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Clusters pp 1-49 | Cite as

Metal-metal multiple bonds in dinuclear clusters

  • F. A. Cotton
  • R. A. Walton
Conference paper
Part of the Structure and Bonding book series (STRUCTURE, volume 62)

Abstract

Just over 20 years have elapsed since the first recognition of the existence of compounds that contain metal-metal multiple bonds. The present article surveys many of the important developments that have occurred in this field since the publication in 1982 of the text “Multiple Bonds Between Metal Atoms” by the present authors. Detailed updates are provided of the chemistry surrounding ditungsten, ditechnetium, and dirhenium complexes that possess quadruple bonds (σ2Π4δ2 electronic configuration) and electron-rich triple bonds (σ2Π4δ2δ*2 electronic configuration). The rapidly developing chemistry of multiply bonded diruthenium and diosmium complexes that possess the M 2 +4 , M 2 5+ , and M 2 6+ cores, especially those containing ligand bridges, is also surveyed. Additional topics that have been covered are the following: the reactivity of dimolybdenum(III) and ditungsten(III) hexaalkoxides; the chemistry of singly bonded diplatinum(III) complexes; experimental and theoretical aspects of the bonding in
complexes; the diatomics Mo2, Cr2, V2 and Ru2; and the photoelectron spectroscopy, optical activity, and M-M bond length/bond order and charge correlations that characterize compounds that contain metal-metal multiple bonds.

Keywords

Bond Length Metal Atom Bond Order Configuration Interaction Axial Ligand 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Cotton, F. A., Walton, R. A.: Multiple Bonds Between Metal Atoms, J. Wiley & Sons, New York, 1982 and references thereinGoogle Scholar
  2. 2.
    Chisholm, M. H., Rothwell, I. P.: Prog. Inorg. Chem. 29, 1 (1982)Google Scholar
  3. 3.
    Felthouse, T. R.: Prog. Inorg. Chem. 29, 73 (1982)Google Scholar
  4. 4.
    Chisholm, M. H. (Editor): ACS Symp. Series, No. 221, 1983; See articles by Lichtenberger, Clark and Stead, Curtis, Chisholm, Cotton, Walton and SattelbergerGoogle Scholar
  5. 5.
    Chisholm, M. H.: Polyhedron 2, 681 (1983)Google Scholar
  6. 6.
    Cotton, F. A., Chisholm, M. H.: Chem. & Eng. News 60, June 28, page 40 (1982)Google Scholar
  7. 7.
    Walton, R. A.: Israeli J. Chem., in pressGoogle Scholar
  8. 8.
    Koz'min, P. A., Surazhskaya, M. D.: Sov. J. Coord. Chem. 6, 309 (1980)Google Scholar
  9. 9.
    Preetz, W., Peters, G.: Z. Naturforsch. 35b, 797 (1980)Google Scholar
  10. 10.
    Cotton, F. A., Daniels, L., Davison, A., Orvig, C.: Inorg. Chem. 20, 3051 (1981)Google Scholar
  11. 11.
    Cotton, F. A., Pedersen, E.: ibid. 14, 383 (1975)Google Scholar
  12. 12.
    Bratton, W. K., Cotton, F. A.: ibid. 87, 921 (1965)Google Scholar
  13. 13.
    Cotton, F. A., Shive, L. W.: ibid. 14, 2032 (1975)Google Scholar
  14. 14.
    Cotton, F. A., Davison, A., Day, V. W., Fredrich, M. F., Orvig, C., Swanson, R.: ibid. 21, 1211 (1982)Google Scholar
  15. 15.
    Cotton, F. A., Gage, L. D.: Nouv. J. Chim. 1, 441 (1977)Google Scholar
  16. 16.
    Zaitseva, L. L., Kotel'nikova, A. S., Rezvov, A. A.: Russ. J. Inorg. Chem. 25, 1449 (1980)Google Scholar
  17. 17.
    Spitsyn, V. I., Baierl, B., Kryuchkov, S. V., Kuzina, A. F., Varen, M.: Dokl. Akad. Nauk SSSR 256, 608 (1981)Google Scholar
  18. 18.
    Kryuchkov, S. V., Kuzina, A. F., Spitsyn, V. I.: ibid. 266, 127 (1982)Google Scholar
  19. 19.
    Rakitin, Yu. V., Kryuchkov, S. V., Aleksandrov, A. I., Kuzina, A. F., Nemtsev, N. V., Ershov, B. G., Spitsyn, V. I.: ibid. 269, 1123 (1983)Google Scholar
  20. 20.
    Koz'min, P. A., Larina, T. B., Surazhskaya, M. D.: Sov. J. Coord. Chem. 8, 451 (1982)Google Scholar
  21. 21.
    Koz'min, P. A., Larina, T. B., Surazhskaya, M. D.: Koord. Khim. 7, 1719 (1981) (Chem. Abs. 96, 13966b (982))Google Scholar
  22. 22.
    Cotton, F. A., Fanwick, P. E., Gage, L. D.: J. Am. Chem. Soc. 102, 1570 (1980)Google Scholar
  23. 23.
    Nefedov, V. I., Koz'min, P. A.: Inorg. Chim. Acta 64, L177 (1982)Google Scholar
  24. 24.
    Spitsyn, V. I., Kuzina, A. F., Kryuchkov, S. V.: Russ. J. Inorg. Chem. 25, 406 (1980)Google Scholar
  25. 25.
    Kryuchkov, S. V., Kuzina, A. F., Spitsyn, V. I.: ibid. 28, 1124 (1983)Google Scholar
  26. 26.
    Barder, T. J., Walton, R. A.: Inorg. Chem. 21, 2510 (1982)Google Scholar
  27. 27.
    Bursten, B. E., Cotton, F. A., Fanwick, P. E., Stanley, G. G.: J. Am. Chem. Soc. 105, 3082 (1983)Google Scholar
  28. 28.
    Hay, P. J.: ibid. 104, 7007 (1982)Google Scholar
  29. 29.
    Clark, R. J. H., Stead, M. J.: Inorg. Chem. 22, 1214 (1983)Google Scholar
  30. 30.
    Nocera, D. G., Gray, H. B.: J. Am. Chem. Soc. 103, 7349 (1981)Google Scholar
  31. 31.
    Nocera, D. G., Maverick, A. W., Winkler, J. R., Che, C., Gray, H. B.: ACS Symp. Ser. No. 211, 21 (1983)Google Scholar
  32. 32.
    Koz'min, P. A., Surazhskaya, M. D., Larina, T. B.: Koord. Khim. 8, 709 (1982) Chem. Abs. 97, 136870u (1982)Google Scholar
  33. 33.
    Calderazzo, F., Marchetti, F., Poli, R., Vitali, D., Zanazzi, P. F.: J. Chem. Soc., Dalton Trans. 1665 (1982)Google Scholar
  34. 34.
    Shtemenko, A. V., Bagirov, Sh. A., Kotel'nikova, A. S., Lebedev, V. G., Kazymov, O. I., Alieva, A. I.: Russ. J. Inorg. Chem. 26, 58 (1981)Google Scholar
  35. 35.
    Misailova, T. V., Kotel'nikova, A. S., Golovaneva, I. F., Evstaf'eva, O. N., Lebedev, V. G.: ibid. 26, 343 (1981)Google Scholar
  36. 36.
    Koz'min, P. A., Surazhskaya, M. D., Larina, T. B., Shtemenko, A. V., Kotel'nikova, A. S., Golovaneva, I. F.: Sov. J. Coord. Chem. 5, 386 (1981)Google Scholar
  37. 37.
    Kotel'nikova, A. S., Moskovkin, A. S., Misailova, T. V., Miroshnichenko, I. V., Bagirov, Sh. A.: Russ. J. Inorg. Chem. 25, 1656 (1980)Google Scholar
  38. 38.
    Cotton, F. A., Gage, L. D., Rice, C. E.: Inorg. Chem. 18, 1138 (1979)Google Scholar
  39. 39.
    Koz'min, P. A., Surazhskaya, M. D., Larina, T. B.: Russ. J. Inorg. Chem. 26, 57 (1981)Google Scholar
  40. 40.
    Kuz'min, A. I., Shtemenko, A. V., Kotel'nikova, A. S.: ibid. 25, 1662 (1980)Google Scholar
  41. 41.
    Eastland, G. W., Yang, G., Thompson, T.: Meth. and Find. Exptl. Clin. Pharmacol. 5, 435 (1983)Google Scholar
  42. 42.
    Martin, D. S., Huang, H.-W., Newman, R. A.: Inorg. Chem. 23, 699 (1984)Google Scholar
  43. 43.
    Srinivasan, V., Walton, R. A.: ibid. 19, 1635 (1980), and references cited thereinGoogle Scholar
  44. 44.
    Brown, P. R., Cloke, F. G. N., Green, M. L. H., Tovey, R. C.: J.C.S. Chem. Commun. 1982, 519Google Scholar
  45. 45.
    Ebner, J. R., Walton, R. A.: Inorg. Chem. 14, 1987 (1975)Google Scholar
  46. 46.
    Glicksman, H. D., Walton, R. A., Inorg. Chim. Acta 19, 91 (1976)Google Scholar
  47. 47.
    Bursten, B. L., Cotton, F. A., Fanwick, P. E., Stanley, G. G., Walton, R. A.: J. Am. Chem. Soc. 105, 2606 (1983)Google Scholar
  48. 48.
    Cotton, F. A., Dunbar, K. R., Falvello, L. R., Tomas, M., Walton, R. A.: ibid. 105, 4950 (1983)Google Scholar
  49. 49.
    Dunbar, K. R., Walton, R. A.: Inorg. Chem. 24, 5 (1985)Google Scholar
  50. 50.
    Cutler, A. R., Walton, R. A.: Inorg. Chim. Acta, in pressGoogle Scholar
  51. 51.
    Walton, R. A.: ACS Symp. Ser. No. 155, 207 (1981)Google Scholar
  52. 52.
    Cole, N. F., Cotton, F. A., Powell, G. L., Smith, T. J.: Inorg. Chem. 22, 2618 (1983)Google Scholar
  53. 53.
    Puddephatt, R. J.: Chem. Soc. Revs. 1983, 99Google Scholar
  54. 54.
    Barder, T. J., Cotton, F. A., Lewis, D., Schwotzer, W., Tetrick, S. M., Walton, R. A.: J. Am. Chem. Soc. 106, 2882 (1984)Google Scholar
  55. 55.
    Abbott, E. H., Bose, K. S., Cotton, F. A., Hall, W. T., Sekutowski, J. C.: Inorg. Chem. 17, 3240 (1978)Google Scholar
  56. 56.
    Barder, T. J., Cotton, F. A., Dunbar, K. R., Powell, G. L., Schwotzer, W., Walton, R. A.: Inorg. Chem., in pressGoogle Scholar
  57. 57.
    Shaik, S., Hoffmann, R., Fisel, R. C., Summerville, R. H.: J. Am. Chem. Soc. 102, 4555 (1980)Google Scholar
  58. 58.
    Barder, T. J., Cotton, F. A., Powell, G. L., Tetrick, S. M., Walton, R. A.: ibid. 106, 1323 (1984)Google Scholar
  59. 59.
    Barder, T. J., Tetrick, S. M., Walton, R. A., Cotton, F. A., Powell, G. L.: ibid. 105, 4090 (1983)Google Scholar
  60. 60.
    Cotton, F. A., Ilsley, W. H., Kaim, W.: ibid. 102, 1918 (1980)Google Scholar
  61. 61.
    Barder, T. J., Cotton, F. A., Falvello, L. R., Walton, R. A.: Inorg. Chem. 24, 1258 (1985)Google Scholar
  62. 62.
    Dunbar, K. R., Walton, R. A.: Inorg. Chim. Acta 87, 185 (1984)Google Scholar
  63. 63.
    Cotton, F. A., Daniels, L. M., Schmulbach, C. D.: ibid. 75, 163 (1983)Google Scholar
  64. 64.
    Allison, J. D., Wood, T. E., Wild, R. E., Walton, R. A.: Inorg. Chem. 21, 3540 (1982)Google Scholar
  65. 65.
    Cameron, C. J., Tetrick, S. M., Walton, R. A.: Organometallics 3, 240 (1984)Google Scholar
  66. 66.
    Cotton, F. A., Daniels, L. M., Dunbar, K. R., Falvello, L. R., Tetrick, S. M., Walton, R. A.: J. Am. Chem. Soc., in pressGoogle Scholar
  67. 67.
    Anderson, L. B., Barder, T. J., Walton, R. A.: Inorg. Chem., in pressGoogle Scholar
  68. 68.
    Sattelberger, A. P., McLaughlin, K. W., Huffman, J. C.: J. Am. Chem. Soc. 103, 2880 (1981)Google Scholar
  69. 69.
    Santure, D. J., McLaughlin, K. W., Huffman, J. C., Sattelberger, A. P.: Inorg. Chem. 22, 1877 (1983)Google Scholar
  70. 70.
    Cotton, F. A., Wang, W.: ibid. 21, 3860 (1982)Google Scholar
  71. 71.
    Cotton, F. A., Wang, W.: ibid. 23, 1604 (1984)Google Scholar
  72. 72.
    Chisholm, M. H., Chiu, H. T., Huffman, J. C.: Polyhedron 3, 759 (1984)Google Scholar
  73. 73.
    Bancroft, G. M., Pellach, E., Sattelberger, A. P., McLaughlin, K. W.: J.C.S. Chem. Commun. 1982, 752Google Scholar
  74. 74.
    Sattelberger, A. P.: ACS Symp. Ser. No. 211, p. 291 (1983)Google Scholar
  75. 75.
    Comments delivered by D. L. Lichtenberger following the presentation of the paper in Ref. 74; see ACS Symp. Ser. No. 211, p. 301 (1983). Note that through an inadvertant omission, the author of the discussion on p. 301 (Dr. Lichtenberger) is not citedGoogle Scholar
  76. 76.
    Santure, D. J., Huffman, J. C., Sattelberger, A. P.: Inorg. Chem. 23, 938 (1984)Google Scholar
  77. 77.
    Girolami, G. S., Mainz, V. V., Andersen, R. A.: ibid. 19, 805 (1980)Google Scholar
  78. 78.
    Cotton, F. A., Lay, D. G.: ibid. 20, 935 (1981)Google Scholar
  79. 79.
    Girolami, G. S., Andersen, R. A.: ibid. 21, 1318 (1982)Google Scholar
  80. 80.
    Cotton, F. A., Kalbacher, B. J.: ibid. 16, 2386 (1977)Google Scholar
  81. 81.
    Sharp, P. R., Schrock, R. R.: J. Am. Chem. Soc. 102, 1430 (1980)Google Scholar
  82. 82.
    Schrock, R. R., Sturgeoff, L. G., Sharp, P. R.: Inorg. Chem. 22, 2801 (1983)Google Scholar
  83. 83.
    Cotton, F. A., Felthouse, T. R., Lay, D. C.: J. Am. Chem. Soc. 102, 1431 (1980)Google Scholar
  84. 84.
    Cotton, F. A., Extine, M. W., Felthouse, T. R., Kolthammer, B. W., Lay, D. G.: ibid. 103, 4040 (1981)Google Scholar
  85. 85.
    Cotton, F. A., Felthouse, T. R.: Inorg. Chem. 20, 3880 (1981)Google Scholar
  86. 86.
    Zietlow, T. C., Klendworth, D. D., Nimry, T., Salmon, D. J., Walton, R. A.: ibid. 20, 947 (1981)Google Scholar
  87. 87.
    Harwood, W. S., Walton, R. A.: unpublished resultsGoogle Scholar
  88. 88.
    Cotton, F. A., Falvello, L. R., Mott, G. N., Schrock, R. R., Sturgeoff, L. G.: Inorg. Chem. 22, 2621 (1983)Google Scholar
  89. 89.
    Cotton, F. A., Mott, G. N., Schrock, R. R., Sturgeoff, L. G.: J. Am. Chem. Soc. 104, 6781 (1982)Google Scholar
  90. 90.
    McCarley, R. E., Ryan, T. R., Toradi, C. C.: ACS Symp. Ser. No. 155, p. 41 (1981)Google Scholar
  91. 91.
    Ryan, T. R., McCarley, R. E.: Inorg. Chem. 21, 2072 (1982)Google Scholar
  92. 92.
    McCarley, R. E.: Phil. Trans. R. Soc. Lond. A308, 141 (1982)Google Scholar
  93. 93.
    Cotton, F. A., Hubbard, J. L., Lichtenberger, D. L., Shim, I.: J. Am. Chem. Soc. 104, 680 (1982)Google Scholar
  94. 94.
    Cotton, F. A., Falvello, L. R., Han, S., Wang, W.: Inorg. Chem. 22, 4106 (1983)Google Scholar
  95. 95.
    Chakravarty, A. R., Cotton, F. A., Shamshoum, E. S.: ibid. 23, 4216 (1984)Google Scholar
  96. 96.
    DeMarco, D., Nimry, T., Walton, R. A.: ibid. 19, 575 (1980)Google Scholar
  97. 97.
    Anderson, L. B., Cotton, F. A., DeMarco, D., Fang, A., Ilsley, W. H., Kolthammer, B. W. S., Walton, R. A.: J. Am. Chem. Soc. 103, 5078 (1981)Google Scholar
  98. 98.
    Cotton, F. A., Mott, G. N.: ibid. 104, 5978 (1982)Google Scholar
  99. 99.
    Cotton, F. A., Felthouse, T. R., Lay, D. G.: Inorg. Chem. 20, 2219 (1981)Google Scholar
  100. 100.
    Klendworth, D. D., Welters, III, W. W., Walton, R. A.: Organometallics 1, 336 (1982)Google Scholar
  101. 101.
    Cotton, F. A., Darensbourg, D. J., Kolthammer, B. W. S.: J. Organomet. Chem. 217, C14 (1981)Google Scholar
  102. 102.
    Yamamoto, T., Imaizumi, K., Jurata, Y.: Inorg. Chim. Acta 85, 175 (1984)Google Scholar
  103. 103.
    Collman, J. P., Barnes, C. E., Collins, T. J., Brothers, P. J., Gallucci, J., Ibers, J. A.: J. Am. Chem. Soc. 103, 7030 (1981)Google Scholar
  104. 104.
    Collman, J. P., Barnes, C. E., Swepston, P. N., Ibers, J. A.: ibid. 106, 3500 (1984)Google Scholar
  105. 105.
    No journal report on this compound has ever appeared, but see MBBMA, p. 197 for informationGoogle Scholar
  106. 106.
    Clegg, W.: Acta Crystallogr. B36, 3112 (1980)Google Scholar
  107. 107.
    Kimura, T., Sakurai, T., Shima, M., Togano, T., Mukaida, M., Nomura, T.: Bull. Chem. Soc. Japan 55, 3927 (1982)Google Scholar
  108. 108.
    Malinski, T., Chang, D., Feldmann, F. N., Bear, J. L., Kadish, K. M.: Inorg. Chem. 22, 3225 (1983)Google Scholar
  109. 109.
    Chavan, M. Y., Feldmann, F. N., Lin, X. Q., Bear, J. L., Kadish, K. M.: ibid. 23, 2373 (1984)Google Scholar
  110. 110.
    Chakravarty, A. R., Cotton, F. A., Tocher, D. A.: J. Am. Chem. Soc. 106, 6409 (1984)Google Scholar
  111. 111.
    Chakravarty, A. R., Cotton, F. A., Tocher, D. A.: Inorg. Chem. 24, 172 (1985)Google Scholar
  112. 112.
    Tooze, R. P., Motevalli, M., Hursthouse, M. B., Wilkinson, G.: J.C.S. Chem. Commun. 1984, 799Google Scholar
  113. 113.
    Cotton, F. A., Thompson, J. L.: J. Am. Chem. Soc. 102, 6437 (1980)Google Scholar
  114. 114.
    Moore, D. S., Alves, A. S., Wilkinson, G.: J.C.S. Chem. Commun. 1981, 1164Google Scholar
  115. 115.
    Stephenson, T. A., Tocher, D. A., Walkinshaw, M. D.: J. Organomet. Chem. 232, C51 (1982)Google Scholar
  116. 116.
    Cotton, F. A., Chakravarty, A. R., Tocher, D. A., Stephenson, T. A.: Inorg. Chim. Acta 87, 115 (1984)Google Scholar
  117. 117.
    Behling, T., Wilkinson, G., Stephenson, T. A., Tocher, D. A., Walkinshaw, M. D.: J.C.S. Dalton Trans. 1983, 2109Google Scholar
  118. 118.
    Chakravarty, A. R., Cotton, F. A., Tocher, D. A.: J.C.S. Chem. Commun. 1984, 501; Inorg. Chem. 23, 4697 (1984)Google Scholar
  119. 119.
    Chakravarty, A. R., Cotton, F. A., Tocher, D. A., Tocher, J. H.: Organometallics 4, 8 (1985)Google Scholar
  120. 120.
    Chakravarty, A. R., Cotton, F. A., Tocher, D. A.: Inorg. Chem. 24, 1334 (1985)Google Scholar
  121. 121.
    Chakravarty, A. R., Cotton, F. A., Tocher, D. A.: ibid. 23, 4693 (1984)Google Scholar
  122. 122.
    Tetrick, S. M., Coombe, V. T., Heath, G. A., Stephenson, T. A., Walton, R. A.: ibid. 23, 4657 (1984)Google Scholar
  123. 123.
    Collman, J. P., Barnes, C. E., Woo, L. K.: Proc. Natl. Acad. Sci. USA 80, 8784 (1983)Google Scholar
  124. 124.
    For a general, introductory explanation of the principles, see Levy, D. H.: Scientific American 250 (No. 2), 96 (1984)Google Scholar
  125. 125.
    Morse, M. D., Smalley, R. E.: Ber. Bunsenges. Chem. 88, 228 (1984)Google Scholar
  126. 126.
    Hopkins, J. B., Langridge-Smith, P. R. R., Morse, M. D., Smalley, R. E.: J. Chem. Phys. 78, 1627 (1983)Google Scholar
  127. 127.
    Goodgame, M. M., Goddard, W. A., III: Phys. Rev. Letters 48, 135 (1982)Google Scholar
  128. 128.
    Michalopoulos, D. L., Gensic, M. E., Hansen, S. G., Powers, D. E., Smalley, R. E.: J. Phys. Chem. 86, 3914 (1982)Google Scholar
  129. 129.
    Riley, S. J., Parks, E. K., Pobo, L. G., Wexler, S.: J. Chem. Phys. 79, 2577 (1983)Google Scholar
  130. 130.
    Pellin, M. J., Gruen, D. M.: ibid. 79, 5887 (1983)Google Scholar
  131. 131.
    Bondybey, V. E., English, J. H.: Chem. Phys. Letters 94, 443 (1983)Google Scholar
  132. 132.
    Efremov, Y. M., Samoilova, A. N., Gurvich, L. V.: Opt. Spectrosc. 36, 381 (1974)Google Scholar
  133. 133.
    Kok, R. A., Hall, M. B.: J. Phys. Chem. 87, 715 (1983)Google Scholar
  134. 134.
    Walch, S. P., Bauschlicker, C. W., Jr., Roos, B. O., Nelin, C. J.: Chem. Phys. Letters 103, 175 (1983)Google Scholar
  135. 135.
    Delley, B., Freeman, A. J., Ellis, D. E.: Phys. Rev. Letters 50, 488 (1983)Google Scholar
  136. 136.
    Langridge-Smith, P. R. R., Morse, M. D., Hansen, G. P., Smalley, R. E., Merer, A. J.: J. Chem. Phys. 80, 595 (1984)Google Scholar
  137. 137.
    Cotton, F. A., Shim, I.: J. Am. Chem. Soc. 104, 7025 (1982)Google Scholar
  138. 138.
    Cotton, F. A., Wang, W.: Nouv. J. Chem. 8, 331 (1984)Google Scholar
  139. 139.
    Atha, P. M., Hillier, I. H., Guest, M. F.: Mol. Phys. 46, 437 (1982)Google Scholar
  140. 140.
    Atha, P. M., Hillier, I. H., MacDowell, A. A., Guest, M. F.: J. Chem. Phys. 77, 195 (1982)Google Scholar
  141. 141.
    Correa de Mello, P., Edwards, W. D., Zerner, M. C.: Int. J. Quantum Chem. 23, 425 (1983)Google Scholar
  142. 142.
    Kok, R. A., Hall, M. B.: J. Am. Chem. Soc. 105, 676 (1983)Google Scholar
  143. 143.
    Atha, P. M., Campbell, J. C., Garner, C. D., Hillier, I. H., MacDowell, A. A.: J.C.S. Dalton Trans. 1085 (1983)Google Scholar
  144. 144.
    Wiest, R., Benard, M.: Chem. Phys. Letters 98, 102 (1983)Google Scholar
  145. 145.
    Ketkar, S. N., Fink, M.: J. Am. Chem. Soc. 107, 338 (1985)Google Scholar
  146. 146.
    Blondel, M.: Ann. Chim. Phys. 8, 110 (1905)Google Scholar
  147. 147.
    Wöhler, L., Frey, W.: Z. Elektroch. 15, 132 (1909)Google Scholar
  148. 148.
    Deléphine, M.: Compt. Rend. 150, 104 (1910)Google Scholar
  149. 149.
    Muraveiskaya, G. S., Orlova, V. S., Evstaf'eva, O. N.: Russ. J. Inorg. Chem. 19, 561 (1974)Google Scholar
  150. 150.
    Muraveiskaya, G. S., Kukina, G. A., Orlova, V. S., Evstaf'eva, O. N., Porai-Koshits, M. A.: Dokl. Akad. Nauk SSSR 226, 76 (1976)Google Scholar
  151. 151.
    Bancroft, D. P., Cotton, F. A., Falvello, L. R., Han, S., Schwotzer, W.: Inorg. Chim. Acta 87, 147 (1984)Google Scholar
  152. 152.
    Muraveiskaya, G. S., Abashkin, V. E., Evstaf'eva, O. N., Golovaneva, I. F., Shchelokov, R. N.: Sov. J. Coord. Chem. (Engl. transl.) 6, 218 (1980)Google Scholar
  153. 153.
    Cotton, F. A., Falvello, L. R., Han, S.: Inorg. Chem. 21, 1709 (1982)Google Scholar
  154. 154.
    Conder, H. L., Cotton, F. A., Falvello, L. R., Han, S., Walton, R. A.: ibid. 22, 1887 (1983)Google Scholar
  155. 155.
    Cotton, F. A., Han, S., Conder, H. L., Walton, R. A.: Inorg. Chim. Acta 72, 191 (1983)Google Scholar
  156. 156.
    Cotton, F. A., Falvello, L. R., Han, S.: Inorg. Chem. 21, 2889 (1982)Google Scholar
  157. 157.
    Schagen, J. D., Overbeek, A. R., Schenk, H.: ibid. 17, 1938 (1978)Google Scholar
  158. 158.
    Barton, J. K., Rabinowitz, H. N., Szalda, D. J., Lippard, S. J.: J. Am. Chem. Soc. 96, 2827 (1977)Google Scholar
  159. 159.
    Hollis, L. S., Lippard, S. J.: ibid. 103, 6761 (1981)Google Scholar
  160. 160.
    Hollis, L. S., Lippard, S. J.: Inorg. Chem. 21, 2116 (1982)Google Scholar
  161. 161.
    Hollis, L. S., Roberts, M. M., Lippard, S. J.: ibid. 22, 3637 (1983)Google Scholar
  162. 162.
    Che, C. M., Schaefer, W. P., Gray, H. B., Dickson, M. K., Stein, P. B., Roundhill, D. M.: J. Am. Chem. Soc. 104, 4253 (1982)Google Scholar
  163. 163.
    Chisholm, M. H., Folting, K., Huffman, J. C., Rothwell, I. P.: ibid. 104, 4389 (1982)Google Scholar
  164. 164.
    Chisholm, M. H., Folting, K., Hoffman, D. M., Huffman, J. C., Leonelli, J.: J.C.S. Chem. Commun. 1983, 589Google Scholar
  165. 165.
    Chisholm, M. H., Hoffman, D. M., Huffman, J. C.: J. Am. Chem. Soc. 106, 6806 (1984)Google Scholar
  166. 166.
    Schrock, R. R., Listemann, M. L., Sturgeoff, L. G.: ibid. 104, 4291 (1982)Google Scholar
  167. 167.
    Chisholm, M. H., Hoffman, D. M., Huffman, J. C.: Inorg. Chem. 22, 2903 (1983)Google Scholar
  168. 168.
    Chisholm, M. H., Huffman, J. C., Marchant, N. S.: J. Am. Chem. Soc. 105, 6162 (1983)Google Scholar
  169. 169.
    Cotton, F. A., Schwotzer, W., Shamshoum, E. S.: Organometallics 3, 1770 (1984)Google Scholar
  170. 170.
    Cotton, F. A., Schwotzer, W., Shamshoum, E. S.: Organometallics 2, 1167, 1340 (1983)Google Scholar
  171. 171.
    Chisholm, M. H., Folting, K., Heppert, J. A., Hoffman, D. M., Huffman, J. C.: J. Am. Chem. Soc. 107, 1234 (1985)Google Scholar
  172. 172.
    Lichtenberger, D. L., Blevins, C. H.: J. Am. Chem. Soc. 106, 1636 (1984)Google Scholar
  173. 173.
    Cotton, F. A.: Chem. Soc. Revs. 12, 35 (1983)Google Scholar
  174. 174.
    Cotton, F. A., Powell, G. L.: Inorg. Chem. 22, 1507 (1983)Google Scholar
  175. 175.
    Campbell, F. L., Cotton, F. A., Powell, G. L.: ibid. 23, 4222 (1984)Google Scholar
  176. 176.
    Cotton, F. A., Fanwick, P. E., Fitch, J. W., Glicksman, H. D., Walton, R. A.: J. Am. Chem. Soc. 101, 1752 (1979)Google Scholar
  177. 177.
    Ebner, J. R., Tyler, D. R., Walton, R. A.: Inorg. Chem. 15, 833 (1976)Google Scholar
  178. 178.
    Best, S. A., Smith, T. J., Walton, R. A.: ibid. 17, 99 (1978)Google Scholar
  179. 179.
    Agaskar, P. A., Cotton, F. A., Fraser, I. F., Peacock, R. D.: J. Am. Chem. Soc. 106, 1851 (1984)Google Scholar
  180. 180.
    Moscowitz, A.: Tetrahedron 13, 48 (1961)Google Scholar
  181. 181.
    Mason, S. F.: Molecular Optical Activity and the Chiral Discriminations, Cambridge University Press 1982Google Scholar
  182. 182.
    Snatzke, G.: Angew. Chem. Int. Ed. Engl. 18, 363 (1979)Google Scholar
  183. 183.
    Snatzke, G., Wagner, U., Wolff, H. P.: Tetrahedron 37, 349 (1981)Google Scholar
  184. 184.
    Engle, V. J., Gerger, R., Snatzke, G., Wagner, U.: Chem.-Ztg. 105, 85 (1981)Google Scholar
  185. 185.
    Omelanezuk, J., Snatzke, G.: Angew. Chem. Int. Ed. Engl. 20, 786 (1981)Google Scholar
  186. 186.
    Cotton, F. A., Falvello, L. R., Murillo, C. A.: Inorg. Chem. 22, 382 (1983)Google Scholar
  187. 187.
    Han, S.: Ph.D. Dissertation, Texas A & M Univ. 1984Google Scholar
  188. 188.
    Falvello, L. F.: unpublished work, Texas A & M Univ.Google Scholar

Copyright information

© Springer-Verlag 1985

Authors and Affiliations

  • F. A. Cotton
    • 1
  • R. A. Walton
    • 2
  1. 1.Department of ChemistryTexas A & M UniversityCollege StationUSA
  2. 2.Department of ChemistryPurdue UniversityWest LafayetteUSA

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