Abstract
Insoluble spread monolayers of Dipalmitoyllecithin and Dipalmitoylcephalin are investigated by π/A isotherms and periodic compression and dilatation to determine their elasticity and the phase angles between strain and stress.
Depending upon the temperature, the phase angle becomes noticeable in the film pressure region in which the phase transition takes place.
From the rheological point of view, we conclude that the relaxation processes in the two-phase film state make the main contribution to the phase angle.
Preview
Unable to display preview. Download preview PDF.
References
Dimitrov DS, Panajotov I, Richmond P, Ter-Minassian-Saraga L (1978) J Colloid Interface Sci 65:483–494
Nagle JF (1980) Ann Rev Phys Chem 31:157–195
Dörfler H-D, Koth C (1984) Wiss Z Univ Halle XXXIII:69–79
Erbrich U, Septinus M, ZImmermann (1982) Ber Bunsenges Phys Chem 86:724–728
Van den Tempel M (1977) J Non-Newt Fluid Mech 2:205–219
Lucassen J, Van den Tempel M (1972) J Colloid Interface Sci 41:441–498
Lucassen-Reynders E (1981) in: Surfactant Science Series Vol 11. Marcel Decker, New York, pp 173–216
Kretzschmar G, Lunkenheimer K, Miller R (1986) IXth European Chemistry of Interfaces, Zakopane. In: Material Science Forum. Trans Tech (1988) 25–26:211–222
Vollhardt D, Zastrow L, Wüstneck R (1978) Colloid & Polymer Sci 256:973–982
Kretzschmar G, König K (1981) J Signal AM 9:203–212
Van Voorst Vader F, Erkens TF, Van den Tempel M (1964) Trans Faraday Soc 60:1170–1177
Veer FA, Van den Tempel M (1973) J Colloid Interface Sci 42:418
Maru HC, Wasan DT (1979) Chem Eng Sci 34:1295–1307
Lucassen J, Van den Tempel M (1972) Chem Eng Sci 27:1283–1291
Helm CA, Laxhuber L, Mösche M, Möhwald H (1986) Colloid & Polymer Sci 264:46–55
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 1988 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
About this paper
Cite this paper
Kretzschmar, G. (1988). Phase transitions in phospholipid monolayers and rheological properties of the corresponding membrane model. In: Hummel, K., Schurz, J. (eds) Dispersed Systems. Progress in Colloid & Polymer Science, vol 77. Steinkopff. https://doi.org/10.1007/BFb0116763
Download citation
DOI: https://doi.org/10.1007/BFb0116763
Received:
Accepted:
Published:
Publisher Name: Steinkopff
Print ISBN: 978-3-7985-0778-4
Online ISBN: 978-3-7985-1692-2
eBook Packages: Springer Book Archive