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Chemical and stereochemical properties of compounds with silicon or germanium-transition metal bonds

  • Ernesto Colomer
  • Robert J. P. Corriu
Conference paper
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 96)

Abstract

Complexes with silicon (or germanium)-transition metal bonds in which silicon or germanium is optically active are very stable both chemically and optically.

The introduction of a group IVB metal into transition metal complexes modifies the behavior of these complexes and a wide variety of reaction sites may result. Thus, reactions at silicon without cleavage of the transition metal-silicon bond are possible in some cases.

As pointed out in Section 3.1, the particular nature of the Si-H bond in transition metal complexes may explain some features of hydrosilylation.

Anions derived from transition metal-group IVB metal bonds may be interesting as potential asymmetric catalysts in phase transfer reactions. This field is developing now and, in general, the use of these complexes as catalysts is at the beginning.

Keywords

Metal Bond Reductive Elimination Manganese Complex Silicon Hydride Stereochemical Property 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1981

Authors and Affiliations

  • Ernesto Colomer
    • 1
  • Robert J. P. Corriu
    • 1
  1. 1.Laboratoire des Organométalliques, Equipe de Recherche Associée au C.N.R.S. No. 554Université des Sciences et Techniques du LanguedocMontpellier-cédexFrance

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