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A titration calorimetry study of a technical grade APG

  • Surfactant Colloids
  • Conference paper
  • First Online:
Trends in Colloid and Interface Science XII

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 110))

Abstract

This paper reports titration microcalorimetric measurements on micellization of a technical grade alkyl polyglucoside (APG) surfactant. The dilution enthalpy was recorded at three different temperatures and the curves obtained were compared to those of pure β-octyl glucoside. For comparative purposes titration microcalorimetry was also conducted with the conventional nonionic surfactant octa (ethylene glycol) monododecyl ether and with the anionic surfactant sodium dodecylsulfate, SDS. The results indicate that, contrary to the alcohol ethoxylate, both glucoside surfactants undergo micellization without much loss of water of hydration. Compared to the pure octyl glucoside, the technical grade APG exhibited a lower cmc and a less endothermic enthalpy of micellization at room temperature.

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Author information

Authors and Affiliations

  1. Institute for Surface Chemistry, P.O. Box 5607, SE 11486, Stockholm, Sweden

    B. K. Jha, M. Svensson & K. Holmberg

Authors
  1. B. K. Jha
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  2. M. Svensson
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  3. K. Holmberg
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Editor information

G. J. M. Koper D. Bedeaux C. Cavaco W. F. C. Sager

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© 1998 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Jha, B.K., Svensson, M., Holmberg, K. (1998). A titration calorimetry study of a technical grade APG. In: Koper, G.J.M., Bedeaux, D., Cavaco, C., Sager, W.F.C. (eds) Trends in Colloid and Interface Science XII. Progress in Colloid & Polymer Science, vol 110. Steinkopff. https://doi.org/10.1007/BFb0118082

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  • DOI: https://doi.org/10.1007/BFb0118082

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1117-0

  • Online ISBN: 978-3-7985-1653-3

  • eBook Packages: Springer Book Archive

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