Abstract
The polymerization-dependent photoconductivity in single crystals of pTS diacetylene was studied. pTS has been known to polymerize topochemically in the solid state, and its polymerization kinetics has been known. Since the monomer is non-photoconducting, a study of the photoconductivity build-up during the polymerization provides information about the transport of photogenerated charge carriers, and, indirectly, about changes of the average clain lengths in function of the polymer contents. A simple model put forward by the present authors allows for a comparison with the estimates of the chain lengths published earlier.
Groupe de Physique Cristalline, Université de Rennes I, Campus de Beaulieu, Rennes, France
This is a preview of subscription content, log in via an institution to check access.
Preview
Unable to display preview. Download preview PDF.
References
Wegner G (1971) Makromol Chem 145:85–94
Wegner G (1972) Makromol Chem 154:35–48
Cantow HJ (ed) (1984) Polydiacetylenes. Springer, Berlin
Bloor D, Chance RR (eds) (1985) Polydiacetylenes: synthesis, structure and electronic properties. Nijhoff, The Hague
Kobelt D, Paulus EF (1974) Acta Cryst. B30:232–234
Enkelmann V (1977) Acta Cryst. B33:2842–2846
Wegner G (1979) In: Hatfield WE (ed) Molecular Metals. Plenum Press, New York, pp 297–314
Bloor D (1979) Phil Trans Roy Soc London A314:51–68
Baessler H (1984) In: Cantow HJ (ed) Polydiacetylenes. Springer, Berlin, pp 1–48
Enkelmann V (1985) In Cantow HJ (ed) Polydiacetylenes. Springer, Berlin, pp 91–136
Aimé JP, Lefebre J, Bertault M, Schott M, Williams JO (1982) J Physique (Paris) 43:307–322
Orczyk M, Sworakowski J, Schott M, Bertault M (1988) Chem Phys 121:245–254
Bertault M (1983) Thèse. Université Paris VII, France
Bertault M, Schott M, Brienne MJ, Collet A (1984) Chem Phys 85:481–490
Kepler RG (1960) Phys Rev 119:1226–1229
Bloor D, Koski L, Stevens GC, Preston FH, Lando DJ (1975) J Mat Sci 10:1678–1688
Baughman RH (1978) J Chem Phys 68:3110–3121
Albouy PA, Keller P, Pouget P (1982) J Am Chem Soc 104:6556–6561
Kollmar C, Sixl H (1984) In: Sixl H (ed) Proc VW-Symposium “Photoreaktive Festkörper”, Kleinwalsertal, Wahl, Karlsruhe, pp 327–356
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 1989 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
About this paper
Cite this paper
Orczyk, M., Sworakowski, J., Bertault, M. (1989). Photoelectric response in the pTS diacetylene monomer-polymer single crystals. In: Pietralla, M., Pechhold, W. (eds) Relaxation in Polymers. Progress in Colloid & Polymer Science, vol 80. Steinkopff. https://doi.org/10.1007/BFb0115409
Download citation
DOI: https://doi.org/10.1007/BFb0115409
Received:
Accepted:
Published:
Publisher Name: Steinkopff
Print ISBN: 978-3-7985-0832-3
Online ISBN: 978-3-7985-1689-2
eBook Packages: Springer Book Archive