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The behavior of ferric oxide hydrosols in the presence of urea

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Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 105))

Abstract

The effect of urea on the stability of α-haematite hydrosols in the presence of various monovalent ions was studied on each side of the pzc (pH 8.2) by measurements of the critical coagulation concentration (CCC) of the hydrosol.

It was observed that for pHs lower than the pzc, the effect of urea depends strongly on the nature of coagulating ion and on the pH:The CCC values of IO 3 increases with urea concentrations but those of ClO 4 and Cl decreases. For pHs higher than the pzc, an inversion of the cationic adsorption sequence was observed. This behavior is in a good agreement with the well-known action of urea on the structure of water and also with the general property of the α-haematite water interface.

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References

  1. Amhamdi H, Dumont F, Buess-Herman C, Colloids Surf to be published

    Google Scholar 

  2. Dumont F, DangVan Tan, Watillon A (1976) J Colloid Interface Sci 55:678–687

    Article  CAS  Google Scholar 

  3. Gierst L, Vandenberghen L, Nicolas E, Fraboni A (1966) J Electrochem Soc 113:1025

    Article  CAS  Google Scholar 

  4. Gurney RW (1953) Ionic Processes in solutions. McGraw-Hill, New York, pp 248–261

    Google Scholar 

  5. Healy TW, Herring AP, Fuerstenau DW (1966) J Coll Interface Sci 21:435

    Article  CAS  Google Scholar 

  6. Dumont F, Warlus J, Watillon A (1990) J Coll Interface Sci 138(2):543

    Article  CAS  Google Scholar 

  7. Brandts JF, Hunt LJ (1967) J Am Chem Soc 89:4826–4838

    Article  CAS  Google Scholar 

  8. Watlaufer DB, Malik SK, Stoller L, Coffin RI (1994) J Am Chem Soc 86:508–514

    Article  Google Scholar 

  9. Brunig W, Holtzer A (1961) J Am Chem Soc 83:4865–4866

    Article  Google Scholar 

  10. Frank HS, Franks F (1968) J Chem Phys 48:4746–4757

    Article  CAS  Google Scholar 

  11. Repley JA (1964) J Phys Chem 68:2002–2003

    Article  Google Scholar 

  12. Israelachvilli JN (1992) Intermolecular and Surface Forces 2nd ed, Academic Press, London, pp 135

    Google Scholar 

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J. B. Rosenholm B. Lindman P. Stenius

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Dedicated to the memory of Julie and Mélissa

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© 1997 Steinkopff Verlag

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Amhamdi, H., Dumont, F., Buess-Herman, C. (1997). The behavior of ferric oxide hydrosols in the presence of urea. In: Rosenholm, J.B., Lindman, B., Stenius, P. (eds) Trends in Colloid and Interface Science XI. Progress in Colloid & Polymer Science, vol 105. Steinkopff. https://doi.org/10.1007/BFb0110959

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  • DOI: https://doi.org/10.1007/BFb0110959

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1086-9

  • Online ISBN: 978-3-7985-1660-1

  • eBook Packages: Springer Book Archive

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