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Carboxylato complexes of the uranyl ion: Effects of ligand size and coordination geometry upon molecular and crystal structure

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Coordination Chemistry

Part of the book series: Structure and Bonding ((STRUCTURE,volume 82))

Abstract

The molecular and crystal structures of complexes with uranyl ion of carboxylate ions of varying type (mono- and polycarboxylate, aliphatic, aromatic, heterocyclic) are surveyed. The tendencies to form monomers on the one hand, or chains or sheets on the other, can be related to ligand size and functionality.

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© 1995 Springer-Verlag

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Leciejewicz, J., Alcock, N.W., Kemp, T.J. (1995). Carboxylato complexes of the uranyl ion: Effects of ligand size and coordination geometry upon molecular and crystal structure. In: Coordination Chemistry. Structure and Bonding, vol 82. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0036825

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  • DOI: https://doi.org/10.1007/BFb0036825

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  • Print ISBN: 978-3-540-58761-3

  • Online ISBN: 978-3-540-49066-1

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