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Catalysis pp 117-154 | Cite as

Heterogeneous photocatalysis

Conference paper
Part of the Fortschritte der Chemischen Forschung book series (TOPCURRCHEM, volume 25/1)

Abstract

By irradiating a solid with photons, it is possible to alter in a well controlled way the occupation of the bond orbitals in the surface of the solid. This procedure enables us to influence surface migrations of atoms of the solid, sorption reactions and catalytic reactions, and to reveal the bond changes fundamental to any surface reaction. Several sorption processes have been investigated and may be interpreted to a certain extent. The interpretation of catalytic processes, however, is still too general. One problem in particular remains unsolved: whether the adsorption states studied so far are identical with the unstable short-lived transition states which occur in catalytic reactions.

Keywords

Activation Energy Electron Hole Pair Glow Curve Chemisorb Oxygen Surface Bond 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1972

Authors and Affiliations

  1. 1.Institut für Physikalische Chemie der UniversitÄt HamburgDeutschland

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