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Rheological properties of fine disperse o/w-emulsions

  • Supramolecular Structures Under Flow
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Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 98))

Abstract

Rheological parameters are important for the characterization of dispersions and emulsions regarding storage stability and application properties. Fine disperse o/w-emulsion concentrates prepared by means of the phase inversion temperature (PIT) method were characterized by dynamic and steady-state rheology, photo correlation spectrocopy for oil droplet size distribution and their phase behaviour. Stable emulsion concentrates show a remarkable yield value and marked shear-thinning flow behaviour. For cosmetic applications as lotions or creams these o/w-emulsion concentrates were diluted up to 80 weight percent water and the desired viscosity was adjusted with a polymer or a self-bodying agent. It could be shown that fatty alcohol thickeners build up a similar gel structure as polymers, when used at higher concentrations. Closer inspection of the rheological profiles reveals remarkable differences in gel properties which can be correlated with advantages in application properties.

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References

  1. Lin TJ (1978) J Soc Cosmet Chem 29:117

    Google Scholar 

  2. Lin TJ, Akabori T, Tanaka S, Shimura K (1981) Cosmet Toil 96:31

    CAS  Google Scholar 

  3. Förster Th, Tesmann H (1991) Cosmet Toil 106:49

    Google Scholar 

  4. Förster Th, Schambil F, Rybinski WV, Dispersion (1992) J Sci Technol, 13:183

    Google Scholar 

  5. Förster Th, Schambil F, Tesmann H (1990) Int J Cosmet Sci 12:33

    Article  Google Scholar 

  6. Barry BW, (1975) Adv Colloid Interface Sci, 5:37

    Article  CAS  Google Scholar 

  7. Barry BW, Saunders GM (1972) J Colloid Interface Sci 5 38:616

    Article  Google Scholar 

  8. Talman FAJ, Rowan EM (1970) J Pharm Pharmae, 22:338

    CAS  Google Scholar 

  9. Davies PJ, Talman PAJ, Expo Congres (1983) Int Techn Pharm 1:337

    CAS  Google Scholar 

  10. Davis SS (1969) J Pharm Sci 58:418

    Article  CAS  Google Scholar 

  11. Eccleston GM (1986) Pharmacy International 63–70

    Google Scholar 

  12. Fukushima S, Takahashi M, Yamaguchi M (1976) J Colloid Interface Sci 57:201

    Article  CAS  Google Scholar 

  13. Krog N, Larsson K (1968) Chem Phys Lipids 2:129

    Article  CAS  Google Scholar 

  14. Pal R (1992) J Rheol 36:1245

    Article  CAS  Google Scholar 

  15. Otsubo Y, Prud'homme RK (1994) Rheol Acta 33:29

    Article  CAS  Google Scholar 

  16. Chen C-R, Zatz JL (1992) J Soc Cosmet Chem 43:1

    CAS  Google Scholar 

  17. Gladwell N, Grimson MJ, Rahalkar RR, Richmond P (1984) J Chem Soc, Faraday Trans 2, 81:643

    Google Scholar 

  18. Sherman P (1968) in: Emuslion Science, Sherman P (Ed), chap 4, 217–347

    Google Scholar 

  19. Tadros ThF, (1992) in: Emulsions — A Fundamental and Practical Approach, J Sjöblom (Ed), NATO ASI Series C, Kluwer 363:173

    Google Scholar 

  20. Barnes H, Hutton JF, Walters K (1989) An Introduction to Rheology, Elsevier, New York

    Google Scholar 

Download references

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J. Appell G. Porte

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© 1995 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Hofmann, R., Förster, T., von Rybinski, W., Wadle, A. (1995). Rheological properties of fine disperse o/w-emulsions. In: Appell, J., Porte, G. (eds) Trends in Colloid and Interface Science IX. Progress in Colloid & Polymer Science, vol 98. Steinkopff. https://doi.org/10.1007/BFb0115218

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  • DOI: https://doi.org/10.1007/BFb0115218

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1031-9

  • Online ISBN: 978-3-7985-1667-0

  • eBook Packages: Springer Book Archive

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