Abstract
The discovery of a large number of shallow and deep levels in ultra-pure germanium has led to a renewed interest in this elemental semiconductor. The new levels are created by complexes typically consisting of one substitutional impurity such as silicon, oxygen, carbon, beryllium, zinc, copper, etc. and one or more interstitial impurities such as hydrogen or lithium. The experimental techniques and results which have been used to determine the structure and composition of these centers are reviewed. One of the most intriguing features of the acceptor centers, an electronic ground-state which does not split under uniaxial compression, has been explained with a tunneling impurity model.
Double acceptors, helium analoga in semiconductors, have been investigated recently with IR spectra and photoluminescence. The new results indicate that contrary to earlier assumptions all double acceptors exhibit split ground-states, a consequence of the hole-hole interaction.
Preview
Unable to display preview. Download preview PDF.
References
C. Winkler, J. f. praktische Chemie, Neue Folge 34, 177 (1886)
H. J. Queisser, Kristallene Krisen, (Piper, München 1985)
E. E. Haller, W. L. Hansen, and F. S. Goulding, Adv. in Physics 30, 93 (1981)
W. L. Hansen and E. E. Haller, Mat. Res. Symp. Proc. 16, 1 (1983)
E. E. Haller and F. S. Goulding, Handbook on Semiconductors Vol. 4, Ch. 6, 799–827, ed. by C. Hilsum (North-Holland, Amsterdam 1981)
R. N. Hall, IEEE Trans. Nucl. Sci. NS-21, 260 (1974) and Inst. Phys. Conf. Series 23, 190 (1975)
N. M. Haegel and E. E. Haller, SPIE Conf. on Materials Techn. for IR Detectors, April 15–17 1986, Innsbruck, Austria, SPIE Proc. Vol. 659, in print
N. M. Haegel, PhD Thesis, UC Berkeley and Lawrence Berkeley Laboratory, LBL 20627
R. E. McMurray Jr., N. M. Haegel, J. M. Kahn, and E. E. Haller, Sol. State Cormm. in print
E. E. Haller, R. E. McMurray Jr., N. M. Haegel, and L. M. Falicov, Proc. 17th Int. Conf. Phys. of Semicond., ed. by J. D. Chadi and W. A. Harrisor (Springer, Berlin 1985), p. 679–682
V. V. Emtsev, T. V. Mashovets, E. Kh. Nazaryan, and E. E. Haller, Sov. Phys. Sermic. 16, 182 (1982)
N. Fukuoka and H. Saito, Physica 116B, 343 (1983)
N. Fukuoka and H. Saito, Jap. J. Appl. Phys. 23, 203 (1984)
E. E. Haller, P. Po-Yee Li, G. S. Hubbard, and W. L. Hansen, IEEE Trans. Nucl. Sci. NS-26, No. 1, 265 (1979)
E. Simoen, P. Clauws, and J. Vennik, J. Phys. D: Appl. Phys. 18, 2041 (1985)
L. J. van der Pauw, Phillips Res. Repts. 13, 1 (1958)
J. H. Yee, S. P. Swierkowski, G. A. Armantrout, and R. Wichner, J. Appl. Phys. 45, 3949 (1974)
T. M. Lifshits and F. Ya. Nad, Sov. Phys.-Doklady 10, 532 (1965) for a review see: Sh. M. Kogan and T. M. Lifshits, phys. stat. sol. (a) 39, 11 (1977)
C. Kittel and A. H. Mitchell, Phys. Rev. 96, 1488 (1954)
R. A. Faulkner, Phys. Rev. 184, 713 (1969)
A. Baldereschi and N. O. Lipari, Phys. Rev. B 8, 2697 (1973); Phys. Rev. B9, 1525 (1974) and Proc. 13th Int. Conf. Phys. Semic., ed. by F. G. Fumi (North-Holland 1976), p. 595
J. Broeckx, P. Clauws, and J. Vennik, J. Phys. C: Solid St. Physics, in print
A. K. Ramdas and S. Rodriguez, Rep. Prog. Phys. 44, 1297 (1981)
B. I. Shklovskii and A. L. Efros, Electronic Properties of Doped Semiconductors, Solid State Sciences, Vol. 45 (Springer, Berlin 1984)
Sh. m. Kogan, Sov. Phys. Semicond. 1, 828 (1973)
A. S. Barker and A. J. Sievers, Rev. Mod. Phys. 47, Suppl. 2, 1 (1975)
R. N. Hall and J. H. Racette, J. Appl. Phys. 35, 379 (1964)
G. Dearnaley, J. H. Freeman, G. A. Gard, and M. A. Wilkins, Can. J. Phys. 46, 587 (1968)
see: Table of Isotopes, ed. by C. M. Lederer and V. S. Shirley, (7th ed., Wiley, New York 1978)
C. Sonntag, H. Rebel, B. Ribbat, S. K. Thio, and W. R. Gramm, Lett. Nuovo Cim. IV, 717 (1970)
M. Hansen and K. Anderko, Constitution of Binary Alloys (McGraw-Hill, New York 1958)
E. E. Haller, W. L. Hansen, P. Luke, R. McMurray Jr., and B. Jarret, IEEE Trans. Nucl. Sci. NS-29, No. 1, 745 (1982).
P. N. Luke and E. E. Haller, J. Appl. Phys. in print
E. Gatti and P. Rehak, Nucl. Instr. and Methods 225, No.3, 608 (1984)
J. Martin and E. Haas, Sol. State Electr. 11, 993 (1968)
W. L. Hansen, E. E. Haller, and P. N. Luke, IEEE Trans. Nucl. Sci. NS-29, No. 1, 738 (1982)
E. E. Haller, Phys. Rev. Lett. 40, 584 (1978)
E. E. Haller and L. M. Falicov, Phys. Rev. Lett. 41, 1192 (1978) and Inst. Phys. Conf. Ser. 43, 1039 (1979)
L. M. Falicov and E. E. Haller, Solid State Comm. 53, 1121 (1985)
B. Joos, E. E. Haller, and L. M. Falicov, Phys. Rev. B 22, 832 (1980)
J. Broeckx, P. Clauws, and J. Vennik, J. Phys. C: Solid St. Physics 13, L141 (1980)
E. E. Haller, G. S. Hubbard, W. L. Hansen, and A. Seeger, Inst. Phys. Conf. Ser. 31, 309 (1977)
N. M. Haegel, E. E. Haller, and P. Luke, Int. J. Infrared and MM Waves 4, No. 6, 945 (1983)
E. E. Haller, Infrared Physics 25, 257, (1985)
R. E. McMurray Jr., N. M. Haegel, J. M. Kahn, and E. E. Haller, Solid State Comm. 53, 1137 (1985)
H. Reiss, C. S. Fuller, and F. J. Morin, Bell Syst. Tech. J. 35, 535 (1956)
C. Kittel and J. Wang, Phys. Rev. B 7, 713 (1973)
J. I. Pankove, P. J. Zan Zucchi, C. W. Magee, and G. Lucovsky, Appl. Phys. Lett. 46, 421 (1985)
C. S. Fuller and J. C. Severins, Phys. Rev. 96, 21 (1954)
A. Schenck, Muon Spin Rotation Spectroscopy (Adam Hilger, Bristol 1985) and references therein
S. F. J. Cox and M. C. R. Symon, Chem. Phys. Lett., in print; also Rutherford Appleton Lab. Report RAL-85-114
G. Flik, J. Bradbury, W. Cooke, R. Heffner, M. Leon, M. Paciotti, M. Schillaci, K. Maier, H. Rempp, J. Reidy, C. Boekema, and H. Daniel, Phys. Rev. Lett., to be published
F. Hashimoto and Y. Kamiura, Jap. J. Appl. Phys. 13, 762 (1974)
Y. Kamiura, F. Hashimoto, T. Takada, Y. Sakaji, and T. Hattori, Inst. Phys. Conf. Ser. 59, 182 (1981)
J. Broeckx, Y. Kamiura, P. Clauws, and J. Vennik, Solid State Commun. 43, 499 (1982)
Y. Kamiura and F. Hashimoto, phys. stat. sol. (a) 85, 227 (1984)
see papers in Proc. 13th Int. Conf. on Defects in Semiconductors, ed by L. C. Kimmerling and J. M. Parsey Jr., AIME Publ. 14a, (1985)
P. Clauws and J. Vennik, Phys. Rev. B 30, 4837 (1984)
P. Clauws, E. Simoen, and J. Vennik, Proc. 13th Int. Conf. on Defects in Semic., ed. by L. C. Kimmerling and J. M. Parsey Jr. (AIME Publ. 14a, 1985), p. 911
E. E. Haller and R. E. McMurray Jr., Physica 116B + C, 349 (1983)
J. W. Cross, L. T. Ho, A. K. Ramdas, R. Sauer, and E. E. Haller, Phys. Rev. B 28, 6953 (1983)
R. A. Chapman and W. G. Hutchinson, Phys. Rev. 157, 615 (1967); and Solid State Comm. 3, 293 (1965)
J. W. Cross, C. R. La Brec, S. Rodriguez, A. K. Ramdas, and E. E. Haller, Phys. Rev. B 32, 7992 (1985)
W. J. Moore, Phys. Rev. B 29, 7062 (1984)
N. R. Butler and P. Fisher, Phys. Rev. B 13, 5465 (1976)
For a review on BE and BMEC in silicon see: M. L. W. Thewalt, in “Excitons”, ed. by E. I. Rashba and M. D. Sturge (North-Holland, Amsterdam 1982), p. 393–458
G. C. Osborn and D. L. Smith, Phys. Rev. B 16, 5426 (1977)
R. Sauer and J. Weber, J. Phys. C: Solid State Phys. 17, 1421 (1984)
M. L. W. Thewalt, E. C. Lightowlers, and E. E. Haller, Solid State Commun. 54, 1043 (1985)
H. Nakata, T. Yodo, and E. Otsuka, Solid State Commun. 45, 55 (1983)
H. Nakata and E. Otsuka, J. Phys. Soc. Japan, 55, 391 (1986), in print
M. L. W. Thewalt, D. Labrie, E. C. Lightowlers, and E. E. Haller, Solid State Commun., to be published
M. L. W. Thewalt, D. Labrie, and B. P. Clayman, Solid State Commun. 56, 751 (1985)
H. Nakata, E. Otsuka, and E. E. Haller, Jap. J. Appl. Phys. 25, L57 (1986)
M. L. W. Thewalt, B. P. Clayman, and D. Labrie, Phys. Rev. B 32, 2663 (1985)
E. E. Haller, R. E. McMurray Jr., L. M. Falicov, N. M. Haegel, and W. L. Hansen, Phys. Rev. Lett. 51, 1089 (1983)
E. E. Haller, R. E. McMurray Jr., N. M. Haegel, and L. M. Falicov, Proc. 17th Int. Conf. Phys. Semic., ed. by J. D. Chadi and W. A. Harrison (Springer, New York 1985), p. 679–682
R. E. McMurray Jr., Sol. State Commun. 53, 1127 (1985)
E. E. Haller, Proc. Mat. Res. Soc. Vol. 46, 495 (1985)
S. J. Pearton, Proc. Mat. Res. Soc. Vol. 59 (1986), in print
S. J. Pearton, E. E. Haller, and A. G. Elliott, Electron. Lett. 19, No. 24, 1052 (1983)
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 1986 Friedr. Vieweg & Sohn Verlagsgesellschaft mbH
About this chapter
Cite this chapter
Haller, E.E. (1986). Semiconductor physics in ultra-pure germanium. In: Grosse, P. (eds) Festkörperprobleme 26. Advances in Solid State Physics, vol 26. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0107798
Download citation
DOI: https://doi.org/10.1007/BFb0107798
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-528-08032-7
Online ISBN: 978-3-540-75359-9
eBook Packages: Springer Book Archive