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Polymer solidification by crystallization under heat transfer and flow conditions

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Solidification Processes in Polymers

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 87))

Abstract

Two limiting cases can be discriminated when solidification processes are considered in which crystallization is involved. With relatively thick samples and high crystallization speeds the process is heat-diffusion controlled, whereas with thin samples and low crystallization speeds the process becomes nucleation-rate controlled. Solidification processes in crystallizable polymers clearly demonstrate the latter type of process. Surprisingly, no mathematical tools had been developed so far for the correct description of the local interplay between heat flow and evolution of heat by crystallization, as controlled by the crystallization kinetics. A review is given of recent developments in this field, which is complicated by the changes in crystallization kinetics, as introduced by the action of shear flow.

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Author information

Authors and Affiliations

  1. Inst. of Chemistry, Linz University, A-4040, Linz, Austria

    H. Janeschitz-Kriegl

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  1. H. Janeschitz-Kriegl
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Editor information

J. -F. Janssson U. W. Gedde

Additional information

Dedicated to Prof. O. Vogl, Herman F. Mark Professor, Polytechnic University Brooklyn, on the occassion of his 65th birthday.

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© 1992 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Janeschitz-Kriegl, H. (1992). Polymer solidification by crystallization under heat transfer and flow conditions. In: Janssson, J.F., Gedde, U.W. (eds) Solidification Processes in Polymers. Progress in Colloid & Polymer Science, vol 87. Steinkopff. https://doi.org/10.1007/BFb0115586

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  • DOI: https://doi.org/10.1007/BFb0115586

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-0911-5

  • Online ISBN: 978-3-7985-1682-3

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