Abstract
The aggregation of colloidal polystyrene latex particles has been investigated using small-angle static light scattering. Aggregate structures were found to be mass fractal in nature for both the salt-aggregated and depletion-flocculated systems. The measured fractal dimensions were found to be highly dependent on the salt concentration, the concentration of non-adsorbing polymer and the initial particle concentration in solution. The fractal dimensions observed for the depletion-flocculated aggregates, particularly at low polymer concentrations, were significantly larger than those observed for the salt-induced aggregates. Interestingly, for both aggregation systems, an increase in the initial particle concentration resulted in lower fractal dimensions.
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References
Mandelbrot BB (1982) The Fractal Geometry of Nature. Freeman, San Francisco
Teixeira J (1988) J Appl Crystallogr 21:781–785
Cannell DS, Aubert C (1986) Phys Rev Lett 56:738–741
Wilcoxon JP, Martin JE, Schaefer DW (1989) Phys Rev A 39:2675–2688
Lin MY, Lindsay HM, Weitz DA, Ball RC, Klein R, Meakin P (1989) Nature 339:360–362
Carpineti M, Ferri F, Giglio M, Paganini E, Perini U (1990) Phys Rev A 42:7347–7354
Zhou Z, Chu B (1991) J Colloid Interface Sci 143:356–365
Amal R, Raper JA, Waite TD (1992) J Colloid Interface Sci 151:244–257
Cowell C, Li-in-on R, Vincent B (1978) J Chem Soc, Faraday Trans 1 74:337–347
Clarke J, Vincent B (1981) J Colloid Interface Sci 82:208–216
Cowell C, Vincent B (1982) J Colloid Interface Sci 87:518–526
Vincent B, Clarke J, Barnett KG (1986) Colloids Surf A 17:51–65
Vincent B, Edwards J, Emmett S, Jones A (1986) Colloids Surf A 18:261–281
Jones A, Vincent B (1989) Colloids Surf A 42:113–138
Milling A, Vincent B, Emmett S, Jones A (1991) Colloid Surf A 57:185–195
Asakura S, Oosawa F (1954) J Chem Phys 22:1255–1256
Feigin RI, Napper DH (1980) J Colloid Interface Sci 75:525–541
de Gennes PG (1982) Macromolecules 15:492–500
Scheutjens JMHM, Fleer GJ (1982) Adv Colloid Interface Sci 16:341–359
Vincent B (1990) Colloids Surf A 50:241–249
Goodwin JW, Hearn J, Ho CC, Ottewill RH (1974) Colloid Polym Sci 252464–471
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© 1998 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
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Burns, J.L., Biggs, S., Yan, Y.D., Jameson, G.J. (1998). A comparison of the fractal properties of salt-aggregated and polymer-flocculated colloidal particles. In: Koper, G.J.M., Bedeaux, D., Cavaco, C., Sager, W.F.C. (eds) Trends in Colloid and Interface Science XII. Progress in Colloid & Polymer Science, vol 110. Steinkopff. https://doi.org/10.1007/BFb0118052
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DOI: https://doi.org/10.1007/BFb0118052
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