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Hybridization schemes for co-ordination and organometallic compounds

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Bioinorganic Chemistry

Part of the book series: Structure and Bonding ((STRUCTURE,volume 72))

Abstract

The important hybridization schemes for co-ordination and organometallic compounds have been derived using a methodology based on a spherical harmonic expansion of the hybridized orbitals. For spherical co-ordination compounds MLn it is possible to define a set of n hybrids which have their maxima in the metal-ligand directions and 9-n d orbitals or hybrids which have nodes along the metal-ligand bonds. The latter are important for π-bonding to the ligands.

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Authors and Affiliations

  1. Inorganic Chemistry Laboratory, University of Oxford, OX1 3QR, South Parks Road, Oxford, UK

    D. Michael, P. Mingos & Lin Zhenyang

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  1. D. Michael
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  2. P. Mingos
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  3. Lin Zhenyang
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© 1990 Springer-Verlag

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Michael, D., Mingos, P., Zhenyang, L. (1990). Hybridization schemes for co-ordination and organometallic compounds. In: Bioinorganic Chemistry. Structure and Bonding, vol 72. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0058196

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  • DOI: https://doi.org/10.1007/BFb0058196

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-51574-6

  • Online ISBN: 978-3-540-46668-0

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