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NMR approach to the phase structure of linear polyethylene

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Polymer Chemistry

Part of the book series: Advances in Polymer Science ((POLYMER,volume 26))

Abstract

The recent studies of the phase structure of linear polyethylene by refined NMR analyses are reviewed. The phase structure of the polymer in various crystalline forms, including bulk-crystals, solution-crystals and drawn fibers, is discussed in terms of different modes of molecular mobilities in a wide range of temperature.

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VIII. References

  1. Mandelkern, L.: Crystallization of polymers. New York: McGraw-Hill 1964

    Google Scholar 

  2. Takayanagi, M.: Pure and Appl. Chem. 15, 555 (1967)

    Google Scholar 

  3. Illers, K. H.: Kolloid-Z. Z. Polym. 231, 622 (1969)

    Article  Google Scholar 

  4. Till, P. H.: J. Polym. Sci. 24, 301 (1957)

    Article  Google Scholar 

  5. Keller, A.: Phil. Mag. 2, 1171 (1957)

    Google Scholar 

  6. Fischer, E. W.: Z. Naturforsch. 12a, 753 (1957)

    Google Scholar 

  7. Kubo, R., Tomita, K.: J. Phys. Soc. Japan 9, 888 (1954)

    Article  Google Scholar 

  8. Odajima, A., Sauer, J. A., Woodward, A. E.: J. Phys. Chem. 66, 718 (1962)

    Google Scholar 

  9. Wilson III, C. W., Pake, G. E.: J. Polym. Sci. 10, 503 (1953)

    Article  Google Scholar 

  10. Fischer, E. W., Peterlin, A.: Makromol. Chem. 74, 1 (1964)

    Article  Google Scholar 

  11. Olf, H. G., Peterlin, A.: Kolloid-Z. Z. Polym. 215, 97 (1967)

    Article  Google Scholar 

  12. Bergmann, K., Nawotki, K.: Kolloid-Z. Z. Polym. 219, 132 (1967)

    Article  Google Scholar 

  13. Bergmann, K.: Ber. Bunsenges. Phys. Chem. 74, 912 (1970)

    Google Scholar 

  14. Bergmann, K., Nawotki, K.: Kolloid-Z. Z. Polym. 250, 1094 (1972)

    Article  Google Scholar 

  15. Bergmann, K.: Kolloid-Z. Z. Polym. 251, 962 (1973)

    Article  Google Scholar 

  16. Loboda-Čačković, J., Hosemann, R., Wilke, W.: Kolloid-Z. Z. Polym. 235, 1253 (1969)

    Article  Google Scholar 

  17. Phaovibul, O., Loboda-Čačković, J., Hosemann, R.: Makromol. Chem. 175, 2991 (1974)

    Article  Google Scholar 

  18. Eichhoff, U., Zachmann, H. G.: Ber. Bunsenges. Phys. Chem. 74, 919 (1970)

    Google Scholar 

  19. Zachmann, H. G.: J. Polym. Sci. Symposium 43, 111 (1973)

    Google Scholar 

  20. Zachmann, H. G.: Kolloid-Z. Z. Polym. 251, 951 (1973)

    Article  Google Scholar 

  21. Smith, J. B., Manuel, A. J., Ward, I. M.: Polymer 16, 57 (1975)

    Article  Google Scholar 

  22. Fischer, E. W., Goddar, H., Piesczek, W.: J. Polym. Sci. C32, 149 (1971)

    Google Scholar 

  23. For example, Allen, G., Peterie, S. E. B., Ed.: Physical structure of the amorphous state. J. Macromol. Sci. Phys. B12, No. 1 and 2, 1976

    Google Scholar 

  24. Kirste, R. G., Kruse, W. A., Schelten, J.: Makromol. Chem. 162, 299 (1972)

    Article  Google Scholar 

  25. Schelten, J., Kruse, W. A., Kirste, R. G.: Kolloid-Z. Z. Polym. 251, 919 (1973)

    Article  Google Scholar 

  26. Kirste, R. G., Kruse, W. A., Ibel, K.: Polymer 6, 120 (1975)

    Article  Google Scholar 

  27. Cotton, J. P., Farnoux, B., Jannink, G., Mons, J., Picot, C.: C. R. Acad. Sci. C275, 175 (1972)

    Google Scholar 

  28. Ballard, D. G. H., Wignall, G. D., Schelten, J.: Eur. Polym. J. 9, 965 (1973)

    Article  Google Scholar 

  29. Wignall, G. D., Ballard, D. G. H., Schelten, J.: Eur. Polym. J. 10, 861 (1974)

    Article  Google Scholar 

  30. Cotton, J. P., Decker, D., Benoit, H., Farnoux, B., Higgins, J., Jannink, G., Ober, R., Picot, C., Des Cloizeaux, J.: Macromolecules 7, 863 (1974)

    Article  Google Scholar 

  31. Daoud, M., Cotton, J. P., Farnoux, B., Jannink, F., Sarma, G., Benoit, H., Duplessix, R., Picot, C., De Gennes, P. G.: Macromolecules 8, 804 (1975)

    Article  Google Scholar 

  32. Schelten, J., Wignall, G. D., Ballard, D. G. H., Schmatz, W.: Colloid Polym. Sci. 252, 749 (1974)

    Article  Google Scholar 

  33. Lieser, G., Fischer, E. W., Ibel, K.: J. Polym. Sci. Polym. Lett. Ed. 13, 39 (1975)

    Article  Google Scholar 

  34. Wendorff, J. H., Fischer, E. W.: Kolloid-Z. Z. Polym. 251, 876 884 (1973)

    Article  Google Scholar 

  35. Renninger, A. A., Wicks, G. G., Uhlmann, D. R.: J. Polym. Sci. Polym. Phys. Ed. 13, 1247, 1481 (1975)

    Article  Google Scholar 

  36. Reinninger, A. A., Uhlmann, D. R.: J. Polym. Sci. Polym. Phys. Ed. 14, 353, 415 (1976)

    Article  Google Scholar 

  37. Hayashi, H., Hamada, F., Nakajima, A.: Macromolecules 9, 543 (1976)

    Article  Google Scholar 

  38. Patterson, G. D.: J. Macromol. Sci. Phys. B12, 61 (1976)

    Google Scholar 

  39. Flory, P. J.: Principles of polymer chemistry. Ithaca, New York: Cornell Univ. 1953

    Google Scholar 

  40. Yeh, G. S. Y., Geil, P. H.: J. Macromol. Sci. B1, 235 (1967)

    Google Scholar 

  41. Yeh, G. S. Y.: J. Macromol. Sci. B6, 451 465 (1972)

    Google Scholar 

  42. Gölz, W. L. F., Zachmann, H. G.: Kolloid-Z. Z. Polym. 247, 814 (1971)

    Article  Google Scholar 

  43. Horii, F., Kitamaru, R., Suzuki, T.: J. Polym. Sci. Polym. Lett. Ed. 15, 65 (1977)

    Article  Google Scholar 

  44. Zachmann, H. Z., Gölz, W.: J. Polym. Sci. Symposium 42, 693 (1973)

    Google Scholar 

  45. Gölz, W. L. F., Zachmann, H. G.: Makromol. Chem. 176, 2721 (1975)

    Article  Google Scholar 

  46. Miyake, A.: J. Polym. Sci. 28, 476 (1958)

    Article  Google Scholar 

  47. Chûjô, R.: J. Phys. Soc. Japan 18, 124 (1963)

    Article  Google Scholar 

  48. Russel, A. M., Torchia, D. A.: Rev. Sci. Instr. 33, 442 (1962)

    Article  Google Scholar 

  49. Wilson, G. V. H.: J. Appl. Phys. 34, 3276 (1963)

    Article  Google Scholar 

  50. Slonim, I. Ya., Lyubimov, A. N., Urman, Ya. G., Konovalov, A. G., Varenik, A. F.: Vysokomolek. Soed. 7, 245 (1965)

    Google Scholar 

  51. Slonim, I. Ya., Lyubimov, A. N.: The NMR of polymers. Translated from Russian Ed. New York: Plenum 1970, p. 155

    Google Scholar 

  52. Gutowsky, H. S., Pake, G. E.: J. Chem. Phys. 18, 162 (1950)

    Article  Google Scholar 

  53. Pechhold, W.: Kolloid-Z. Z. Polym. 228, 1 (1968)

    Article  Google Scholar 

  54. Wahlquist, H.: J. Chem. Phys. 35, 1708 (1961)

    Article  Google Scholar 

  55. Smith, G. W.: J. Appl. Phys. 35, 1217 (1964)

    Article  Google Scholar 

  56. Arndt, R.: J. Appl. Phys. 36, 2522 (1965)

    Article  Google Scholar 

  57. Buckmaster, H. A., Dering, J. C.: J. Appl. Phys. 39, 4486 (1968)

    Article  Google Scholar 

  58. For example, Kowalik, J., Osborne, M. R.: Methods for unconstrained optimization problems. New York: American Elsevier Publ. 1968

    Google Scholar 

  59. Spendley, W., Hext, G. R., Himsworth, F. R.: Technometrics 4, 441 (1962)

    Google Scholar 

  60. Nelder, J. A., Mead, R.: Computer J. 7, 308 (1965)

    Google Scholar 

  61. Ogawa, K., Horii, F., Hyon, S.-H., Kitamaru, R., Yasuda, T., Okuno, T.: Polym. Prepr., Japan 26, No. 2, 343 (1977)

    Google Scholar 

  62. Kitamaru, R., Mandelkern, L.: J. Polym. Sci. Polym. Phys. Ed. 8, 2079 (1970)

    Google Scholar 

  63. Mandelkern, L., Allou, Jr., A. L., Gopalan, N.: J. Phys. Chem. 72, 309 (1968)

    Article  Google Scholar 

  64. Anderson, F. R.: J. Appl. Phys. 35, 64 (1964)

    Article  Google Scholar 

  65. Mandelkern, L., Price, J. M., Gopalan, M., Fatou, J. G.: J. Polym. Sci. Part A-2, 4, 385 (1966)

    Google Scholar 

  66. Kitamaru, R., Horii, F., Hyon, S.-H.: J. Polym. Sci. Polym. Phys. Ed. 15, 821 (1977)

    Article  Google Scholar 

  67. Kitamaru, R., Horii, F., Hyon, S.-H.: ACS Polym. Prepr. 17 (2), 549 (1976); revised results are used in this review, considering the effect of modulation amplitude

    Google Scholar 

  68. Mandelkern, L., Chow, C. Y.: private communication; Chow, C. Y.: A broad-line NMR study of molecular weight fractions of bulk polyethylene. Ph. D. dissertation, Florida State University 1973

    Google Scholar 

  69. Mandelkern, L.: Characterization of materials in research, ceramics and polymers. Syracuse, New York: Syracuse Univ. Press 1975, chap. 13

    Google Scholar 

  70. Hendus, H., Schneel, G.: Kunststoffe 55, 69 (1961)

    Google Scholar 

  71. Okada, T., Mandelkern, L.: J. Polym. Sci. Part A-2, 5, 239 (1967)

    Article  Google Scholar 

  72. Gopalan, M. R., Mandelkern, L.: J. Polym. Sci. Part B, 5, 925 (1967)

    Article  Google Scholar 

  73. Mandelkern, L.: J. Phys. Chem. 75, 3909 (1968)

    Article  Google Scholar 

  74. Fatou, J. G., Mandelkern, L.: J. Phys. Chem. 69, 417 (1965)

    PubMed  Google Scholar 

  75. Hyon, S.-H., Horii, F., Kitamaru, R.: Bull. Inst. Chem. Res. Kyoto Univ. 55, 248 (1977)

    Google Scholar 

  76. Hyndman, D., Origlio, G. G.: J. Polym. Sci. 39, 556 (1959)

    Article  Google Scholar 

  77. Stein, R. S., Noriss, F. H.: J. Polym. Sci. 21, 381 (1956)

    Article  Google Scholar 

  78. Stein, R. S.: J. Polym. Sci. 31, 327 (1958)

    Article  Google Scholar 

  79. Glenz, W., Morosoff, N., Peterlin, A.: J. Polym. Sci. Polym. Lett. Ed. 9, 211 (1971)

    Google Scholar 

  80. Flory, P. J.: J. Amer. Chem. Soc., 84, 2857 (1962)

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Institute for Chemical Research, Kyoto University, 611, Uji, Kyoto, Japan

    Ryozo Kitamaru & Fumitaka Horii

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  1. Ryozo Kitamaru
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  2. Fumitaka Horii
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Kitamaru, R., Horii, F. (1978). NMR approach to the phase structure of linear polyethylene. In: Polymer Chemistry. Advances in Polymer Science, vol 26. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0022823

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  • DOI: https://doi.org/10.1007/BFb0022823

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-08677-2

  • Online ISBN: 978-3-540-35896-1

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