Abstract
The possibilities and limits of DSC and DTA for the determination of binary phase diagrams are discussed. The major factors, responsible for the experimentally measured signal shapes and their interpretation are structural relationships of the phases (nucleation) and chemical reaction rates (diffusion). Examples for a variety of signals are given, using several oxide systems.
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Dedicated to Hans Seifert on the occasion of his 60th birthday
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© 1991 Springer-Verlag
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Eysel, W. (1991). Thermoanalytical investigations of binary oxide systems. In: Smykatz-Kloss, W., Warne, S.S.J. (eds) Thermal Analysis in the Geosciences. Lecture Notes in Earth Sciences, vol 38. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0010265
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DOI: https://doi.org/10.1007/BFb0010265
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