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Speciality Polymers/Polymer Physics pp 129–180Cite as

Thermotropic Mesophases in Element-Organic Polymers

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Part of the book series: Advances in Polymer Science ((POLYMER,volume 88))

Abstract

This review is primarily concerned with mesomorphic behaviour of element-organic polymers, such as linear and cyclolinear polyorganosiloxanes and linear polyphosphazenes. These polymers can form thermotropic mesophases without any mesogens. Recent development in thermodynamics, kinetics, structure and morphology, elasticity and thermoelasticity and some other properties are considered. The influence of the molecular structure and molecular weight of linear macromolecules on the ability to form the mesophases and their temperature stability is discussed. The phase behaviour of cyclolinear polyorganosiloxanes is described with special emphases on the temperature stability of the mesophases as a function of molecular structure, tacticity, substituents and flexible spacers. The state of order of polyorganosiloxanes is analysed in comparison to mesophase states of linear and cyclic low molecular siloxanes. The lyotropic mesophase behaviour of the ladder polyorganosiloxanes is also examined briefly.

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Abbreviations

b0 :

thickness of nucleus

C1, C2 :

constants in the Mooney-Rivlin equation

E:

activation energy

f:

retractive force

fu :

energy component of retractive force

G:

free energy

Hi :

enthalpy of isotropization

Hm :

enthalpy of fusion

K:

overall rate of a transition

M:

molecular weight (mass)

n:

Avrami parameter

Q:

heat

<r 20 >:

mean square end-to-end distance of unperturbed chains

T:

absolute temperature

Tg :

glass transition temperature

Ti :

isotropization temperature

T 0i :

isotropization temperature of lamellae of infinite thickness

Tm :

melting point

U:

internal energy

V:

linear growth rate; volume

W:

work

λ:

elongation ratio

σ:

interfacial free energy parallel to the molecular chain direction

σe :

interfacial free energy perpendicular to the molecular chain direction

PDPhS:

polydiphenylsiloxane

CLPOS:

cyclolinear polyorganosiloxanes

POSSO:

polyorganosilsesquioxane

OPCTS:

octaphenylcyclotetrasiloxane

DOTES:

1,3-dioxytetramethyldisiloxane

DOTPS:

1,3-dioxytetra-n-propyldisiloxane

DECPS:

decaethylcyclopentasiloxane

PBFP:

poly bis(trifluoroethoxy)phosphazene

PDES:

polydiethylsiloxane

PDPS:

polydipropylsiloxane

PDMS:

polydimethylsiloxane

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Authors and Affiliations

  1. Karpov Institute of Physical Chemistry, Institute of Synthetic Polymer Materials, USSR Academy of Sciences, Moscow, Russia

    Yu. K. Godovsky & V. S. Papkov

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  1. Yu. K. Godovsky
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  2. V. S. Papkov
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  3. K. Dušek
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© 1989 Springer-Verlag Berlin Heidelberg

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Godovsky, Y.K., Papkov, V.S., Dušek, K. (1989). Thermotropic Mesophases in Element-Organic Polymers. In: Speciality Polymers/Polymer Physics. Advances in Polymer Science, vol 88. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0017966

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  • DOI: https://doi.org/10.1007/BFb0017966

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  • Print ISBN: 978-3-662-15081-8

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