Skip to main content
SpringerLink
Log in
Book cover

Trends in Colloid and Interface Science IX pp 42–46Cite as

Association between hydrophobic polyelectrolytes and nonionic surfactants. Phase behavior and rheology

  • Mixed Systems
  • Conference paper
  • First Online:

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 98))

Abstract

We studied the association between hydrophobically modified poly(sodium acrylate) (HMPA) and nonionic surfactants of the oligoethylene glycol monododecyl ether type (mainly C12E8 and C12E4). The HMPA contains octadecyl chains randomly anchored on 1 or 3 mol% of the monomer units. The association has a large impact on the phase behavior and the rheological properties of the aqueous HMPA/nonionic surfactant mixtures.

Small amounts of HMPA dramatically increase the stability of micellar and lamellar phases of C12E4. In the presence of C12E8 small mixed micelles are formed, including the alkyl side chains of the polymer, acting as crosslinks between the polymer chaisn. On the other hand, C12E4 forms giant vesicle aggregates (above 23 °C) on the surface of which the polymer is adsorbed forming bridges between adjacent vesicles. By utilizing the intrinsic phase behavior of water/nonionic surfactant system, thermal gelation can be induced in the presence of polymer at the temperature corresponding to the formation of bilayers in the binary surfactant/water system.

This is a preview of subscription content, log in via an institution.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Goddard ED (1986) Colloids Surf 19:301

    Article  CAS  Google Scholar 

  2. Hayakawa K, Kwak JCT (1991) In: Rubingh D, Holland PM (eds) Cationic Surfactants Physical Chemistry. Marcel Dekker, New York, pp 189

    Google Scholar 

  3. Lindman B, Thalberg K (1992) In: Goddard ED, Ananthapadmanabham K (eds) Polymer-Surfactant Interaction. C.R.C. Press, Boca Raton, pp 203

    Google Scholar 

  4. Magny B, Iliopoulos I, Audebert R, Piculell L, Lindman B (1992) Prog Colloid Polym Sci 89:118–121

    Article  CAS  Google Scholar 

  5. McCormick CL, Nonaka T, Johnson CB (1988) Polymer 29:731–739

    Article  CAS  Google Scholar 

  6. Binana-Limbele W, Clouet F, François J (1993) Colloid Polym Sci: 748–758

    Google Scholar 

  7. Landoll LM (1982) J Polym Sci Polym Chem 20:443–455

    CAS  Google Scholar 

  8. Valint PL, Bock J (1988) Macromolecules 21:175–179

    Article  CAS  Google Scholar 

  9. Wang TK, Iliopoulos I, audebert R (1991) In: Shalaby SW, McCormick CL, Butler GB (eds) Water Soluble Polymers. Synthesis, Solution properties and Applications; ACS Symposium Series 467, American Chemical Society: Washington, DC, pp 218–231

    Google Scholar 

  10. Biggs S, Hill A, Selb J, Candau F (1992) J PHys Chem 96:1505–1511

    Article  CAS  Google Scholar 

  11. Wang TK, Iliopoulos I, Audebert R (1988) Polym Bull 20:577–582

    Article  CAS  Google Scholar 

  12. Nilsson PG, Wennerström H, Lindman B (1989) J Phys Chem 87:1377–1385

    Article  Google Scholar 

  13. Henriksson U, Jonströmer M, Olsson U, Söderman O, Klose G (1991) J Phys Chem 95:3815–3819

    Article  CAS  Google Scholar 

  14. Mitchell DJ, Tiddy GJT, Waring L, Bostock T, McDonald MP (1981) J Chem Soc, Faraday Trans 1 79:975–1000

    Article  Google Scholar 

  15. Kunieda H, Nakamura K, Davis HT, Evans DF (1991) Langmuir 7:1915–1919

    Article  CAS  Google Scholar 

  16. Sarrazin-Cartalas A, Iliopoulos I, Audebert R, Olsson U (1994) Langmuir 10:1421–1426

    Article  CAS  Google Scholar 

  17. Iliopoulos I, Wang TK, Audebert R (1991) Langmuir 7:617–619

    Article  CAS  Google Scholar 

  18. Jonströmer M, Strey R (1992) J Phys Chem 96:5993–6000

    Article  Google Scholar 

  19. Iliopoulos I, Olsson U (1994) J Phys Chem 98:1500–1505

    Article  CAS  Google Scholar 

  20. Douglas CB, Kaler EW (1994) J Chem Soc Faraday Trans 90(3):471–477

    Article  CAS  Google Scholar 

  21. Biggs S, Selb J, Candau F (1993) Polymer 34(3):580–591

    Article  CAS  Google Scholar 

  22. Ferry JD (1980) In: Viscoelastic Properties of Polymer. 3rd ed. John Wiley, New York

    Google Scholar 

  23. Olsson U, Strey R, unpublished results

    Google Scholar 

  24. Schomäcker R, Strey R (1994) J Phys Chem 98:3908–3912

    Article  Google Scholar 

  25. Hofland HEJ, Bouwstra JA, Gooris GS, spies F, Talsma H, Junginger HE (1993) J Colloid Interface Sci 161:366–376

    Article  CAS  Google Scholar 

  26. Carlsson A, Karlström G, Lindman B (1990) Colloids Surf 47:147–167

    Article  CAS  Google Scholar 

  27. Carlsson A, Karlström G, Lindman B, Stenberg O (1988) Colloid Polym Sci 266:1031–1036

    Article  CAS  Google Scholar 

  28. Karlström G, Carlsson A, Lindman B (1990) J Phys Chem 94:5005–5015

    Article  Google Scholar 

  29. Carlsson A, Lindman B, Watanabe T, Shirahama K (1989) Langmuir 5:1250

    Article  CAS  Google Scholar 

  30. Carlsson A, Karlström G, Lindman B (1989) J Phys Chem 93:3673–3677

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Physico-Chimie Macromoléculaire, Université Pierre et Marie Curie CNRS URA 278 E.S.P.C.I., 10 rue Vauquelin, 75231, Paris Cedex 5, France

    K. Loyen, I. Iliopoulos & R. Audebert

  2. Physical Chemistry 1 Chemical Center, Lund University, P.O. Box 124, x22100, Lund, Sweden

    U. Olsson

Authors
  1. K. Loyen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. Iliopoulos
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. Audebert
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. U. Olsson
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

J. Appell G. Porte

Rights and permissions

Reprints and permissions

Copyright information

© 1995 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

About this paper

Cite this paper

Loyen, K., Iliopoulos, I., Audebert, R., Olsson, U. (1995). Association between hydrophobic polyelectrolytes and nonionic surfactants. Phase behavior and rheology. In: Appell, J., Porte, G. (eds) Trends in Colloid and Interface Science IX. Progress in Colloid & Polymer Science, vol 98. Steinkopff. https://doi.org/10.1007/BFb0115205

Download citation

  • DOI: https://doi.org/10.1007/BFb0115205

  • Published:

  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1031-9

  • Online ISBN: 978-3-7985-1667-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation