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A titration calorimetry study of a technical grade APG

  • B. K. Jha
  • M. Svensson
  • K. Holmberg
Surfactant Colloids
Part of the Progress in Colloid & Polymer Science book series (PROGCOLLOID, volume 110)

Abstract

This paper reports titration microcalorimetric measurements on micellization of a technical grade alkyl polyglucoside (APG) surfactant. The dilution enthalpy was recorded at three different temperatures and the curves obtained were compared to those of pure β-octyl glucoside. For comparative purposes titration microcalorimetry was also conducted with the conventional nonionic surfactant octa (ethylene glycol) monododecyl ether and with the anionic surfactant sodium dodecylsulfate, SDS. The results indicate that, contrary to the alcohol ethoxylate, both glucoside surfactants undergo micellization without much loss of water of hydration. Compared to the pure octyl glucoside, the technical grade APG exhibited a lower cmc and a less endothermic enthalpy of micellization at room temperature.

Key words

Microcalorimetry enthalpy micellization surfactants alkyl polyglucosides 

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References

  1. 1.
    Rosen MJ (1989) Surfactants and Interfacial Phenomena. Wiley, New YorkGoogle Scholar
  2. 2.
    Moroi Y (1992) Micelles: Theoretical and Applied Aspects. Plenum, New YorkGoogle Scholar
  3. 3.
    Zajac J, Chorro C, Lindheimer M, Partyka S (1997) J Phys Chem 13:1486–1495Google Scholar
  4. 4.
    Paula S, Sus W, Tuchten H, Blume A (1995) J Phys Chem 99:11742–11751CrossRefGoogle Scholar
  5. 5.
    Aratono M, Ohta A, Ikeda N, Matsubara A, Motomura K, Takiu T (1997) J Phys Chem B 101:3535–3539CrossRefGoogle Scholar
  6. 6.
    Zajac J, Chorro M, Chorro C (1995) Prog Colloid Polym Sci 98:199–302Google Scholar
  7. 7.
    Weckström K, Rosenholm JB (1997) J Chem Soc Faraday Trans 93:569–578CrossRefGoogle Scholar
  8. 8.
    Olofsson G (1985) J Phys Chem 89:1473–1477CrossRefGoogle Scholar
  9. 9.
    Birdi KS (1983) Colloid Polym Sci 26:45–48CrossRefGoogle Scholar
  10. 10.
    Andersson B, Olofsson G (1988) J Chem Soc Faraday Trans 84(1):4087–4095CrossRefGoogle Scholar
  11. 11.
    Lisi RD, Inglese A, Milioto A, Pellerito A (1997) Langmuir 13:192–202CrossRefGoogle Scholar
  12. 12.
    Gu G, Yan H, Chen W, Wang W (1996) J Colloid Interface Sci 178:614–619CrossRefGoogle Scholar
  13. 13.
    Johnson I, Olofsson G, Jönsson B (1987) J Chem Soc Faraday Trans 83(1):3331–3344CrossRefGoogle Scholar
  14. 14.
    Nusselder JJH, Engberts JBFN (1992) J Colloid Interface Sci 48:353–361CrossRefGoogle Scholar
  15. 15.
    Desnoyers JE, Perron G (1996) Langmuir 12:4044–4045CrossRefGoogle Scholar
  16. 16.
    Nilsson F (1996) INFORM 7:490–497Google Scholar
  17. 17.
    Kameyama K, Takagi T (1990) J Colloid Interface Sci 137:1–10CrossRefGoogle Scholar
  18. 18.
    Marl DB (1991) Tenside Surf Det 28:419–427Google Scholar
  19. 19.
    Förster T, Guckenbiehl, Hansen H, von Rybinski W (1996) Prog Colloid Polym Sci 101:105–112CrossRefGoogle Scholar
  20. 20.
    Mitchell DJ, Tiddy GJT, Waring L, Bostock T, Bcdonald MP (1983) J Chem Soc Faraday Trans 79:975–1000CrossRefGoogle Scholar
  21. 21.
    Hato M, Minamikawa H (1996) Langmuir 12:1658–1665CrossRefGoogle Scholar
  22. 22.
    Dupuy C, Auvray X, Petipas C, Rico-Lattes I, Lattes A (1997) Langmuir 13:3965–3967CrossRefGoogle Scholar
  23. 23.
    Crowe LM, Mouradian R, Crowe JH, Jackson SA, Womersely C (1984) Biochim Biophys Acta 769:141–150CrossRefGoogle Scholar
  24. 24.
    Nilsson F, Söderman O (1996) Langmuir 12:902–908CrossRefGoogle Scholar
  25. 25.
    Drummond CJ, Warr GG, Griesser F, Ninham BW, Evans DF (1985) J Phys Chem 89:2103–2107CrossRefGoogle Scholar
  26. 26.
    von Rybinski W (1996) Current Opinion Colloid Interface Sci 1:587–597CrossRefGoogle Scholar
  27. 27.
    Suurkuusk J, Wadsoe I (1982) Chem Scr 20:155–163Google Scholar
  28. 28.
    Bach J, Blandamer MJ, Burgess J, Cullis PM, Soldi LG, Bijma K, Engberts JBFN, Kooreman PA, Kacperska A, Rao KC, Subha MCS (1995) J Chem Soc Faraday Trans 91:1229–1235CrossRefGoogle Scholar
  29. 29.
    van Os NM, Daane GJ, Haandrikman G (1991) J Colloid Interface Sci 141:199–217CrossRefGoogle Scholar
  30. 30.
    Olofsson G, Wang G (to be published)Google Scholar
  31. 31.
    Desnoyers JE, Caron G, DeLisi R, Roberts D, Roux A, Perron G (1983) J Phys Chem 87:1397–1406CrossRefGoogle Scholar
  32. 32.
    Corkill JM, Goodman JF, Harrold SP (1964) Trans Faraday Soc 60:202–207CrossRefGoogle Scholar
  33. 33.
    Jönsson B, Lindman B, Holmberg K, Kronberg B (1998) Surfactants and Polymers in Aqueous Solution. Wiley, New York, Ch. 2Google Scholar
  34. 34.
    Balzer D (1996) Tenside Surf Det 33:102–110Google Scholar

Copyright information

© Dr. Dietrich Steinkopff Verlag GmbH & Co. KG 1998

Authors and Affiliations

  • B. K. Jha
    • 1
  • M. Svensson
    • 1
  • K. Holmberg
    • 1
  1. 1.Institute for Surface ChemistryStockholmSweden

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