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Relaxation in Polymers pp 209–220Cite as

Relaxation in permanent networks

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Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 80))

Abstract

By linking together the theory of finite elasticity and thermodynamics of irreversible processes one is led to a very general description of deformation. The clue to the simplicity of describing relaxation in permanent networks is the existence of the van der Waals network model which allows a unique description of the nonlinear equilibrium states of reference. Having then a set of relaxation processes coupled to the network (“global level”) one arrives at the prediction that only shear relaxation is important. This is proven to hold true by describing relaxation during stress-strain experiments at different temperatures in different deformation modes including the regime of large strains.

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Author information

Authors and Affiliations

  1. Abt. für Experimentelle Physik, Universität Ulm, Albert-Einstein-Allee 11, 7900, Ulm

    H. Ambacher, H. F. Enderle, H. G. Kilian & A. Sauter

Authors
  1. H. Ambacher
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  2. H. F. Enderle
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  3. H. G. Kilian
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  4. A. Sauter
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Editor information

M. Pietralla W. Pechhold

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© 1989 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Ambacher, H., Enderle, H.F., Kilian, H.G., Sauter, A. (1989). Relaxation in permanent networks. In: Pietralla, M., Pechhold, W. (eds) Relaxation in Polymers. Progress in Colloid & Polymer Science, vol 80. Steinkopff. https://doi.org/10.1007/BFb0115432

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  • DOI: https://doi.org/10.1007/BFb0115432

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-0832-3

  • Online ISBN: 978-3-7985-1689-2

  • eBook Packages: Springer Book Archive

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