Abstract
By irradiating a solid with photons, it is possible to alter in a well controlled way the occupation of the bond orbitals in the surface of the solid. This procedure enables us to influence surface migrations of atoms of the solid, sorption reactions and catalytic reactions, and to reveal the bond changes fundamental to any surface reaction. Several sorption processes have been investigated and may be interpreted to a certain extent. The interpretation of catalytic processes, however, is still too general. One problem in particular remains unsolved: whether the adsorption states studied so far are identical with the unstable short-lived transition states which occur in catalytic reactions.
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Steinbach, F. (1972). Heterogeneous photocatalysis. In: Catalysis. Fortschritte der Chemischen Forschung, vol 25/1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0051372
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