Abstract
The objective of this chapter is to provide the reader with a general account of various aspects of lignin chemistry with emphasis on issues that have seen rapid growth during the past two decades. This is accomplished by describing the research efforts of over 360 literature citations, embarking from early concepts and concluding with the current views on the subject.
After a general introduction that deals with the occurrence and role of lignin in the cell wall and within woody tissue, recent advances of lignin biosynthesis are discussed commencing with a description of the metabolic pathways that determine the synthesis of the various lignin precursors. The main reactions leading to the various bonding patterns in lignin are then discussed including accumulating evidence that pertains to the connectivity of lignin to carbohydrates. The overal architecture of the lignin macromolecule is then dealt with by critically examining various aspects of the early literature and recent scientific evidence that points to the possibility of order in it. After a brief description of the methods available to isolate lignin, the chapter concludes with an outline of the various major procedures currently available for its structural determination.
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Argyropoulos, D.S., Menachem, S.B. (1997). Lignin. In: Eriksson, K.E.L., et al. Biotechnology in the Pulp and Paper Industry. Advances in Biochemical Engineering/Biotechnology, vol 57. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0102073
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