, 1944, Reported in reference 37.Google Scholar
  36. 36.
    Holm, R. H.: Ph. D. Thesis, Massachusetts Institute of Technology, 1959. Cited in reference 37. Facker, J. P., Cotton, F. A.: J. Am. Chem. Soc. 83, 2818 (1961).Google Scholar
  37. 37.
    Fackler, J. P., Cotton, F. A.: J. Am. Chem. Soc. 83, 2818 (1961).CrossRefGoogle Scholar
  38. 38.
    a) Jørgensen, C. K.: Acta Chem. Scand. 9, 1362 (1955). Jørgensen observed that the visible spectra for Ni(acac)2·2 C2H5OH and Ni(acac)2 were virtually identical and was the first to correctly suggest that Ni(acac)2 contained octahedral nickel. b) Maki, A.: J. Chem. Phys. 29, 162 (1958).Google Scholar
  39. 39.
    a) Bullen, G. J.: Nature 177, 537 (1956)—only very preliminary results reported; b) Bullen, G. J., Mason, R., Pauling, P.: Nature 189, 291 (1961); c) Bullen, G. J., Mason, R., Pauling, P., Inorg. Chem. 4, 456 (1965)—complete structural data.CrossRefGoogle Scholar
  40. 40.
    Holm, R. H., Cotton, F. A.: J. Phys. Chem. 65, 321 (1961).CrossRefGoogle Scholar
  41. 41.
    Bullen, G. J.: Acta Cryst. 12, 103 (1959).CrossRefGoogle Scholar
  42. 42.
    Graddon, D. P., Watton: Nature 190, 906 (1961).CrossRefGoogle Scholar
  43. 43.
    Fackler, J. P., Cotton, F. A.: J. Am. Chem. Soc. 83, 3775 (1961).CrossRefGoogle Scholar
  44. 44.
    Bennett, M. J., Cotton, F. A., Eiss, R., Elder, R. C.: Nature 213, 174 (1967).CrossRefGoogle Scholar
  45. 45.
    Cotton, F. A., Elder, R. C.: J. Am. Chem. Soc. 86, 2294 (1964).CrossRefGoogle Scholar
  46. 46.
    Graddon, D. P.: Coord. Chem. Rev. 4, 1 (1969).CrossRefGoogle Scholar
  47. 47.
    a) Collman, J. P., Barker, R. H.: reported in Angew. Chem. Intern. Ed. Engl. 4, 132 (1965); b) Barker, R. H., Collman, J. P., Marshall, R. L.: J. Org. Chem. 29, 3216 (1964).CrossRefGoogle Scholar
  48. 48.
    Wilkins, J. P., Wittbecker, E. L.: U.S. Patent 2,659,711 (Nov. 17, 1953).Google Scholar
  49. 49.
    Grove, D. E., Johnson, N. P., Lock, C. J. L., Wilkinson, G.: J. Chem. Soc. 490 (1965).Google Scholar
  50. 50.
    Calvin, M., Wilson, K. W.: J. Am. Chem. Soc. 67, 2003 (1945).CrossRefGoogle Scholar
  51. 51.
    Holm, R. H. Cotton, F. A.: J. Am. Chem. Soc. 80, 5658 (1958).CrossRefGoogle Scholar
  52. 52.
    Belford, R. L., Martell, A. E., Calvon, M.: J. Inorg. Nucl. Chem. 2, 11 (1956).CrossRefGoogle Scholar
  53. 53.
    Forster, L. S.: J. Am. Chem. Soc. 86, 3001 (1964).CrossRefGoogle Scholar
  54. 54.
    a) Barnum, D. W.: J. Inorg. Nucl. Chem. 21, 221 (1961); b) Barnum, D. W.: J. Inorg. Nucl. Chem. 22, 183 (1961).CrossRefGoogle Scholar
  55. 55.
    Hill, J. O., Irving, R. J.: J. Chem. Soc. 3116 (1968).Google Scholar
  56. 56.
    Hill, J. O., Irving, R. J.: J. Chem. Soc. 1052 (1968).Google Scholar
  57. 57.
    Hill, J. O., Irving, R. J.: J. Chem. Soc. 1052 (1968).Google Scholar
  58. 58.
    Jørgensen, C. K.: Acta Chem. Scand. 16, 2406 (1962).CrossRefGoogle Scholar
  59. 59.
    —: Absorption Spectra and Chemical Bonding in Complexes, p. 146ff. and references therein. Reading, Mass.: Addison-Wesley 1962.Google Scholar
  60. 60.
    —: Orbitals in Atoms and Molecules, p. 94ff. New York: Academic Press 1962.Google Scholar
  61. 61.
    a) Cotton, F. A., Harris, C. B., Wise, J. J.: Inorg. Chem. 6, 909 (1967); b) Cotton, F. A., Wise, J. J.: Inorg. Chem. 6, 917 (1967) and references therein.CrossRefGoogle Scholar
  62. 62.
    Forman, A., Murrell, J. N., Orgel, L. E.: J. Chem. Phys. 31, 1129 (1959).CrossRefGoogle Scholar
  63. 63.
    Eaton, D. R.: J. Am. Chem. Soc. 87, 3097 (1965).CrossRefGoogle Scholar
  64. 64.
    Collman, J. O., Marshall, R. L., Young, W. L.: Chem. Ind. (London) 1380 (1962).Google Scholar
  65. 65.
    Linck, R. G., Sievers, R. E.: Inorg. Chem. 5, 806 (1966).CrossRefGoogle Scholar
  66. 66.
    Reference 47a and references therein.CrossRefGoogle Scholar
  67. 67.
    Hester, R. E.: Chem. Ind. (London) 1397 (1963).Google Scholar
  68. 68.
    a) Sepone, N., Fay, R. C.: Inorg. Chem. 8, 2379 (1969); b) Fay, R. C., Sepone, N.: J. Am. Chem. Soc. 90, 5701 (1968).CrossRefGoogle Scholar
  69. 69.
    Singh, P. R., Sahai, R.: Australian J. Chem. 23, 269 (1970).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag 1971

Authors and Affiliations

  • D. W. Thompson
    • 1
  1. 1.Department of ChemistryCollege of William and MaryWilliamsburgUSA

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