Abstract
A three-dimensional model consisting of a fluid in contact with a planar wall containing a lattice of adsorption sites is useful for studying phase transitions at the solid-fluid interface. Results have been obtained both for adsorption from a fluid of hard spheres and for deposition of a metal from a dilute solution of metal ions. The latter case is used to model the underpotential deposition of a metal onto a single-crystal electrode. The model explains the qualitative features of the voltammogram of the underpotential deposition of copper on the (111) surface of a gold electrode in the presence of bisulfate.
This is a preview of subscription content, log in via an institution to check access.
Preview
Unable to display preview. Download preview PDF.
References
D. A. Huckaby and L. Blum, J. Chem. Phys. 92, 2646 (1990).
L. Blum and D. A. Huckaby, J. Chem. Phys. 94, 6887 (1991).
L. Blum and D. A. Huckaby, in Liquids, Freezing, and Glass Transition, edited by J. P. Hansen, D. Levesque, and J. Zinn-Justin, (Elsevier, Amsterdam, 1991), p. 983.
D. A. Huckaby and L. Blum, J. Electroanal. Chem. 315, 255 (1991).
D. A. Huckaby and L. Blum, in X-Ray Methods in Corrosion and Interfacial Electrochemistry, edited by A. Davenport and J. G. Gordon II, (Electrochemical Society, Pennington, New Jersey, 1992), p. 139.
D. A. Huckaby and L. Blum, J. Chem. Phys. 97, 5773 (1992).
D. A. Huckaby and L. Blum, in Condensed Matter Theories, vol. 8, edited by L. Blum and F. B. Malik, (Plenum, New York, 1993) p. 637.
L. Blum and D. A. Huckaby, in Microscopic Models of Electrode-Electrolyte Interfaces, edited by J. W. Halley and L. Blum, (Electrochemical Society, Pennington, New Jersey, 1993), p. 232.
L. Blum and D. A. Huckaby, J. Electroanal. Chem., in press.
M. L. Rosinberg, J. L. Lebowitz, and L. Blum, J. Stat. Phys. 44, 153 (1986).
J. P. Badiali, L. Blum, and M. L. Rosinberg, Chem. Phys. Lett. 129, 149 (1986).
D. M. Kolb, K. Al Jaaf-Golze, and M. S. Zei, Dechema Monographien, (VCH, Weinheim, 1986), vol. 102, p. 53.
L. Blum, M. Legault, and P. Turq, J. Electroanal. Chem., in press.
J. G. Kirkwood, J. Chem. Phys. 3, 300 (1935).
R. J. Baxter, J. Phys. A 13, L61 (1980).
G. S. Joyce, J. Phys. A 21, L983 (1988).
M. Wertheim, J. Math. Phys. 5, 643 (1964).
J. A. Barker and D. Henderson, Rev. Mod. Phys. 48, 587 (1976).
N. F. Carnahan and K. E. Starling, J. Chem. Phys. 51, 635 (1969).
E. Müller-Hartmann and J. Zittarz, Z. Physik B27, 261 (1977).
J. Dóczi-Réger and P. C. Hemmer, Physica 109A, 541 (1981).
C. Domb, in “Phase Transitions and Critical Phenomena,” edited by C. Domb and M. S. Green (Academic, New York, 1974), vol. 3, pp. 1 and 375.
T. Hachiya, H. Honbo, and K. Itaya, J. Electroanal. Chem. 315, 275 (1991).
G. L. Borges, K. K. Kanazawa, J. G. Gordon II, K. Ashley, and J. Richer, J. Electroanal. Chem. 364, 281 (1994).
Z. Shi and J. Lipkowski, J. Electroanal. Chem. 365, 303 (1994).
P. Zelenay, L. M. Rice, and A. Wieckowski, Surf. Sci. 256, 253 (1991).
L. M. Rice-Jackson, Ph.D. Thesis, Univ. of Illinois, Urbana (1990).
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 1994 Springer-Verlag
About this paper
Cite this paper
Huckaby, D.A., Blum, L. (1994). A model for the underpotential deposition of metals. In: Pękalski, A. (eds) Diffusion Processes: Experiment, Theory, Simulations. Lecture Notes in Physics, vol 438. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0031128
Download citation
DOI: https://doi.org/10.1007/BFb0031128
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-58653-1
Online ISBN: 978-3-540-49038-8
eBook Packages: Springer Book Archive