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New Developments pp 35–90Cite as

Synergic extraction of actinides

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Part of the book series: Structure and Bonding ((STRUCTURE,volume 56))

Abstract

Studies on the solvent extraction of actinide ions by different combinations of extractants have been reviewed. Various equilibria involved in the extraction processes and the formation of the extractable complexes have been considered along with their equilibrium constant data. Various methods which are useful in establishing the composition and the nature of the extractable complexes are presented. The data on isolation and structural studies of some complexes, involved in synergic extraction, are also included. A brief description of the different areas in which synergic extraction is finding application is also given. Many combinations of extractants, where the studies conducted are very few but, which are likely to yield enhanced extractions are indicated. Areas of research, both from the academic and applied points of view, which require attention are suggested.

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Abbreviations

TOPO:

tri-n-octyl phosphine oxide

TBPO:

tri-n-butyl phosphine oxide

TEHPO:

tri-2, ethylhexyl phosphine oxide

TPPO:

tri-phenyl phosphine oxide

BDBP:

n-butyl, di(n-butyl) phosphinate

DBBP:

di(n-butyl), n-butyl phosphonate

DAMP:

di(isopantyl), methyl phosphonate

DEEP:

di(ethyl), ethyl phosphonate

TMP:

trimethylphosphate

TBP:

tri-n-butyl phosphate

TEP:

tri ethyl phosphate

TPrP:

tri propyl phosphate

DBDECMP:

dibutyl-N, N-diethylcarbamoyl methylene phosponate

TPP:

tri phenyl phosphate

TBTP:

tributyl thio phosphate

TIOTP:

tri isoocytl thio phosphate

TLAO:

tri lauryl amine oxide

PO:

Pyridine-N-oxide

2 MPO:

2-methyl, pyridine-N-oxide

3MPO:

3-methyl, pyridine-N-oxide

4MPO:

4-methyl, pyridine-N-oxide

4MOPO:

4-methoxy, pyridine-N-oxide

4CPO:

4-chloro pyridine-N-oxide

4NPO:

4-nitro pyridine-N-oxide

2,6-DMPO:

2,6-dimethyl, pyridine-N-oxide

DMSO:

dimethyl sulphoxide

D-n-PSO:

di(n-pentyl) sulphoxide

DHSO:

dihexyl sulphoxide

DOSO:

dicotyl sulphoxide

DISO:

di(isooctyl) sulphoxide

DDSO:

didecyl sulphoxide

DBSO:

dibenzyl sulphoxide

DPSO:

diphenyl sulphoxide

MIBK:

methyl isobutyl ketone

DMF:

dimethyl formamide

DBE:

di-n-butyl ether

DIBE:

di-(isobutyl) ether

DBS:

dibutyl thio ether

DBSO2 :

dibutyl sulfone

DPE:

diphenyl ether

DPS:

diphenyl thio ether

DPSe:

diphenyl seleno ether

n-BA:

n-butylalcohol

N Bu:

nitrobutane

N Be:

nitrobenzene

DEA:

N,N-diethylacetamide

DIPY:

di-pyridyl

PHEN:

O-phenanthroline

HTTMA:

thenoyl trifluoro (methyl) acetone

HDBM:

dibenzoyl methane

HTR:

Tropolone

HIPT:

β-isopropyl tropolone

HOx :

oxine (8-hydroxy quinoline)

HDBHQ:

5,7-dibromo, 8-hydroxy-quinoline

HCF:

Cupferron

HBPHA:

N-benzoyl, N-phenyl, hydroxylamine

HPMBP:

1-phenyl, 3-methyl, 4-benzoyl, pyrazolone-5

HDEHP:

di(2-ethylhexyl) phosphoric acid

HDBP:

di(butyl) phosphoric acid

HDAP:

di(isopentyl) phosphoric acid

HAMP:

isopentyl methyl phosphoric acid

HDOPP:

di(4-octyl phenyl) phosphoric acid

DIDP:

di(isodecyl) phosphoric acid

H2MEHP:

mono, 2-ethylhexyl, phosphoric acid

H2MBP:

mono, butyl, phosphoric acid

HBz :

benzoic acid

HDNNS:

di, nonyl, naphthalene sulphonic acid

HDMPP:

3,5-dibutyl, 1-methyl, 4-propylpyrazole

HAA:

acetyl acetone

Claa:

3-chloro, pentane 2,4-dione

HBA:

benzoyl acetone

HTA:

thenoyl acetone

HTFA:

trifluoro acetyl acetone

HHFA:

hexafluoro acetyl acetone

HBTA:

benzoyl trifluoro acetone

HFTA:

furoyl trifluoro actone

HTTA:

thenoyl trifluoro acetone

ALIQ:

aliquat-336, a quaternary amine

Q:

capriquat (or)

TOMA:

Tri-n-octyl methyl ammonium, a quaternary amine

TOA:

tri-n-octyl amine

TLA:

tri lauryl amine

MNDDA:

N-methyl didecyl amine

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  1. Radiochemistry Division, Bhabha Atomic Research Centre, 400 085, Trombay, Bombay, India

    V. V. Ramakrishna & S. K. Patil

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Ramakrishna, V.V., Patil, S.K. (1984). Synergic extraction of actinides. In: New Developments. Structure and Bonding, vol 56. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0111654

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