Skip to main content
SpringerLink
Log in

Entwicklung und präparative Möglichkeiten der Carben-Chemie

Erster Teil

  • Conference paper
  • First Online:
Organische Synthesen

Part of the book series: Fortschritte der Chemischen Forschung ((TOPCURRCHEM,volume 5/1))

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literatur

  1. Anderson, J. C., and C. B. Reese: Competitive Insertion of a Dihalocarbene in an Olefin. Chem. and Ind. 1963, 575.

    Google Scholar 

  2. Andreades, S.: Evidence for Net Insertion of Difluorocarbene in a N-F Bond. Chem. and Ind. 1962, 782.

    Google Scholar 

  3. Atkinson, B., and V. A. Atkinson: The Thermal Decomposition of Tetrafluoroethylene. J. chem. Soc. (London) 1957, 2086.

    Google Scholar 

  4. Badea, F., u. C. D. Nenitzescu: Neue Methode zur Darstellung von Carbenen. Angew. Chem. 72, 415 (1960).

    CAS  Google Scholar 

  5. Ball, W. J., and S. R. Landor: The Addition of Carbenes to Allenes. Proc. chem. Soc. (London) 1961, 246.

    Google Scholar 

  6. Banus, J., H. J. Emeleus, and R. N. Haszeldine: The Heterolytic Fission of the Carbon-Iodine Bond in Trifluoroiodmethane. J. chem. Soc. (London) 1951, 60.

    Google Scholar 

  7. Bergman, E.: Reactions Related to the Addition of Dichlorocarbene to Norbornylene. J. org. Chemistry 28, 2210 (1963).

    CAS  Google Scholar 

  8. Bevan, W. I., R. N. Haszeldine, and J. C. Young: A New Route to Carbenes. Chem. and Ind. 1961, 789.

    Google Scholar 

  9. Bezaguet, A.: Action des dihalogénocarbènes sur les dialcoyl-3.3-diènes-1.2. C. R. hebd. Séances Acad. Sci. 254, 3371–3373 (1962).

    CAS  Google Scholar 

  10. Birchall, J. M., G. W. Cross, and R. N. Haszeldine: Difluorocarbene. Proc. chem. Soc. (London) 1960, 81.

    Google Scholar 

  11. Blanchard, E. P., and H. E. Simmons: Cyclopropane Synthesis from Methylene Iodide, Zinc-Copper Couple, and Olefins. II. J. Amer. chem. Soc. 86, 1337 (1964).

    CAS  Google Scholar 

  12. Bohm, B. A., and P. I. Abell: Stereochemistry of Free Radical Additions to Olefins. (Übersichtsreferat.) Chem. Reviews 62, 599–609 (1962).

    CAS  Google Scholar 

  13. Boutlerow, M. A.: Sur un nouveau mode de formation de l'éthylène et de quelquesuns de ses congénères. C. R. hebd. Séances Acad. Sci. 53, 247 (1861).

    Google Scholar 

  14. Chambers, R. D., H. C. Clark, and J. C. Willis: Some Salts of Trifluoromethylfluoboric Acid. J. Amer. chem. Soc. 82, 5298 (1960).

    CAS  Google Scholar 

  15. Chinoporos, E.: Carbenes. Reactive Intermediates Containing Divalent Carbon. (Übersichtsreferat.) Chem. Reviews 63, 235 (1963).

    CAS  Google Scholar 

  16. Clark, H. C., and J. C. Willis: Perfluoralkyl Derivatives of Tin. I. Trimethyltrifluoromethyltin. J. Amer. chem. Soc. 82, 1888 (1960).

    CAS  Google Scholar 

  17. Closs, G. L., and L. E. Closs: Synthesis of Chlorocyclopropanes from methylene Chloride and Olefins. J. Amer. chem. Soc. 81, 4996 (1959).

    CAS  Google Scholar 

  18. --: Addition of Chlorocarbene to Benzene. Tetrahedron Letters (London) 1960, Nr 10, 38.

    Google Scholar 

  19. --: Carbenes from Alkyl Halides and Organo-Lithium Compounds. I. Synthesis of Chlorocyclopropanes. J. Amer. chem. Soc. 82, 5723 (1960).

    CAS  Google Scholar 

  20. --: Carbenes from Alkyl Halides and Organo-Lithium Compounds. II. The Reactivity of Chlorocarbene in its Additions to Olefins. J. Amer. chem. Soc. 82, 5729 (1960).

    CAS  Google Scholar 

  21. --: Carbenes from Alkyl Halides and Organo-Lithium Compounds. III. Syntheses of Alkyltropones from Phenols. J. Amer. chem. Soc. 83, 599 (1961).

    CAS  Google Scholar 

  22. -: Carbenes from Alkyl Halides and Organo-Lithium Compounds. IV. Formation of Alkylcarbenes from Methylene Chloride and Alkyl-Lithium Compounds. J. Amer. chem. Soc. 84, 809 (1962).

    CAS  Google Scholar 

  23. -, and J. J. Coyle: The preparation, Pyrolysis and Photolysis of Chlorodiazomethane. J. Amer. chem. Soc. 84, 4350 (1962).

    CAS  Google Scholar 

  24. -, R. A. Moss, and J. J. Coyle: Steric Course of some Carbenoid Additions to Olefins. J. Amer. chem. Soc. 84, 4985 (1962).

    CAS  Google Scholar 

  25. -, and L. E. Closs: Carbenes from Alkyl Halides and Organolithium Compounds. V. Formation of Alkylcyclopropenes by Ring Closure of Alkenyl Substituted Carbenoid Intermediates. J. Amer. chem. Soc. 85, 99 (1963).

    CAS  Google Scholar 

  26. --, and W. Böll: The Base-Induced Pyrolysis of Tosylhydrazones of α,β-Unsaturated Aldehydes and Ketones. A Convenient Synthesis of some Alkylcyclopropenes. J. Amer. chem. Soc. 85, 3796 (1963).

    CAS  Google Scholar 

  27. Coates, G. E.: Organometallic Compounds, 2. Ausgabe. London: Methuen & Co. 1960.

    Google Scholar 

  28. Collette, J. W.: The Reaction of Trisobutylaluminium with Carbon Tetrachloride. A Novel Preparation of Diisobutylaluminium Chloride. J. org. Chemistry 28, 2489 (1963).

    CAS  Google Scholar 

  29. Cook, A. G., and E. K. Fields: Reaction of Dichlorocarbene with Imines. J. org. Chemistry 27, 3686–3687 (1962).

    CAS  Google Scholar 

  30. Cook, C. E., and M. E. Wall: The Reaction of Dichlorocarbene with Enol Acetates — Novel 2.2-Dichloro-1-steroidalcyclopropyl Acetates. Chem. and Ind. 1963, 1927.

    Google Scholar 

  31. Crawford, R. J., and R. Raap: Homolytic Decomposition of Diethoxydiazomethane. Proc. Chem. Soc. (London) 1963, 370.

    Google Scholar 

  32. Cudlín, J., and V. Chvalovsky: Organo Silicon Compounds. XXXII. Addition of Dichloromethylene to Vinylmethyl-and Allylmethylsiloxanes. Coll. Czechoslov. chem. Commun. 28, 3088 (1963).

    Google Scholar 

  33. De Selms, R. C.: Brief Survey of Carbene Chemistry. Org. chem. Bull. 34, 5 (1962).

    Google Scholar 

  34. -, and C. M. Combs: Addition Products of Dichlorocarbene to Norbornylene and Norbornadiene and their Rearrangements. J. org. Chemistry 28, 2206 (1963).

    Google Scholar 

  35. Doering, W. v. E., and A. K. Hoffmann: The Addition of Dichlorocarbene to Olefins. J. Amer. chem. Soc. 76, 6162 (1954).

    CAS  Google Scholar 

  36. -, and P. M. La Flamme: The cis-Addition of Dibromocarbene and Methylene to cis-and trans-Butene. J. Amer. chem. Soc. 78, 5447 (1956).

    CAS  Google Scholar 

  37. -, and L. H. Knox: The Reaction of Carbalkoxycarbene with Saturated Hydrocarbons. J. Amer. chem. Soc. 78, 4947 (1956).

    CAS  Google Scholar 

  38. -, and P. M. La Flamme: A two Step Synthesis of Allenes from Olefins. Tetrahedron (London) 2, 75 (1958).

    Google Scholar 

  39. -, and W. A. Henderson jr.: Electron-seeking Demands of Dichlorocarbene in its Addition to Olefins. J. Amer. chem. Soc. 80, 5274 (1958).

    CAS  Google Scholar 

  40. -, and W. Kirmse: The Absolute Configuration of Trans-1.2-Dimethylcyclopropane. Tetrahedron (London) 11, 272 (1960).

    CAS  Google Scholar 

  41. Duchesne, J., and L. Burnelle: Ground and Excited Electronic States and Molecular Vibrations of some Poliatomic Molecules. J. chem. Physics 21, 2005 (1953).

    CAS  Google Scholar 

  42. Dumas, M. M. J., et E. Péligot: Mémoire sur l'esprit de Bois et sur les divers composés ethérés qui en proviennent. Ann. Chim. Phys. 58, 9 (1835).

    Google Scholar 

  43. D'Yakonov, I. A., T. V. Nizovkina, and T. A. Kornilova: On the Reaction of Dichlorocarbene with Chloroprene. J. allg. Chem. 32, 664–665 (1962), Engl. Übers. J. Gen. Chem. USSR 32, 664–665 (1962).

    Google Scholar 

  44. -, and L. P. Danilkina: Reactions of Dichloro-and Carbethoxycarbene with 2-Methylpenten-1-yne-3. J. allg. Chem. 32, 1008–1009 (1962), Engl. Übers. in J. Gen. Chem. USSR 32, 994–995 (1962).

    Google Scholar 

  45. Farah, B., and S. Horensky: Sym-difluorotetrachloroacetone as a Source of Chlorofluorocarbene. J. org. Chemistry 28, 2494 (1963).

    CAS  Google Scholar 

  46. Fields, E. K., and J. M. Sandri: Addition of Dihalocarbenes to Imines. Chem. and Ind. 39, 1216 (1959).

    Google Scholar 

  47. -: Insertion of Dichlorocarbene into Aromatic Hydrocarbons. J. Amer. chem. Soc. 84, 1744 (1962).

    CAS  Google Scholar 

  48. -, and S. Meyerson: Preparation and Mass Spectrum of Hexachlorocyclopropane. J. org. Chemistry 28, 1915 (1963).

    CAS  Google Scholar 

  49. Frankel, M. B., H. Feuer, and J. Bank: The Preparation of N-Disubstituted Formamides. Tetrahedron Letters (London) 1959, 5.

    Google Scholar 

  50. Franzen, V., u. L. Fikentscher: Untersuchungen über Carbene. XI. Umsetzung metallorganischer Verbindungen mit Trifluorbromethan und Difluordibrommethan. Chem. Ber. 95, 1958 (1962).

    CAS  Google Scholar 

  51. -: Untersuchungen über Carbene. XII. Bestimmung der Lebensdauer des Difluorcarbens. Chem. Ber. 95, 1964 (1962).

    CAS  Google Scholar 

  52. Fröling, A., and J. F. Arens: Syntheses with Metalated Thioacetals and Orthothioformates. Recueil Trav. chim. Pays-Bas 81, 1009 (1962).

    Google Scholar 

  53. Funakubo, E., I. Moritani, S. Murahashi, and T. Tuji: The Addition of Carbene to Endomethylene Cyclic Compounds. Tetrahedron Letters (London) 1962, 539.

    Google Scholar 

  54. Gaspar, P. P., and G. S. Hammond: The Spin States of Methylenes. (Übersichtsreferat) unveröffentlicht.

    Google Scholar 

  55. Geuther, A.: Über die Zersetzung des Chloroforms durch alkoholische Kalilösung. Liebigs Ann. Chem. 123, 121 (1862).

    Google Scholar 

  56. Gilman, H., and D. Aoki: Reactions of Triphenylsilyl-lithium with Haloforms and Methylene Halides. Chem. and Ind. 1960, 1165.

    Google Scholar 

  57. Ghosez, L., and P. Laroche: Addition of Dichlorocarbene to Norbornylene. Proceedings Chem. Soc. 1963, 90.

    Google Scholar 

  58. Goldstein, M. J., and S. J. Baum: Deuterium Isotope Effect in Intramolecular Insertion. J. Amer. chem. Soc. 85, 1885 (1963).

    CAS  Google Scholar 

  59. Grant, F. W., and W. B. Cassie: Hexachloroacetone as a Source of Dichlorocarbene. J. org. Chemistry 25, 1433 (1960).

    CAS  Google Scholar 

  60. Hammond, G. S.: A Correlation of Reaction Rates. J. Amer. chem. Soc. 77, 334 (1955).

    CAS  Google Scholar 

  61. Hauser, C. R., W. G. Kofron, W. R. Dunnavant, and W. F. Owens: Reactions of Alkali Diphenylmethides, Displacements on Halogen or Hydrogen, J. org. Chemistry 26, 2627 (1961).

    CAS  Google Scholar 

  62. Hermann, M.: Über die bei der technischen Gewinnung des Broms beobachtete flüssige Bromverbindung. Liebigs Ann. Chem. 95, 211 (1855).

    Google Scholar 

  63. Hine, J.: Physical Organic Chemistry. New York-San Francisco-Toronto-London: McGraw Hill Book Inc. 1962.

    Google Scholar 

  64. -: Carbon Dichloride as an Intermediate in the Basic Hydrolysis of Chloroform. A mechanism for substitution reactions at a saturated carbon atom. J. Amer. chem. Soc. 72, 2438 (1950).

    CAS  Google Scholar 

  65. -, R. C. Peek, and B. D. Oakes: The Kinetics of the Basecatalyzed Exchange of Chloroform in Aqueous Solution. J. Amer. chem. Soc. 76, 827 (1954).

    CAS  Google Scholar 

  66. -, and A. M. Dowell: Carbon Dihalides as Intermediates in the Basic Hydrolysis of Haloforms. III. Combination of Carbon Dichloride with Halide Ions. J. Amer. chem. Soc. 76, 2688 (1954).

    CAS  Google Scholar 

  67. --, and J. E. Singley: Carbon Dihalides as Intermediates in the Basic Hydrolysis of Haloforms. IV. Relative Reactivities of Haloforms. J. Amer. chem. Soc. 78, 479 (1956).

    CAS  Google Scholar 

  68. -, and N. W. Burske: The Kinetics of the Base-catalyzed Deuterium Exchange of Dichlorofluoromethane in Aqueous Solution. J. Amer. chem. Soc. 78, 3337 (1956).

    CAS  Google Scholar 

  69. -, and K. Tanabe: Isopropoxy Fluoromethylene. J. Amer. chem. Soc. 79, 2654 (1957).

    CAS  Google Scholar 

  70. -, and J. J. Porter: Methylene Derivatives in Polar Reactions. VIII. Difluoromethylene in the Reaction of Chlorodifluoromethane with Sodium Methoxide. J. Amer. chem. Soc. 79, 5493 (1957).

    CAS  Google Scholar 

  71. -, and P. Langford: Methylene Derivatives as Intermediates in Polar Reactions. IX. The Concerted Mechanism for α-Eliminations of Haloforms. J. Amer. chem. Soc. 79, 5497 (1957).

    CAS  Google Scholar 

  72. -, R. Butterworth, and P. B. Langford: The Hydrolysis and Deuterium Exchange of Dibromofluoromethane and Fluorodiiodomethane. J. Amer. chem. Soc. 80, 819 (1958).

    CAS  Google Scholar 

  73. -, and S. J. Ehrenson: The Effect of Structure on the Relative Stability of Dihalomethylenes. J. Amer. chem. Soc. 80, 824 (1958).

    CAS  Google Scholar 

  74. -, and K. Tanabe: Methylene Derivatives as Intermediates in Polar Reactions. XII. Isopropoxy fluoromethylene. J. Amer. chem. Soc. 80, 3002 (1958).

    CAS  Google Scholar 

  75. -, and F. P. Prosser: Methylene Derivatives as Intermediates in Polar Reactions. XIII. The Basis Hydrolysis of Bromochloroiodomethane. J. Amer. chem. Soc. 80, 4282 (1958).

    CAS  Google Scholar 

  76. Hine, J., and P. B. Langford: Methylene Derivatives as Intermediates for Polar Reactions. XIV. The Effect of pH on the Rate of Hydrolysis of Chloroform. J. Amer. chem. Soc. 80, 6010 (1958).

    CAS  Google Scholar 

  77. -, and D. C. Duffey: Methylene Derivatives as Intermediates in Polar Reactions. XV. The Decomposition of Dichlorofluoroacetic Acid. J. Amer. chem. Soc. 81, 1129 (1959).

    CAS  Google Scholar 

  78. -: Mechanism of the Basic Hydrolysis and the Base-catalysed Chloride Exchange of Chloroform. J. Res. Inst. Catalysis, Hokkaido Univ. 6, 202 (1959).

    Google Scholar 

  79. -, and D. C. Duffey: Methylene Derivatives as Intermediates in Polar Reactions. XVI. The Decomposition of Chlorodifluoroacetic Acid. J. Amer. chem. Soc. 81, 1131 (1959).

    CAS  Google Scholar 

  80. -, and J. M. van der Veen: The Mechanism of the Reimer-Tiemann Reaction. J. Amer. chem. Soc. 81, 6446 (1959).

    CAS  Google Scholar 

  81. -, A. D. Ketley, and K. Tanabe: Methylene Derivatives as Intermediates in Polar Reactions. XIX. The Reaction of Potassium Isopropoxide with CHCl3, CHBr3, and CHCl2F. J. Amer. chem. Soc. 82, 1398 (1960).

    CAS  Google Scholar 

  82. --: Methylene Derivatives as Intermediates in Polar Reactions. XX. Reaction of Aqueous and Alcoholic Base with Chlorodifluoromethane and Difluoroiodomethane. J. org. Chemistry 25, 606 (1960).

    CAS  Google Scholar 

  83. -, and J. J. Porter: Methylene Derivatives as Intermediates in Polar Reactions. XXI. A Sulfur-containing Methylene. J. Amer. chem. Soc. 82, 6118 (1960).

    CAS  Google Scholar 

  84. -, R. J. Rosscup, and D. C. Duffey: Methylene Derivatives as Intermediates in Polar Reactions. XXII. Formation of the Intermediate Methoxy Chloromethylene in the Reaction of Dichloromethyl Ether with Base. J. Amer. chem. Soc. 82, 6120 (1960).

    CAS  Google Scholar 

  85. -, and J. J. Porter: Methylene Derivatives as Intermediates in Polar Reactions. XXIII. The Formation of Difluoromethylene from Difluoromethyl Phenyl Sulfone and Sodium Methoxide. J. Amer. chem. Soc. 82, 6178 (1960).

    CAS  Google Scholar 

  86. -, and J. M. van der Veen: Methylene Derivatives as Intermediates in Polar Reactions. XXIV. The Reimer-Tiemann Reaction with two p-substituted Phenols. J. org. Chemistry 26, 1407 (1961).

    Google Scholar 

  87. -, R. P. Bayer, and G. G. Hammer: Formation of Bis-(Methylthio)-methylene from methyl ortho thioformate and Potassium Amide. J. Amer. chem. Soc. 84, 1751 (1962).

    CAS  Google Scholar 

  88. -, N. W. Burske, M. Hine, and P. B. Langford: The Relative Rates of Formation of Carbanions by Haloforms. J. Amer. chem. Soc. 79, 1406 (1957).

    CAS  Google Scholar 

  89. Hofmann, K., S. F. Orochena, and C. W. Yoko: Unequivocal Syntheses of D,L-cis-9.10-Methyleneoctadecanoic acid (dihydrosterculic acid) and D,L-cis-11.12-Methyleneoctadecanoic acid. J. Amer. chem. Soc. 79, 3608 (1957).

    CAS  Google Scholar 

  90. Hoffmann, R. W., u. H. Häuser: Thermische Spaltung von 7,7-Dimethoxybicycloheptadien-2∶2∶1-Derivaten, ein Weg zum Tetramethoxy-Äthylen. Tetrahedron Letters (London) 4, 197–201 (1964).

    Google Scholar 

  91. --: Übertragung von Dimethoxy-Carben-Resten aus Tetramethoxy-Äthylen. Tetrahedron Letters (London) 21, 1365–1367 (1964).

    Google Scholar 

  92. Horiuti, J., and Y. Sakamoto: Isotopic Interchange Reaction between Chloroform and Water. Bull. chem. Soc. Japan 11, 627–628 (1936).

    Google Scholar 

  93. -, and M. Katayama: The Mechanism of Decomposition of Chloroform in Aqueous Solution and the Simultaneous Chlorine Exchange between them. J. Res. Inst. Catalysis, Hokkaido Univ. 6, 57 (1958). [C. A. 53, 10917 g (1958).]

    Google Scholar 

  94. Huisgen, R.: Kinetik und Mechanismus 1,3-Dipolarer Cycloadditionen. Angew. Chem. 75, 742 (1963).

    CAS  Google Scholar 

  95. Ioan, V., F. Badea, E. Cioranescu u. C. D. Nenitzescu: Dichlorcarben beim thermischen Zerfall von Silbertrichloracetat. Angew. Chem. 72, 416 (1960).

    CAS  Google Scholar 

  96. Jander, J., u. H. Nagel: Lösungen von Trifluormethan in flüssigem Ammoniak. Angew. Chem. 73, 540 (1961). Versammlungsber. Südwestdt. Chemie-Dozenten-Tagg, München, 24.–27. Mai 1961.

    Google Scholar 

  97. Kadaba, P. D., and J. O. Edwards: Hexachloroacetone as a Novel Source of Dichlorocarbene. J. org. Chemistry 25, 1431 (1960).

    CAS  Google Scholar 

  98. Katz, Th. J., and P. J. Garratt: The Cyclononatetraenyl Anion. J. Amer. chem. Soc. 85, 2852 (1963).

    CAS  Google Scholar 

  99. Khalafawi, T. El., et A. Johannin-Gilles: Spectres d'émission dans l'ultraviolet du tétrachlorure de carbone et du dichlorodifluoromethane. C. R. hebd. Séances Acad. Sci. 242, 1716 (1956).

    CAS  Google Scholar 

  100. Kenney, H. E., D. Komanowsky, L. L. Cook, and A. N. Wrigley: Preparation and Etherification of Fatty Dichlorocyclopropanes. J. Amer. Oil Chemists' Soc. 41 (1), 82–85 (1964).

    CAS  Google Scholar 

  101. Kharash, M. S., and H. N. Friedländer: Reactions of Atoms and Free Radicals in Solution. XIX. The Comparative Reactivities of Double Bonds in Cyclic Olefins toward Free Radicals. J. org. Chemistry 14, 239 (1949).

    Google Scholar 

  102. -, and M. Sage: Reactions of Atoms and Free Radicals in Solution. XXI. The Relative Reactivity of Olefins towards a Free Trichloromethyl Radical. J. org. Chemistry 14, 537 (1949).

    Google Scholar 

  103. -, E. Simon, and W. Nudenberg: Reactions of Atoms and Free Radicals in Solution. XXIX. The Relative Reactivity of Olefins toward the Free Trichloromethyl Radical. J. org. Chemistry 18, 328 (1953).

    Google Scholar 

  104. Kirmse, W.: Reactionen mit Carbenen und Iminen als Zwischenstufen. (Übersichtsreferat.) Angew. Chem. 71, 537 (1959).

    CAS  Google Scholar 

  105. -: Neues über Carbene. (Übersichtsreferat.) Angew. Chem. 73, 161 (1961).

    CAS  Google Scholar 

  106. Kloosterziel, H.: Synthetic applications of carbenes. (Übersichtsreferat.) Chem. Weekbl. 59, 77–84 (1963).

    CAS  Google Scholar 

  107. Knox, L. H., E. V. Velarde, S. M. Berger, and D. H. Cuadriello: Reactions of Dihalocarbenes with Unsaturated Steroids. Chem. and Ind. 1962, 860.

    Google Scholar 

  108. -3α-, 4α-and 5β, 6β-Cyclopropano-pregnenes. USP 3, 080,385 (Cl. 260-397.1) Mar. 5,1963. [C. A. 59, 14086 (1963).

    Google Scholar 

  109. -Cyclopropanopregnenes. USP 3,080,386 (Cl. 260-397.1) Mar. 5, 1963. [C. A. 60, 626g (1964).]

    Google Scholar 

  110. -Cyclopropanoandrostenes. USP 3,080,387 (Cl. 260-397.1) Mar. 5, 1963. [C. A. 60, 626b (1964).]

    Google Scholar 

  111. Köbrich, G., K. Flory u. W. Drischel: Dichlormethyl-lithium und Trichlormethyl-lithium. Angew. Chem. 76, 536 (1964).

    Google Scholar 

  112. Kofron, W. G., and C. R. Hauser: Mechanism of Reaction of Potassium Diphenylmethide with Carbon Tetrachloride. J. org. Chemistry 28, 577 (1963).

    CAS  Google Scholar 

  113. -, F. B. Kirby, and C. R. Hauser: Reactions of Tetrahalomethanes with Potassium tert-butoxide and Potassium Amide. J. org. Chemistry 28, 873–875 (1963).

    CAS  Google Scholar 

  114. Krapcho, A. P.: Addition of CCl2 to Diethyl-Methylsodiumalonate. J. org. Chemistry 27, 2357–2358 (1962).

    Google Scholar 

  115. Kuo, Ch'i-Chen: Chemistry of Cyanocarbenes. Jua Hsueh T'ung Pao 1962, 27–34. (Übersichtsreferat.) [C. A. 58, 12377 (1963).]

    Google Scholar 

  116. Laird, A. K., E. B. Andrews, and A. F. Barrow: The Absorption Spectrum of CF2. Trans. Faraday Soc. 54, 803 (1950).

    Google Scholar 

  117. Lalancette, E. A., and R. E. Benson: Cyclononatetraenide. An Aromatic 10-π-Electron System. J. Amer. chem. Soc. 85, 2853 (1963).

    CAS  Google Scholar 

  118. Landgrebe, J. A., and R. D. Mathis: Carbene Insertion into the Carbon Mercury Bond. Formation of Stable Dichlorocarbene Insertion Products which undergo an Unusual Thermal Breakdown. J. Amer. chem. Soc. 86, 524 (1964).

    CAS  Google Scholar 

  119. Ledwith, A., and R. M. Bell: Reaction of Dihalocarbenes with Isoprene. Chem. and Ind. 1959, 459.

    Google Scholar 

  120. Lemal, D. M., and E. H. Banitt: Bis-(Alkylthio)-carbenes. Tetrahedron Letters (London) 1964 (5/6), 245–251.

    Google Scholar 

  121. Leusen, A. M. van, R. J. Mulder, and J. Strating: Chemistry of α-Diazosulphones. Tetrahedron Letters (London) 1964 (11), 543–546.

    Google Scholar 

  122. Mahler, W.: Double Addition of a Carbene to an Acetylene. J. Amer. chem. Soc. 84, 4600 (1962).

    CAS  Google Scholar 

  123. Margrave, J. L., and K. W. Wieland: Equilibria involving CF(g) and CF2(g) Radicals at high Temperatures. J. chem. Physics 21, 2552 (1953).

    Google Scholar 

  124. McElvain, S. M., and P. L. Weyna: Cyclopropanone Acetals from Ketene Acetals and Carbene. J. Amer. chem. Soc. 81, 2579 (1959).

    CAS  Google Scholar 

  125. Miginiac, P.: Les Carbènes. (Übersichtsreferat.) Bull. Soc. chim. France 1962, 2000.

    Google Scholar 

  126. Miller jr., W. T., and C. S. Y. Kim: Reactions of Alkyllithiums with Polyhalides. J. Amer. chem. Soc. 81, 5008 (1959).

    CAS  Google Scholar 

  127. Miller, W. T., and D. M. Whalen: Trichloromethyllithium, an Electrophilic Reagent. J. Amer. chem. Soc. 86, 2089 (1964).

    CAS  Google Scholar 

  128. Moore, W. R., and H. R. Ward: The Formation of Allenes from gem-Dihalocyclopropanes by Reaction with Alkyllithium Reagents. J. org. Chemistry 27, 4179 (1962).

    CAS  Google Scholar 

  129. -, S. E. Krikorian, and J. E. La Prade: Formation of Hexachlorocyclopropane by Addition of Dichlorocarbene to Tetrachloroethylene. J. org. Chemistry 28, 1404 (1963).

    CAS  Google Scholar 

  130. -, W. R. Moser, and J. E. La Prade: Reactions of Dibromocarbene. Adducts of Bicyclo [2.2.1] heptene and Bicyclo [2.2.1] heptadiene. J. org. Chemistry 28, 2200 (1963).

    CAS  Google Scholar 

  131. Moss, R. A.: Improved Production of Phenyl-Chlorocarbene. J. org. Chemistry 27, 2683 (1962).

    CAS  Google Scholar 

  132. Mousseron, M., M. Mousseron-Canet, G. Philippe, et J. Wylde: Sur l'octaline-9.10 et quelques-uns de ses dérivés. C. R. hebd. Séances Acad. Sci. 256, 51 (1963).

    CAS  Google Scholar 

  133. Murray, R. W.: The Reaction of CCl2 with Anthracene. Tetrahedron Letters (London) 1960 (7), 27.

    Google Scholar 

  134. Nef, J. U.: Über das zweiwertige Kohlenstoffatom, 1. Abhandlung. Liebigs Ann. Chem. 270, 267 (1892).

    Google Scholar 

  135. -: Über das zweiwertige Kohlenstoffatom, 4. Abhandlung. Die Chemie des Methylens. Liebigs Ann. Chem. 298, 202 (1897).

    Google Scholar 

  136. Nefedov, O. M., N. N. Novitskaya, and A. S. Petrov: Preparation of Cyclopropanes by Reduction of Adducts of Dihalocarbenes and Olefins. Ber. Akad. Wiss. UdSSR 152 (3), 629 (1963). [C. A. 60, 1609a (1964).]

    Google Scholar 

  137. -A. A. Ivashenko, M. N. Manakov, V. I. Shiryaev, and A. D. Petrov: A new Method of Preparation of Carbenes. Nachr. Akad. Wiss. UdSSR, Abt. Chem. Wiss. 1962, 367. [C. A. 57, 11041g (1962).]

    Google Scholar 

  138. Nefedov, O. M., M. N. Manakov, and A. H. Ivashenko: Addition of Carbenes to some 1-substituted 1-cyclohexanes. Nachr. Akad. Wiss. UdSSR, Abt. Chem. Wiss. 1962, 1242. [C. A. 58, 5528f (1963).]

    Google Scholar 

  139. Oda, R., Y. Ito, and M. Okamo: Reaction of Ylides with Halocarbenes. Tetrahedron Letters (London) 1964 (1/2), 7–9.

    Google Scholar 

  140. Orchin, M., and E. C. Herrick: Reaction of Dichlorocarbene with Conjugated Dienes. J. org. Chemistry 24, 139 (1959).

    CAS  Google Scholar 

  141. Parham, W. E., and H. E. Reiff: Ring Expansion during the Reaction of Indenylsodium and Chloroform. (The Formation of Naphthalenes from Indenes. I.) J. Amer. chem. Soc. 77, 1177 (1955).

    CAS  Google Scholar 

  142. --, and P. Schwartzengruber: The Formation of Naphthalenes from Inden. II. J. Amer. chem. Soc. 78, 1437 (1956).

    CAS  Google Scholar 

  143. -, and R. R. Twelves: Formation of Naphthalenes from Indenes. III. Substituted Methanes as Carbene Percursors. J. org. Chemistry 22, 730 (1957).

    CAS  Google Scholar 

  144. -, and F. C. Loew: Formation of Carbenes from alpha-halo-esters. J. org. Chemistry 23, 1705 (1958).

    CAS  Google Scholar 

  145. -, and E. E. Schweizer: An Improved Synthesis of Dichlorocarbene from Ethyl Trichloroacetate. J. org. Chemistry 24, 1733 (1959).

    CAS  Google Scholar 

  146. -, F. C. Loew, and E. E. Schweizer: Mechanism of Carbene Formation from t-Butyl Dichloroacetate. J. org. Chemistry 24, 1900 (1959).

    CAS  Google Scholar 

  147. -, D. A. Bolon, and E. E. Schweizer: The Reaction of Halocarbenes with Aromatic Systems. Synthesis of Chlorotropones. J. Amer. chem. Soc. 83, 603 (1961).

    CAS  Google Scholar 

  148. -, and R. Koncos: The Reaction of Dichlorocarbene with 2 H-1-Benzothiopyran and 4 H-1-Benzothiopyran. J. Amer. chem. Soc. 83, 4034 (1961).

    CAS  Google Scholar 

  149. -, and L. D. Huestis: Reaction of Dichlorocarbene with 2.3-chromene and 3.4-chromene. J. Amer. chem. Soc. 84, 813 (1962).

    CAS  Google Scholar 

  150. -, R. W. Soeder, and R. M. Dodson: A Convenient Synthesis of 3.5-Cycloheptadienone. J. Amer. chem. Soc. 84, 1756 (1962).

    Google Scholar 

  151. -, G. G. Fritz, R. W. Soeder, and R. M. Dodson: The Reaction of Dichlorocarbene. J. org. Chemistry 28, 577 (1963).

    CAS  Google Scholar 

  152. Pearson, T. G., R. H. Purcell, and G. S. Saigh: Methylene (Originalarbeit und zugleich Übersichtsreferat.) J. chem. Soc. (London) 1938, 409.

    Google Scholar 

  153. Perrot, A.: Note concernant l'action de la chaleur sur le chlorure de méthyle. Ann. Chim. Phys. 3 49, 94 (1857).

    Google Scholar 

  154. Petrenko-Kritschenko, P., u. V. Opotsky: Über das Gesetz der Periodizität. I. Mitteilung: Über die Aktivität organischer Haloidverbindungen. Ber. dtsch. chem. Ges. 59 B, 2131 (1926).

    Google Scholar 

  155. Plate, A. F., and O. A. Sheherbakova: Synthesis of Chloroorganic Insecticides containing the Cyclopropane Ring. Neftekhimiya 3, (2), 276–279 (1963). [C. A. 59, 8613e (1963).]

    CAS  Google Scholar 

  156. Prilezhaeva, E. P., N. P. Petukhova, and M. F. Shostakovskii: Reaction of Dichlorcarbene with Vinylsulfides. Ber. Akad. Wiss. UdSSR 144, 1059 (1962). [C. A. 57, 13632i (1962).]

    CAS  Google Scholar 

  157. Rabinowitz, R., and R. Marcus: Ylide Intermediate in the Reaction of Triphenylphosphine in Carbon Tetrachloride. J. Amer. chem. Soc. 84, 1312 (1962).

    CAS  Google Scholar 

  158. Ramirez, F., N. B. Desai, and N. McKelvie: New Syntheses of 1.1-dibromoolefines via phosphinedibromomethylenes. The Reaction of triphenylphosphine with Carbon Tetrabromide. J. Amer. chem. Soc. 84, 1745 (1962).

    CAS  Google Scholar 

  159. Rees, C. W., and C. E. Smithen: Reactions of Dihalocarbenes with some Indoles. Chem. and Ind. (London) 1962, 1022.

    Google Scholar 

  160. Reimlinger, H.: Reaktionen der Carbene mit Diazo-alkanen. Angew. Chem. 74, 153 (1962).

    CAS  Google Scholar 

  161. -: Reaktionen der Carbene mit Diazoalkanen. II. Chem. Ber. 97, 339 (1964).

    CAS  Google Scholar 

  162. Rice, F. O., and A. L. Glasebrook: The Thermal Decomposition of Organic Compounds from the Standpoint of Free Radicals. XI. The Methylene Radical. J. Amer. chem. Soc. 56, 2381 (1934).

    CAS  Google Scholar 

  163. Robinson, B.: Reaction of Dichloromethylene with 2.3-Dimethylindole and 1.2.3.4-Tetrahydrocarbazole. Tetrahedron Letters (London) 1962, 139.

    Google Scholar 

  164. Sakamoto, Y.: Interchange Reaction between Chloroform and Heavy Water. J. chem. Soc. Japan 57, 1169–1174 (1936). [C. A. 31, 9314 (1937).]

    CAS  Google Scholar 

  165. Sanderson, W. A., and H. S. Mosher: Stereospecific Rearrangement of Neopentylalcohol-1-d. J. Amer. chem. Soc. 83, 5033 (1961).

    CAS  Google Scholar 

  166. Saunders, M., and R. W. Murray: The Reaction of Dichlorocarbene with Secondary Amines. Tetrahedron (London) 6, 88 (1959).

    CAS  Google Scholar 

  167. --: The Reaction of Dichlorocarbene with Amines. Tetrahedron (London) (London) 11, 1 (1960).

    CAS  Google Scholar 

  168. Schamp, N.: Carbene. (Übersichtsreferat.) Meded. vlaamsche chem. Vereen. 24, 65–91 (1962).

    Google Scholar 

  169. Schöllkopf, U., u. A. Lerch: Phenoxy-carben. Angew. Chem. 73, 27 (1961).

    Google Scholar 

  170. --, W. Pitteroff u. G. L. Lehmann: Einige Synthesen mit Phenoxy-Methoxy-und Phenylmercapto-carben. Angew. Chem. 73, 765 (1961) Versammlungsber. der GdCh-Hauptversammlg Aachen, 18.–23. Sept. 1961.

    Google Scholar 

  171. Schöllkopf, U., u. P. Hilbert: Dichlorcarben aus Trichlormethansulfinsäuremethylester und Trichlormethan-sulfonylchlorid. Angew. Chem. 74, 431 (1962).

    Google Scholar 

  172. -, u. G. J. Lehmann: Phenylmercaptocyclopropane aus Phenylmercaptocarben und Olefinen. Tetrahedron Letters (London) 1962, 165.

    Google Scholar 

  173. -A. Lerch, and W. Pitteroff: Phenoxy-, Methoxy-, Butoxy-und Isopropoxy-carben. Tetrahedron Letters (London) 1962, 241.

    Google Scholar 

  174. -, u. H. Küppers: Phenylselen-cyclopropane aus Phenylselen-carben und Olefinen. Tetrahedron Letters (London) 1963, 105.

    Google Scholar 

  175. -, u. J. Paust: Einfache Synthese von Alkoxycyclopropanen. Angew. Chem. 75, 670 (1963).

    Google Scholar 

  176. -, u. E. Wiskott: Bismethylmercapto-carben (Kohlenmonoxyd-methylmercaptal) aus Bis-methylmercapto-diazomethan. Angew. Chem. 75, 725 (1963).

    Google Scholar 

  177. -, A. Lerch u. J. Paust: α-Eliminierungen bei alkalimetallorganischen Verbindungen. II. Synthese von Phenoxycyclopropanen aus Phenoxycarben und Olefinen. Ber. dtsch. chem. Ges. 96, 2266 (1963).

    Google Scholar 

  178. -, u. W. Pitteroff: α-Eliminierungen bei alkalimetallorganischen Verbindungen. III. Alkoxycyclopropane aus Alkoxycarbenen und Olefinen. (Manuskript.)

    Google Scholar 

  179. Schröder, G.: Synthese und Eigenschaften von Tricyclo-3.3.2.0.4.6. deca-2.7.9-trien (Bullvalen). Angew. Chem. 75, 722 (1963).

    Google Scholar 

  180. Schweizer, E. E., and W. E. Parham: Oxepines. I. Preparation of 2.3-Dihydroöxepine and 2.3-Dihydroöxepine. J. Amer. chem. Soc. 82, 4085 (1960).

    CAS  Google Scholar 

  181. Semeluk, G. P., and R. B. Bernstein: The Thermal Decomposition of Chloroform. I. Produkts. J. Amer. chem. Soc. 76, 3793 (1954).

    Google Scholar 

  182. --: The Thermal Decomposition of Chloroform. II. Kinetics. J. Amer. chem. Soc. 79, 46 (1957).

    CAS  Google Scholar 

  183. Seyferth, D., S. O. Grim, and T. O. Read: A New Preparation of Triphenylphosphinemetylenes by the Reaction of Carbenes with Triphenylphosphine. J. Amer. chem. Soc. 82, 1510 (1960).

    Google Scholar 

  184. -, J. M. Burlitch, and J. K. Heeren: A New Preparation of Dihalocarbenes by an Organometallic Route. J. org. Chemistry 27, 1491 (1962).

    CAS  Google Scholar 

  185. --: Concerning the Mechanism of Formation of Phenyl-(trihalomethyl)-mercurials. J. Amer. chem. Soc. 84, 1757 (1962).

    Google Scholar 

  186. -, R. J. Minasz, A. J.-H. Treiber, M. M. Burlitch, and S. R. Down: The Reaction of Phenyl-(trihalomethyl)-mercurials with Olefins of Low Reactivity toward Dihalocarbenes. J. org. Chemistry 28, 1163 (1963).

    CAS  Google Scholar 

  187. -, and J. M. Burlitch: The Preparation of Dihalomethyl Derivatives of Carbon, Silicon, and Germanium by the Action of Phenyl-(trihalomethyl)-mercurials on C-H, Si-H, and Ge-H Linkages. J. Amer. chem. Soc. 85, 2667 (1963).

    Google Scholar 

  188. Simons, J. P., and A. J. Yarwood: Photochemical Formation and Stability of the CF2 Radical. Nature 187, 316 (1960).

    CAS  Google Scholar 

  189. --: Decomposition of Hot Radicals. I. Production of CCl and CBr from Halogen Substituted Methyl Radicals. Trans Faraday Soc. 57, 2167–2175 (1961).

    CAS  Google Scholar 

  190. Shen, T. Y., S. Lucas, and L. H. Sarett: Chlorodifluoromethane as a Difluoromethylating Agent. Tetrahedron Letters (London) 1961, (2), 43.

    Google Scholar 

  191. Shingaki, T., and M. Takebayashi: Reaction of Dichlorocarbene and Primary Amines. Preparation of Aromatic Isocyamides. Bull. chem. Soc. Japan 36, 617 (1963).

    CAS  Google Scholar 

  192. Skattebøl, L.: The Synthesis of Allenes from 1.1-Dihalocyclopropane Derivatives and Alkyllithium. Acta chem. scand. 17, 1683 (1963).

    Google Scholar 

  193. Skell, P. S., and A. Y. Garner: The Stereochemistry of Carbene-Olefin Reactions. Reactions of Dibromocarbene with cis-and trans-2-butenes. J. Amer. chem. Soc. 78, 3409 (1956).

    CAS  Google Scholar 

  194. -, and R. C. Woodworth: Structure of Carbene. J. Amer. chem. Soc. 78, 4496 (1956).

    CAS  Google Scholar 

  195. -, and A. Y. Garner: Reactions of Bivalent Carbon Compounds. Reactivities in Olefin-Dibromocarbene Reactions. J. Amer. chem. Soc. 78, 5430 (1956).

    CAS  Google Scholar 

  196. -, and S. R. Sandler: Reactions of 1.1-Dihalocyclopropanes with Electrophilic Reagents. Synthetic Route for Inserting a C-Atom between the Atoms of a Double Bond. J. Amer. chem. Soc. 80, 2024 (1958).

    CAS  Google Scholar 

  197. Speziale, A. J., G. J. Marco, and K. W. Ratts: A Novel Synthesis of 1.1-Dihaloolefins. J. Amer. chem. Soc. 82, 1260 (1960).

    CAS  Google Scholar 

  198. Staudinger, H., u. O. Kupfer: Über Reaktionen des Methylens. III. Diazomethan. Ber. dtsch. chem. Ges. 45, 501 (1912).

    CAS  Google Scholar 

  199. Streitwieser, A.: Solvolytic Displacement Reactions. New York-San Francisco-Toronto-London: McGraw Hill Book Inc. 1962.

    Google Scholar 

  200. -: Molecular Orbital Theory for Organic Chemistry. New York and London: John Wiley & Sons. Inc. 1961.

    Google Scholar 

  201. Syono, T., and R. Oda: On the Reaction of Buta-1.3-Diene homologues with Dichlorocarbene. J. chem. Soc. Japan (Pure Chemistry Section) 80, 1200 (1959). Englische Zusammenfassung, A. 94.

    Google Scholar 

  202. Ter Borg, A. P., and A. F. Bickel: A New Synthesis of Benzocyclobutene. Proc. Chem. Soc. 283 (1958).

    Google Scholar 

  203. --: The Chemistry of Cycloheptatriene I Synthesis of Benzocyclobutene. Recueil Trav. chim. Pays-Bas 80, 1217 (1961).

    CAS  Google Scholar 

  204. Thompson, J. E.: Reactions of Dichlorocarbene with certain substituted Styrenes and a Study of the Chemistry and the Ultraviolet Absorption Spectra of Related Cyclopropylbenzenes. Dissertation, Univ. Missouri, Columbia 1962.

    Google Scholar 

  205. Tobey, S. W., and R. West: Tetrachlorocyclopropene and Hexachlorocyclopropane. Tetrahedron Letters (London) 1963 (18) 1179–1182.

    Google Scholar 

  206. --: Hexachlorocyclopropane. J. Amer. chem. Soc. 86, 56 (1964).

    CAS  Google Scholar 

  207. Venkatesvarlu, P.: On the Emission Bands of CF2. Physic. Rev. 77, 676 (1950).

    Google Scholar 

  208. Verzele, M., and H. Sion: Note on the Reimer-Tiemann Aldehyde Sinthesis. Bull. Soc. chim. belges 65, 627 (1956).

    CAS  Google Scholar 

  209. Viehe, H. G., u. P. Valange: Kondensationsreaktionen mit Haloformcarbanionen in flüssigem Ammoniak. I. Chem. Ber. 96, 420 (1963).

    CAS  Google Scholar 

  210. --: Die Kondensation mit Haloformcarbanionen in flüssigem Ammoniak als katalytische Reaktion. II. Chem. Ber. 96, 426 (1963).

    CAS  Google Scholar 

  211. Vogel, E.: Kleine Kohlenstoffringe. (Übersichtsreferat.) Angew. Chem. 72, 4 (1960).

    CAS  Google Scholar 

  212. -: Addition von Carbenen an Cyclo-octatetraen. Angew. Chem. 73, 548 (1961). Versammlungsber. Südwestdtsch. Chemie-Dozententagg München, 24.–27. Mai 1961.

    Google Scholar 

  213. -, u. H. D. Roth: Synthese eines Cyclodecaptentaens. Angew. Chem. 76, 145 (1964).

    CAS  Google Scholar 

  214. Wagner, W. M.: New Syntheses of Dichlorocarbene. Proc. chem. Soc. 1959, 229.

    Google Scholar 

  215. -, H. Kloosterziel, and S. van der Ven: The Thermal Decarboxylation of Alkali Trichloroacetates in Aprotic Solvents. II. Decarboxylation in the Presence of Olefins. Recueil Trav. chim. Pays-Bas 80, 740 (1961).

    CAS  Google Scholar 

  216. --, and A. F. Bickel: The Thermal Decarboxylation of Alkali Trichloroacetates in Aptoric Solvents. III. Decarboxylation in the Presence of Perchloro Compounds. Recueil Trav. chim. Pays-Bas 81, 925 (1962).

    CAS  Google Scholar 

  217. ---: Thermal Decarboxylation of Alkali Trichloroacetates in Aprotic Solvents. IV. Decarboxylation in the Presence of Perchloro Compounds. Recueil Trav. chim. Pays-Bas 81, 933 (1962).

    CAS  Google Scholar 

  218. --, S. van der Ven, and A. F. Bickel: The Thermal Decarboxylation of Alkali Trichloroacetates in Aprotic Solvents. V. The Decarboxylation and its Catalytic Effect on the Decomposition of Trichloroacetic Anhydride. Recueil Trav. chim. Pays-Bas 81, 947 (1962).

    CAS  Google Scholar 

  219. Walter, W., u. G. Maerten: Darstellung N,N-disubstituiertcr Thioformanide über Dichlorcarben. Angew. Chem. 73, 755 (1961).

    CAS  Google Scholar 

  220. Wanzlick, H. W., u. E. Schikora: Ein neuer Zugang zur Carbenchemie. Angew. Chem. 72, 494 (1960).

    CAS  Google Scholar 

  221. -, u. H. J. Kleiner: Nucleophile Carben-Chemie. Darstellung des Bis-[1,3-diphenyl-imidazolidinyliden-(2)]. Angew. Chem. 73, 493 (1961).

    CAS  Google Scholar 

  222. -: Nucleophile Carben-Chemie. (Übersichtsreferat.) Angew. Chem. 74, 129 (1962).

    CAS  Google Scholar 

  223. -, F. Esser u. H. J. Kleiner: Nucleophile Carbenchemie. III. Neue Verbindungen vom Typ des Bis-[1,3-diphenylimidazolidinylidens-(2)]. Chem. Ber. 96, 1208 (1963).

    CAS  Google Scholar 

  224. -, u. H. J. Kleiner: Energiearme „Carbene“. Angew. Chem. 75, 1204 (1963).

    Google Scholar 

  225. --: Nucleophile Carbenchemie. IV. Reaktionen des Bis-[1,3-diphenylimidazolidinylidens-(2)] mit einigen Carbonylverbindungen. Chem. Ber. 96, 3024 (1963).

    CAS  Google Scholar 

  226. Wanzlick, H., H. Ahrens, B. König u. M. Riccius: Neue Reaktionen des Bis-[1,3-diphenylimidazolidinylidens-(2)]. Angew. Chem. 75, 685 (1963).

    Google Scholar 

  227. Wawzonek, S., and R. C. Duty: Polarographic Studies in Acetonitrile and Dimethylformamide. VI. The Formation of Dihalocarbenes. J. electrochem. Soc. 108, 1135 (1961).

    CAS  Google Scholar 

  228. Winberg, H. E.: Synthesis of Cycloheptatriene. J. org. Chemistry 24, 264 (1959).

    CAS  Google Scholar 

  229. Wittig, G., u. M. Schlosser: Triphenylphosphin-chlormethylen. Angew. Chem. 72, 324 (1960).

    Google Scholar 

  230. -, u. F. Wingler: (unveröffentlicht). Diss. F. Wingler, Heidelberg 1963.

    Google Scholar 

  231. -, u. W. Böll: Über Phosphinalkylene als olefinbildende Reagentien. VII. Über Zersetzungsreaktionen des Triphenylphosphinbutoxy-methylens und analoger Verbindungen. Chem. Ber. 95, 2526 (1962).

    CAS  Google Scholar 

  232. Woodworth, R. C.: The Stereo Chemistry of some Radical and Carbene Additions to the 2-butenes. Dissertation Abstracts 17, 1201 (1957).

    Google Scholar 

  233. -, and P. S. Skell: Reactions of Bivalent Carbon Species. Addition of Dihalogenocarbenes to Buta-1:3-diene. J. Amer. chem. Soc. 79, 2542 (1957).

    CAS  Google Scholar 

  234. Wynberg, H.: Some Observations on the Mechanism of the Reimer-Tiemann Reaction. J. Amer. chem. Soc. 76, 4998 (1954).

    CAS  Google Scholar 

  235. -: The Reimer Tiemann Reaction. Chem. Rev. 60, 169 (1960). (Übersichtsreferat.)

    CAS  Google Scholar 

  236. Ziegler, K., u. H. G. Gellert: Addition von Lithium-alkylen an Äthylen. Liebigs Ann. Chem. 567, 195 (1950).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Instituto Superior Técnico Avenida Rovisco Pais Lisboa-1, Portugal

    Prof. Dr. B. Jerosch Herold & Prof. Dr. P. P. Gaspar

  2. Washington University, St. Louis, Mo., USA

    Prof. Dr. B. Jerosch Herold & Prof. Dr. P. P. Gaspar

Authors
  1. Prof. Dr. B. Jerosch Herold
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Prof. Dr. P. P. Gaspar
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

Copyright information

© 1965 Springer-Verlag

About this paper

Cite this paper

Jerosch Herold, B., Gaspar, P.P. (1965). Entwicklung und präparative Möglichkeiten der Carben-Chemie. In: Organische Synthesen. Fortschritte der Chemischen Forschung, vol 5/1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0051665

Download citation

  • DOI: https://doi.org/10.1007/BFb0051665

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-03291-5

  • Online ISBN: 978-3-540-37130-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation