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Theoretical considerations for cyclic (pd)π systems

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π Complexes of Transition Metals

Part of the book series: Fortschritte der Chemischen Forschung ((TOPCURRCHEM,volume 28/1))

Abstract

In most of the cyclic (pd)π systems which may be formed by use of either outer or inner d orbitals, cyclic delocalization through the d-orbital center is possible and leads to an increase in stability, but in no case will the (pd)π system alone lead to an extraordinary ground-state stabilization which can be classified as aromatic.

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  1. Lehrstuhl für Organische Chemie der Universität Tübingen, Deutschland

    Priv.-Doz. Dr. Günter Häfelinger

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  1. Priv.-Doz. Dr. Günter Häfelinger
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Häfelinger, G. (1972). Theoretical considerations for cyclic (pd)π systems. In: π Complexes of Transition Metals. Fortschritte der Chemischen Forschung, vol 28/1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0051448

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  • DOI: https://doi.org/10.1007/BFb0051448

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