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Infrared studies of adsorption at the solid/liquid interface

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Book cover Mechanisches Verhalten von Polymeren Wechselwirkung in Polymeren bzw. kolloiden Systemen

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 67))

Abstract

Infrared spectroscopy provides an extremely important method for the study of surface-adsorbate interactions at the solid-liquid interface. The characterization of types of interaction and modes of adsorption can often be achieved in a way which is not possible by any other experimental method. Several modes of adsorption involving a single adsorbate can sometimes be distinguished and unambiguously characterized. Competitive adsorption from multi-component liquid mixtures can be monitored. Information can be gained about the orientation of adsorbed molecules, and changes of orientation with coverage recognized. The application of infrared spectroscopy to study of the solid/liquid interface appears to promise the rewards already experienced from infrared investigations of the solid/vapour interface. The addition of a liquid phase is a complicating experimental factor which may limit the spectral regions available for study. The use of cells with short optical path-lengths is essential. Work at Nottingham has entirely involved study of the adsorption of small molecules onto pressed discs of oxides immersed in liquids. The use of discs is unsuitable for systems containing polymeric adsorbate. Studies of polymer adsorption are better carried out by spectroscopic examination of ‘loose’ dispersions of solid adsorbents in liquid dispersion medium (17–22, 27–30).

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Authors and Affiliations

  1. Chemistry Department of the, Universityof Nottingham, NG 7 2 RD, Nottingham, England

    C. H. Rochester

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  1. C. H. Rochester
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H. Rupprecht R. Bonart F. H. Müller A. Weiss

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© 1980 Dr. Dietrich Steinkopff Verlag

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Rochester, C.H. (1980). Infrared studies of adsorption at the solid/liquid interface. In: Rupprecht, H., Bonart, R., Müller, F.H., Weiss, A. (eds) Mechanisches Verhalten von Polymeren Wechselwirkung in Polymeren bzw. kolloiden Systemen. Progress in Colloid & Polymer Science, vol 67. Steinkopff. https://doi.org/10.1007/BFb0117380

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  • DOI: https://doi.org/10.1007/BFb0117380

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  • Print ISBN: 978-3-7985-1812-4

  • Online ISBN: 978-3-7985-1813-1

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