Abstract
The effect of urea on the stability of α-haematite hydrosols in the presence of various monovalent ions was studied on each side of the pzc (pH 8.2) by measurements of the critical coagulation concentration (CCC) of the hydrosol.
It was observed that for pHs lower than the pzc, the effect of urea depends strongly on the nature of coagulating ion and on the pH:The CCC values of IO −3 increases with urea concentrations but those of ClO −4 and Cl− decreases. For pHs higher than the pzc, an inversion of the cationic adsorption sequence was observed. This behavior is in a good agreement with the well-known action of urea on the structure of water and also with the general property of the α-haematite water interface.
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Amhamdi, H., Dumont, F., Buess-Herman, C. (1997). The behavior of ferric oxide hydrosols in the presence of urea. In: Rosenholm, J.B., Lindman, B., Stenius, P. (eds) Trends in Colloid and Interface Science XI. Progress in Colloid & Polymer Science, vol 105. Steinkopff. https://doi.org/10.1007/BFb0110959
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DOI: https://doi.org/10.1007/BFb0110959
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